Leaching behavior of metals from asphalt mixtures modified with crumb rubber from scrap tires.

There are concerns about the potential toxicity of bitumen and recycled materials such as reclaimed asphalt pavements from end-of-life roads and crumb rubber from scrap tires used in asphalt mixtures because they contain metals that may be released into the groundwater. This study investigated the potential metal leaching of laboratory-prepared asphalt mixtures modified with polymer coated rubber (PCR) with wet and dry technology, devulcanized rubber (DVR), compared to an unmodified control mixture and a blend modified with a synthetic polymer (SBS). The objectives were to i) quantify concentrations of metals released, ii) calculate the flux rate, the cumulative mass release, and the assessment ratio for each metal, iii) verify if the metals exceeded the EPA drinking water limit, and, finally, iv) assess the source of metals release. Zinc had the highest concentration among all metals and was present in eluates from all mixtures. The cumulative zinc concentration from DVR mixture was 41% and 34% higher than the control and SBS mixtures, respectively. For PCR wet, the cumulative zinc concentration was 9% higher than the control blend and 1% lower than the SBS mix. The assessment ratio indicated that all metal concentrations would not exceed the drinking water limit, except for zinc, for which further evaluations were required. The main source of zinc may derive from aggregates. This work showed that crumb rubber might not be the only source of metal leaching, and its use in asphalt pavements does not cause a metal leaching higher than other materials.

Solar array placement, electricity generation, and cropland displacement across California's Central Valley.

Understanding agriculturally co-located solar photovoltaic (PV) installation capacity, practices, and preferences is imperative to foster a future where solar power and agriculture co-exist with limited impacts on food production. Crops and PV panels are often co-located as they have similar ideal conditions for maximum yield. The recent boom in solar photovoltaics is displacing a significant amount of cropland. The literature on agriculturally co-located PV array installations lacks important spatiotemporal details that could help inform future array installations and improve associated policies and incentive programs. This study used imagery from the National Agriculture Imagery Program for object-based analysis (within eCognition Developer), and from Landsat 5 TM, 7 ETM+ and 8 OLI for temporal analysis (using LandTrendr) to identify and characterize non-residential ground-mounted PV arrays in California's Central Valley installed between 2008 and 2018. This dataset includes over 210,000 individually identified panels grouped by mount and installation year into 1006 PV arrays (69% are agriculturally co-located). The most common type of mounting system is fixed-axis, and individual co-located systems tend to be small (0.34 MW). There were fewer single-axis tracking arrays, although the average capacity per system is nearly four times higher (1.20 MW). In total, the mapped arrays accounted for 3.6 GW of capacity and generated a cumulative of 32,700 GWh within the Central Valley during the study period. For the 694 identified agriculturally co-located arrays (2.1 GW), significantly sub-optimal installation practices were observed in the spacing and spatial field placement of the arrays. In terms of crop conversion preferences, commodity crops (pastureland) dominated the total cumulative area converted although specialty crops (orchards) also contributed to a large number of solar installations on cropland. These results provide important details of current PV placement practices; understanding these can help to inform future practices and guide future regulations that might promote solar installations while preserving agricultural production.

Well-to-wheel greenhouse gas emissions of electric versus combustion vehicles from 2018 to 2030 in the US.

CONCISE ABSTRACT: Electric vehicles (EVs) can reduce transportation-related greenhouse gas (GHG) emissions, given the planned electric grid decarbonization. Regulations can also reduce internal combustion engine vehicle's (ICEVs) emissions by mandating increased fuel economies or ethanol-gasoline mixes. Factors such as fuel economy, electricity grid mix, vehicle choice, and temperature affect EV GHG emissions relative to ICEVs, and successfully decarbonizing the transportation sector depends on understanding their combined effects. We use life-cycle assessment to compare the EV and ICEV well-to-wheel GHG emissions in the United States and four other states from 2018 to 2030. We found lower emissions for EVs than ICEVs in most conditions considered. In New York state, where natural gas power plants replace nuclear energy, GHG emissions of electricity generation increase over time after 2020. Future ICEVs can have comparable emissions to EVs due to fuel economy increase. Therefore, EV and ICEV can together lower transportation GHG emissions at a faster pace. EXTENDED ABSTRACT: Transportation-related greenhouse gas (GHG) emissions can be reduced by (a) increasing the share of electric vehicles (EVs) and (b) reducing GHG emissions of internal combustion engine vehicles (ICEVs) by mandating increased fuel economies or ethanol-gasoline mixes. Factors, such as fuel economy, electricity grid mix, vehicle choice, and temperature affect EVs' relative GHG emissions compared to ICEVs, and understanding their combined effect is necessary for a successful decarbonization of the transportation sector. We used life-cycle assessment to evaluate the simultaneous effect of the above-mentioned factors on the well-to-wheel GHG emissions of EVs and ICEVs from 2018 to 2030. The analysis was performed for the United States (US) average and state-level for Arizona, California, New York, and Oregon. Our results showed lower GHG emissions for EVs than ICEVs for most conditions considered. GHG emissions are expected to decrease in the US on average by 5% for EVs and 27% for ICEVs in 2030 compared to 2018. In 2030, the ICEV well-to-wheel GHG emissions were comparable to those of the EVs in the US average and Arizona. EVs perform best in California and Oregon throughout the considered period. In regions, such as New York, EVs driven 2021 and after will have higher GHG emissions than ICEVs, as natural gas power plants are replacing nuclear energy. While EV GHG emissions decrease over time due to grid decarbonization, future ICEVs can lower the GHG emissions, especially for larger vehicles, where EVs might not be the best option. Therefore, EV and ICEV can together lower transportation GHG emissions at a faster pace.

