Enhancing oxygen reaction kinetics in lanthanum nickelate Ruddlesden-Popper electrodes via praseodymium oxide infiltration for solid oxide cells.

This study explores the effect of praseodymium oxide (PrOx) impregnation in lanthanum nickelate Ruddlesden-Popper (RP) type materials for use in oxygen electrodes of solid oxide cells (SOCs). These mixed conductors are free of cobalt and strontium, which are increasingly being avoided in solid oxide cell applications. We investigate two compositions, La2NiO4+δ (L2N1) and La4Ni3O10-δ (L4N3), demonstrating distinct electrical and oxygen kinetic properties. The L2N1 material exhibits superior performance due to its higher bulk oxygen-ion diffusion, which governs the enhanced ambipolar conduction, crucial for the oxygen exchange process. In the PrOx-impregnated samples, at 700 °C, the total polarization resistance (Rpol) values decrease to ∼0.6 Ω cm2 for L2N1 + PrOx and ∼0.8 Ω cm2 for L4N3 + PrOx, representing reductions by factors of ∼7 and ∼17, respectively, compared to the non-impregnated counterparts. Electrochemical measurements as a function of oxygen partial pressure suggest that surface-exchange processes may be rate-limiting. The impregnated PrOx acts as a catalyst for the dissociative adsorption of oxygen and improves the charge transfer, leading to significant enhancements in the polarization processes. The electrochemical properties and stability of these RP phases in oxidizing conditions, combined with the oxygen transport capabilities and mixed oxidation state of praseodymium oxide (Pr4+/Pr3+), offer promising Co- and Sr-free oxygen electrodes for SOC applications.

The Effect of Microstructural Changes on Mechanical and Electrochemical Corrosion Properties of Duplex Stainless Steel Aged for Short Periods.

This work reports the effects of microstructural changes due to the secondary phases, in particular sigma (σ), on the mechanical properties and electrochemical behavior of thermally aged duplex stainless steel (DSS). Structural, morphological, mechanical, and electrochemical characterizations were performed. Sigma phase content increased with increasing aging treatment time. It had a net-like shape, as observed by electron backscatter diffractometry (EBSD). Its presence directly damaged mechanical properties. The corrosion assessment included electrochemical impedance spectroscopy (EIS) in 1 M NaCl solution at temperatures of 25, 40, and 65 °C. EIS results demonstrate that an increase in the σ phase content decreased the corrosion resistance (21.1-0.8, 3.5-0.3, and 3.1-0.2 kΩ cm2 at 25, 40, and 60 °C, respectively).