1.
Dalton Trans
; 40(30): 7697-700, 2011 Aug 14.
Article
in English
| MEDLINE
| ID: mdl-21709913
ABSTRACT
From a series of N,N'-disubstituted-1,1'-binaphthyl-2,2'-diamines, several group 3 metal complexes were synthesized via an in situ procedure. These chiral complexes were subsequently applied to catalysis of intramolecular alkene hydroamination. Significant structure-activity relationships were observed, most notably a reversal of stereoselectivity for cyclopentyl versus diphenylmethyl substituents.