Trends in Water Use, Energy Consumption, and Carbon Emissions from Irrigation: Role of Shifting Technologies and Energy Sources.

Novel low-pressure irrigation technologies have been widely adopted by farmers, allowing both reduced water and energy use. However, little is known about how the transition from legacy technologies affected water and energy use at the aquifer scale. Here, we examine the widespread adoption of low-energy precision application (LEPA) and related technologies across the Kansas High Plains Aquifer. We combine direct energy consumption and carbon emission estimates with life cycle assessment to calculate the energy and greenhouse gas (GHG) footprints of irrigation. We integrate detailed water use, irrigation type, and pump energy source data with aquifer water level and groundwater chemistry information to produce annual estimates of energy use and carbon emissions from 1994 to 2016. The rapid adoption of LEPA technologies did not slow pumping, but it reduced energy use by 19.2% and GHG emissions by 15.2%. Nevertheless, water level declines have offset energy efficiency gains because of LEPA adoption. Deeper water tables quadrupled the proportion of GHG emissions resulting from direct carbon emissions, offsetting the decarbonization of the regional electrical grid. We show that low-pressure irrigation technology adoption, absent policies that incentivize or mandate reduced water use, ultimately increases the energy and carbon footprints of irrigated agriculture.

Evaluating the cost and carbon footprint of second-life electric vehicle batteries in residential and utility-level applications.

The volume of end-of-life automotive batteries is increasing rapidly as a result of growing electric vehicle adoption. Most automotive lithium-ion batteries (LIBs) are recycled but could be repurposed as second-life batteries (SLBs) since they have 70-80% residual capacity, which can be adequate for stationary applications. SLBs have been proposed as potential, inexpensive, low-carbon energy storage for residential and utility-level applications, with or without photovoltaics (PV). However, it is unknown whether SLBs will be better than new batteries and whether SLBs will provide similar cost and carbon emission reduction for the different stationary applications in all locations. This work compared the levelized cost of electricity and life-cycle carbon emissions associated with using SLBs and new LIBs in the US for three energy storage applications: (1) residential energy storage with rooftop PV, (2) utility-level PV firming, and (3) utility-level peak-shaving, leading to a total of 41 scenarios. SLBs reduced the levelized cost of electricity by 12-57% and carbon emissions by 7-31% compared to new LIBs in the considered applications, with higher reductions for utility-level applications. SLBs still provided benefits at the residential level when compared to rooftop PV alone by reducing the levelized cost by 15-25% and carbon emissions by 22-51%, making SLBs attractive to residential consumers as well. SLBs offer an opportunity to utilize an end-of-life product for energy storage applications, provided the uncertainty in SLB quality and availability is addressed.

Economic and Environmental Feasibility of Second-Life Lithium-Ion Batteries as Fast-Charging Energy Storage.

Energy storage can reduce peak power consumption from the electricity grid and therefore the cost for fast-charging electric vehicles (EVs). It can also enable EV charging in areas where grid limitations would otherwise preclude it. To address both the need for a fast-charging infrastructure as well as management of end-of-life EV batteries, second-life battery (SLB)-based energy storage is proposed for EV fast-charging systems. The electricity grid-based fast-charging configuration was compared to lithium-ion SLB-based configurations in terms of economic cost and life cycle environmental impact in five U.S. cities. Compared to using new batteries, SLB reduced the levelized cost of electricity (LCOE) by 12-41% and the global warming potential (GWP) by 7-77%. Photovoltaics along with SLB reduced the use of grid electricity and provided higher GWP and cumulative energy demand (CED) reduction compared to only using SLB. The LCOE of the SLB-based configurations was sensitive to SLB cost, lifetime, efficiency, and discount rate, whereas the GWP and CED were affected by SLB lifetime, efficiency, and the required enclosure materials. Solar insolation and electricity pricing structures were key in determining the configuration, which was economically and environmentally suitable for a location.

