1.
Chem Commun (Camb)
; (37): 3886-8, 2006 Oct 01.
Article
in English
| MEDLINE
| ID: mdl-17268659
ABSTRACT
The detection of chemical warfare simulants is attained by the PET mechanism that gives an "off-on" fluorescent response with a half-life of approximately 50 ms upon phosphorylation of a reactive oximate functionality; the X-ray crystal structure of the oximate was also obtained and is discussed.
2.
Org Biomol Chem
; 1(12): 2148-51, 2003 Jun 21.
Article
in English
| MEDLINE
| ID: mdl-12945905
ABSTRACT
The reaction of aryl alkynes with dilute methylene chloride solutions of quaternary ammonium bromide and 20% trifluoroacetic acid produces primarily the syn Markovnikov adducts of hydrogen bromide. At moderate concentrations of the bromide, the principal product is the Markovnikov anti adduct. At high concentrations of bromide, the anti-Markovnikov anti addition product predominates.