1.
J Am Chem Soc
; 126(51): 16708-9, 2004 Dec 29.
Article
in English
| MEDLINE
| ID: mdl-15612693
ABSTRACT
Pd(bcope)(OTf)2 (where bcope is (C8H14)PCH2CH2P(C8H14)) is shown to react with an alkyne in the presence of parahydrogen to form alkyl hydrides, such as Pd(bcope)(CHPhCH2Ph)(H), that are detectable by NMR spectroscopy because the proton resonances of the alkyl arm appear with strongly enhanced signal strengths.