Effect of Chemical Treatments on the Mechanical Properties of Jute/Polyester Composites.

Natural fiber composites have been extensively studied for structural applications, with recent exploration into their potential for various uses. This study investigates the impact of chemical treatments on the properties of Brazilian jute woven fabric/polyester resin composites. Sodium hydroxide, hydrogen peroxide, and peracetic acid were utilized to treat the jute fabrics, followed by resin transfer molding (RTM) to form the composites. Evaluation included water absorption, flexural strength, tensile strength, and short-beam strength. The alkaline treatment induced changes in the chemical composition of the fibers' surface. Chemical treatments resulted in increased flexural and short-beam strength of the composites, with no significant alterations in tensile properties. The hydrogen peroxide treatment exhibited lower water absorption, suggesting its potential as a viable option for enhancing the performance of these composites.

Wood-Poly(furfuryl Alcohol) Prepreg: A Novel, Ecofriendly Laminate Composite.

Prepregs are commonly fabricated with non-renewable petroleum-based materials. To reduce the impact of the manufacturing of these materials and to produce more sustainable prepregs, this research aims to manufacture poly(furfuryl alcohol)/wood veneer prepregs and their posterior molding in laminate composites. For this purpose, the vacuum infusion process was used to impregnate the wood veneers, and compression molding was applied to manufacture three- and four-layer laminate composites. Scanning electronic microscopy was used to evaluate the impregnation. the laminate manufacturing and differential scanning calorimetry were used to predict the shelf-life of the prepregs, Fourier-transform infrared was used to evaluate the induced hydrolysis resistance, and thermogravimetric analysis was used to determine the thermal degradation of the laminates. Moreover, water uptake and flexural, compressive, and tensile properties were evaluated. The kinetic models were effective and showed a shelf life for the laminates of approximately 30 days in storage at -7 °C, which is an interesting result for laminates with lignocellulosic materials. FTIR proved the laminates' excellent resistance to hydrolysis. The water absorption, thermal stability, and mechanical properties did not differ as the amount of wood veneer increased, but these results were up to ~40% higher compared with unidirectional wood laminates found in the literature, which is probably linked to the excellent interface observed with SEM.

Rigid Polyurethane Biofoams Filled with Pine Seed Shell and Yerba Mate Wastes.

Pine seed shells and yerba mate are common wastes leftover from the food and beverage industry. This study presents the development of rigid polyurethane foams (RPUFs) filled with pine seed shells and yerba mate at 5, 10 and 15 wt%. The fillers were characterized for chemical properties using bench chemistry analyses, and the RPUFs were investigated in terms of chemical, morphological, mechanical, thermal and colorimetric characteristics. The main results indicated that yerba mate showed good compatibility with the polyurethane system, probably because its available hydroxyl groups reacted with isocyanate groups to form urethane bonds, producing increases in mechanical and thermal properties. However, pine seed shell did not appear to be compatible. Anisotropy increased slightly, as there was an increase in the percentage of reinforcement. The mechanical properties of the yerba mate reinforced foams proved stable, while there was a loss of overall up to ~50% for all mechanical properties in those reinforced with pine seed shell. Thermal properties were improved up to ~40% for the yerba mate reinforced foams, while those reinforced with pine nuts were stable. It was possible to observe a decrease in the glass transition temperature (Tg) of ~-5 °C for the yerba mate reinforced foams and ~-14 °C for the pine seed shell reinforced ones.

Experimental and Numerical Study of the Influence of Pre-Existing Impact Damage on the Low-Velocity Impact Response of CFRP Panels.

