Treatment of oil sands process water using petroleum coke: Field pilot.

This is the first large-scale field pilot study that examined the feasibility and effectiveness of petroleum coke (PC), produced by a Fluid Coking Process, as an adsorbent for oil sands process water (OSPW) treatment. The pilot program consisted of an inline series of two reactors (pipeline reactor 1, and batch reactor 2) and lasted for approximately 4 months. The quality of treated OSPW as a function of residence time in the PC deposit under natural climatic conditions was assessed by looking at changes in organic compounds (acid extractable fraction (AEF), dissolved organic carbon (DOC), etc.), vanadium, and other trace element concentrations, major ions, conductivity, total suspended solids (TSS), pH and toxicity. The results indicated that the AEF adsorption by PC followed pseudo-second order kinetics and the overall combined removal efficiency of AEF was greater than 80%. Reactor 1 showed higher AEF removal than Reactor 2. DOC decreased about 50% after 4 weeks of retention in the PC deposit. An increase of vanadium concentration after PC contact indicated that vanadium leaching occurred. However, with increased residence time in the PC deposit, vanadium concentration decreased in the cells and tanks by 42% and 98%, respectively. Filtration through the PC deposit reduced the TSS in OSPW to less than laboratory detectable limits. Unlike untreated OSPW, treated OSPW did not show an acute toxic response based on whole effluent toxicity testing using trout, zooplankton, and bacteria. This study demonstrated that PC adsorption is a potentially commercially viable technology for highly efficient treatment of OSPW.

Influences of coagulation pretreatment on the characteristics of crude oil electric desalting wastewaters.

Highly polluted crude oil electric desalting wastewaters (EDWs) severely affect the efficiency of refinery wastewater treatment plants (WWTPs). Coagulation is an efficient pretreatment to reduce the impacts of EDWs. In the present study, the influences of coagulation pretreatment on the characteristics of EDWs of three typical Chinese crude oils, Liaohe heavy oil (LHO), Karamay heavy oil (KHO) and Daqing light oil (DLO), were investigated. The stability of three raw EDWs was broken and the contents of organic pollutants were significantly reduced by aluminum sulfate coagulation. More soluble COD and polar oils were removed from LHO-EDW (1241 and 98 mg L-1) and KHO-EDW (779 and 57 mg L-1) compared to DLO-EDW (417 and 11 mg L-1). Coagulation significantly changed the compositions of the organic pollutants of two heavy oil EDWs; however, slightly influenced DLO-EDW, particularly the polar organic pollutants. Most types of aromatic compounds, aliphatic acids and Ox polar compounds were removed from two heavy oil EDWs, but mainly alkanes were removed from DLO-EDW. As such, the differences in the types of dominant polar compounds became insignificant among treated heavy oil and light oil EDWs. Coagulation notably decreased the acute biotoxicity and improved the biodegradability of all treated EDWs. The residual organic nitrogen compounds in treated KHO-EDW contributed to a higher residual biotoxicity compared to treated LHO-EDW. The results demonstrate that coagulation can effectively improve the qualities of heavy oil EDWs by lowering the contents of organic pollutants and removing recalcitrant compounds, thus guaranteeing the efficiency of refinery WWTPs.