Identifying alternative solvents for C60 manufacturing using singular and combined toxicity assessments.

Linseed oil, olive oil, and sunflower oil were selected based on green chemistry principles and C60 solubility as alternative solvents to replace 1,2,4-trimethylbenzene (TMB) for C60 manufacturing. Singular acute toxicity experiments of C60 and the four solvents was performed using Daphnia magna to identify the solvent with the lowest toxicity and estimate the toxicity of C60. The EC50 for C60 was estimated to be higher than 176 ppm. The toxicity of the solvents increased from sunflower oil to olive oil, linseed oil, and TMB. Combined toxicity tests were conducted to investigate the interaction between C60 and the solvent since essential oils can be nanocarriers and facilitate the transport of C60 into the cell membranes, which would increase its toxicity. Various concentrations of C60 (0, 11, 22, 44, 88, and 176 mg/L) were mixed with solvents at their EC50 concentrations. The toxicity of linseed oil increased with increasing C60 concentrations. For olive and sunflower oil, the toxicity was lowered with low concentrations of C60. Olive oil was determined to be a suitable solvent for C60 manufacturing based on singular and combined toxicity assessments. This study showed the importance of considering combined toxicity for solvent selection.

Anions for Near-Infrared Selective Organic Salt Photovoltaics.

Organic molecular salts are an emerging and highly tunable class of materials for organic and transparent photovoltaics. In this work, we demonstrate novel phenyl borate and carborane-based anions paired with a near-infrared (NIR)-selective heptamethine cation. We further explore the effects of anion structures and functional groups on both device performance and physical properties. Changing the functional groups on the anion significantly alters the open circuit voltage and yields a clear dependence on electron withdrawing groups. Anion exchange is also shown to selectively alter the solubility and film surface energy of the resulting molecular salt, enabling the potential fabrication of solution-deposited cascade or multi-junction devices from orthogonal solvents. This study further expands the catalog and properties of organic salts for inexpensive, and stable NIR-selective molecular salt photovoltaics.

Integrating algaculture into small wastewater treatment plants: process flow options and life cycle impacts.

Algaculture has the potential to be a sustainable option for nutrient removal at wastewater treatment plants. The purpose of this study was to compare the environmental impacts of three likely algaculture integration strategies to a conventional nutrient removal strategy. Process modeling was used to determine life cycle inventory data and a comparative life cycle assessment was used to determine environmental impacts. Treatment scenarios included a base case treatment plant without nutrient removal, a plant with conventional nutrient removal, and three other cases with algal unit processes placed at the head of the plant, in a side stream, and at the end of the plant, respectively. Impact categories included eutrophication, global warming, ecotoxicity, and primary energy demand. Integrating algaculture prior to activated sludge proved to be most beneficial of the scenarios considered for all impact categories; however, this scenario would also require primary sedimentation and impacts of that unit process should be considered for implementation of such a system.

Material and energy intensity of fullerene production.

Fullerenes are increasingly being used in medical, environmental, and electronic applications due to their unique structural and electronic properties. However, the energy and environmental impacts associated with their commercial-scale production have not yet been fully investigated. In this work, the life cycle embodied energy of C(60) and C(70) fullerenes has been quantified from cradle-to-gate, including the relative contributions from synthesis, separation, purification, and functionalization processes, representing a more comprehensive scope than used in previous fullerene life cycle studies. Comparison of two prevalent production methods (plasma and pyrolysis) has shown that pyrolysis of 1,4-tetrahydronaphthalene emerges as the method with the lowest embodied energy (12.7 GJ/kg of C(60)). In comparison, plasma methods require a large amount of electricity, resulting in a factor of 7-10× higher embodied energy in the fullerene product. In many practical applications, fullerenes are required at a purity >98% by weight, which necessitates multiple purification steps and increases embodied energy by at least a factor of 5, depending on the desired purity. For applications such as organic solar cells, the purified fullerenes need to be chemically modified to [6,6]-phenyl-C(61)-butyric acid methyl ester (PCBM), thus increasing the embodied energy to 64.7 GJ/kg C(60)-PCBM for the specified pyrolysis, purification, and functionalization conditions. Such synthesis and processing effects are even more significant for the embodied energy of larger fullerenes, such as C(70), which are produced in smaller quantities and are more difficult to purify. Overall, the inventory analysis shows that the embodied energy of all fullerenes are an order of magnitude higher than most bulk chemicals, and, therefore, traditional cutoff rules by weight during life cycle assessment of fullerene-based products should be avoided.