This paper presents an experimental and numerical investigation on the influence of pre-existing impact damage on the low-velocity impact response of Carbon Fiber Reinforced Polymer (CFRP). A continuum damage mechanics-based material model was developed by defining a user-defined material model in Abaqus/Explicit. The model employed the action plane strength of Puck for the damage initiation criterion together with a strain-based progressive damage model. Initial finite element simulations at the single-element level demonstrated the validity and capability of the damage model. More complex models were used to simulate tensile specimens, coupon specimens, and skin panels subjected to low-velocity impacts, being validated against experimental data at each stage. The effect of non-central impact location showed higher impact peak forces and bigger damage areas for impacts closer to panel boundaries. The presence of pre-existing damage close to the impact region leading to interfering delamination areas produced severe changes in the mechanical response, lowering the impact resistance on the panel for the second impact, while for non-interfering impacts, the results of the second impact were similar to the impact of a pristine specimen.

Imidazolium Ionic Liquids as Compatibilizer Agents for Microcrystalline Cellulose/Epoxy Composites.

Four imidazolium-based ionic liquids (IL; 1-butyl-3-methylimidazolium chloride, 1-carboxymethyl-3-methylimidazolium chloride, 1,3-dicarboxymethylimidazolium chloride and 1-(2-hydroxyethyl) -3-methylimidazolium chloride) were tested as compatibilizers of microcrystalline cellulose (MCC). Subsequently, ethanolic IL solutions were prepared; MCC was mixed, and the mixtures were left to evaporate the ethanol at ambient conditions. These modified MCC were characterized and applied as reinforcements (5.0 and 10 phr) in an epoxy resin aiming to manufacture biobased composites with enhanced performances. The IL did not significantly modify the morphological and structural characteristics of such reinforcements. Regarding the thermal stability, the slight increase was associated with the MCC-IL affinity. The IL-modified MCC-epoxy composites presented improved mechanical responses, such as flexural strength (≈22.5%) and toughness behavior (≈18.6%), compared with pure epoxy. Such improvement was also obtained for the viscoelastic response, where the storage modulus at the glassy state depended on the MCC amount and IL type. These differences were associated with stronger hydrogen bonding between IL and epoxy hardener or the IL with MCC, causing a "bridging" effect between MCC and epoxy matrix.

Castor Oil-Based Polyurethane/S2 Glass/Aramid Hybrid Composites Manufactured by Vacuum Infusion.

This study evaluates the hybridization effect of S2-glass/aramid on polyurethane (PU) composites produced by vacuum infusion. Different laminates were produced with similar thickness (around 2.5 mm), using, as reinforcement, only aramid fabrics (five layers, named as K5) or only S2-glass fabrics (eight layers, named as G8). Furthermore, hybridization was obtained by manufacturing symmetrical hybrid inter-ply laminates, with four S2-glass layers and two of aramid, (G2K)S and (KG2)S. The mechanical response of the laminates was evaluated in tensile, interlaminar shear strength, dynamical mechanical analysis and quasi-static indentation tests, and related to their morphological characteristics. The main results show that the pure glass composites presented less voids, but a higher density as well as higher tensile stiffness and strength. The aramid laminates showed a high capability for absorbing impact energy (ca. 30% higher than the pure glass laminates), and the hybrid laminates had intermediate properties. More importantly, this work shows the possibility of using a polyurethane matrix for vacuum infusion processing, effective even for aramid/S2-glass hybrid composites with thermoset polyurethane resin. This study is therefore promising for impact absorption in applications such as protective armor. The studied hybrid laminate may display a suitable set of properties and greater energy absorption capability and penetration resistance for impact applications.

Rigid Polyurethane Biofoams Filled with Chemically Compatible Fruit Peels.

Banana and bergamot peels are underutilized byproducts of the essential oil and juice-processing industry. This study was designed for the development of rigid polyurethane foam (RPUF) composites using polysaccharide-rich fruit peels as fillers. These fillers were characterized for chemical properties using wet analyses. Additionally, the influences of the filler type and filler content on morphological, thermal, mechanical, hygroscopic, and colorimetric properties of the RPUF were investigated. The main results indicated that, in a comparison with the neat RPUF, the insertion of up to 15% of fillers yielded similar water uptake, apparent density, compressive strength, and color properties, as well as increases up to 115% in thermal stability and up to 80% in cell size.

Experimental Investigation on the Mechanical and Physical Properties of Glass/Jute Hybrid Laminates.

Natural fibres have been partly substituting synthetic fibres in polymer composites due to their renewable character and many other advantages, and sometimes, they can be hybridized into a single composite for a better combination of properties. This work aims to study the effect of hybridization and stacking sequence on the mechanical and physical properties of the glass/jute laminates. For that, pure jute, pure glass and glass/jute hybrids were manufactured by vacuum infusion process using orthophthalic polyester resin. The composites were characterized via C-scan analysis, density, volume fraction of constituents and optical microscopy analyses. Mechanical properties were obtained from tensile, compression and shear tests. The longitudinal properties were higher than transverse properties for all laminates. The hybrids presented intermediate density and mechanical properties compared to pure glass and pure jute laminates. The hybrids produced similar density and tensile modulus, but with small differences in tensile strength and compressive strength which were justified based on variations in resin and void content due to the influence of the stacking sequence (glass/jute interlayer regions). In addition, the pure glass and the hybrid laminates displayed acceptable failure morphology in the in-plane shear test, but not the pure jute laminate.

Multifunctional Characteristics of Carbon Fibers Modified with Imidazolium Ionic Liquids.

A multifunctional designing approach is of great importance for advanced composite applications. This study assessed the use of ionic liquids (ILs) to modify the surface of carbon fiber (CF) and impart multifunctional characteristics to it. For that, ethanolic solutions of different ILs, 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, 1-butyl-3-methylimidazolium chloride and 1-(2-hydroxyethyl)-3-methylimidazolium chloride, at different concentrations, were used to treat the CF. Fourier-transform infrared spectroscopy confirmed the presence of IL on the CF surface. The contact angle for 1% w/v IL-treated CF and DGEBA epoxy decreased by up to 35%, corresponding to an increase in surface energy of fiber, accompanied by an increase of 91% in interfacial shear strength. These enhancements were achieved with the hydroxy-functionalized IL, showing the tunability of CF properties through the N-imidazolium substituent. An increase in crystallite size along the basal plane was also found due to the ordering of the graphitic structure on the surface. Moreover, there was a decrease in electrical resistivity of 77%. In all, the imidazolium ILs were considered a promising approach to induce multifunctional characteristics, namely enhanced interfacial strength and electrical conductivity, to unsized CF, which can also be beneficial for recycled fibers without deteriorating their inherent surface properties.

A Numerical Study on the Influence of Strain Rate in Finite-Discrete Element Simulation of the Perforation Behaviour of Woven Composites.

Predicting the perforation limit of composite laminates is an important design aspect and is a complex task due to the multi-mode failure mechanism and complex material constitutive behaviour required. This requires high-fidelity numerical models for a better understanding of the physics of the perforation event. This work presents a numerical study on the perforation behaviour of a satin-weave S2-glass/epoxy composite subjected to low-velocity impact. A novel strain-rate-dependent finite-discrete element model (FDEM) is presented and validated by comparison with experimental data for impacts at several energies higher and lower than their perforation limit. The strain rate sensitivity was included in the model by developing a novel user-defined material model, which had a rate-dependent bilinear traction separation cohesive behaviour, implemented using a VUSDFLD subroutine in Abaqus/Explicit. The capability of the model in predicting the perforation limit of the composite was investigated by developing rate-sensitive and insensitive models. The results showed that taking the strain rate into account leads to more accurate predictions of the perforation limit and damage morphology of the laminate subjected to impacts at different energies. The experimental penetration threshold of 89 J was estimated as 79 J by the strain-rate-sensitive models, which was more accurate compared to 52 J predicted by the strain-rate-insensitive model. Additionally, the coupling between interlaminar and intralaminar failure modes in the models led to a more accurate prediction of the delamination area when considering the rate sensitivity.

Optimization of Pin Position and Angle for Z-Pin-Reinforced Foam Core Sandwich Structures.

Sandwich panels (SP) are very promising components for structures as they ally high levels of specific stiffness and strength. Civil, marine and automotive industries are some examples of the sectors that use SPs frequently. This work demonstrates the potential of manufacturing Z-pin-reinforced foam core SPs, using a design strategy that indicated optimal values for both pin position and angle, keeping the same pin diameter as determined in a previous study. A simple search algorithm was applied to optimize each design, ensuring maximum flexural stiffness. Designs using optimal pin position, optimal pin angle and optimal values for both parameters are herein investigated using numerical and experimental approaches. The optimal pin position yielded an increase in flexural stiffness of around 8.0% when compared to the non-optimized design. In this same comparison, the optimal pin angle by itself increased the flexural stiffness by about 63.0%. Besides, the highest increase in the maximum load was found for those composites, molded with optimized levels of pin position and pin angle, which synergistically contributed to this result. All results were demonstrated with numerical and experimental results and there was a good agreement between them.

Recent studies on modified cellulose/nanocellulose epoxy composites: A systematic review.

Cellulose and its derivatives are widely explored for films and thickening of pharmaceutical solutions, in paints, as reinforcement in composites, among others. This versatility is due to advantages such as renewability, low cost, and environmental friendliness. When used in polymer composites, due to the hydrophilic character of the cellulose, surface chemical modification is highly recommended to improve its compatibility with the polymeric matrix. Hence, this paper presents a systematic review of chemically modified cellulose/epoxy resin composites focusing on the last five years. The investigation followed the PRISMA protocol that delivers a meticulous summary of all available primary research in response to a research question. After including/excluding steps, thirty-six studies were included in the review. The results were presented focusing on thermal, mechanical and dynamic-mechanical properties of the composites. In brief, this methodology helped identifying the main gaps in knowledge in that field.

The influence of silane surface modification on microcrystalline cellulose characteristics.

Microcrystalline cellulose (MCC) can be a reinforcement in composites, especially after surface modification. In this paper, MCC was modified using 3-aminopropyltriethoxysilane (APTES) in the following ratios (MCC/APTES): 1:3, 1:4, 1:5, 1:10). The MCC morphologies did not change with the treatment even though the distribution of APTES over the MCC surface varied. FTIR analysis showed MCC and APTES characteristic peaks for all samples. The crystallinity index (CI) decreased with the APTES ratio. The non-isothermal kinetic degradation by thermogravimetric analysis in different heating rates was studiedin order to evaluate the kinetic triplet: activation energy Ea, exponential factor (A), and reaction order (f(α)). The Ea dependence on conversion degree was not affected, but two degradation steps were observed for all samples. Ratios up to 1:4 suggested two consecutive autocatalytic degradation mechanisms. The 1:5 and 1:10 ratios caused a change in the most probable degradation mechanism for nucleation followed by autocatalytic degradation mechanism.

Osteoblastlike cell adhesion on titanium surfaces modified by plasma nitriding.

PURPOSE: The aim of this study was to evaluate the characteristics of various titanium surfaces modified by cold plasma nitriding in terms of adhesion and proliferation of rat osteoblastlike cells. MATERIALS AND METHODS: Samples of grade 2 titanium were subjected to three different surface modification processes: polishing, nitriding by plasma direct current, and nitriding by cathodic cage discharge. To evaluate the effect of the surface treatment on the cellular response, the adhesion and proliferation of osteoblastlike cells (MC3T3) were quantified and the results were analyzed by Kruskal-Wallis and Friedman statistical tests. Cellular morphology was observed by scanning electron microscopy. RESULTS: There was more MC3T3 cell attachment on the rougher surfaces produced by cathodic cage discharge compared with polished samples (P < .05). CONCLUSIONS: Plasma nitriding improves titanium surface roughness and wettability, leading to osteoblastlike cell adhesion.