Your browser doesn't support javascript.
loading
Show: 20 | 50 | 100
Results 1 - 3 de 3
Filter
Add more filters










Database
Language
Publication year range
1.
J Mater Chem B ; 12(28): 6840-6846, 2024 Jul 17.
Article in English | MEDLINE | ID: mdl-38913346

ABSTRACT

Organic luminescent radicals are a new class of materials with potential applications not only in light-emitting devices but also in the biochemistry field. New tris(2,4,6-trichlorophenyl)methyl (TTM) radicals with alkoxy-substituted carbazole donors were synthesized and characterized. PEG-substituted carbazole-TTM was found to be water-soluble. The water-soluble TTM radical aqueous solution showed fluorescence at 777 nm and the ability to shorten the longitudinal relaxation time (T1) of water. The concept of water-soluble luminescent radicals is expected to be used to develop a potential fluorescence and MR dual-use imaging moiety.


Subject(s)
Carbazoles , Solubility , Water , Carbazoles/chemistry , Carbazoles/chemical synthesis , Water/chemistry , Free Radicals/chemistry , Luminescence , Molecular Structure , Luminescent Agents/chemistry , Luminescent Agents/chemical synthesis
2.
Faraday Discuss ; 250(0): 192-201, 2024 Mar 11.
Article in English | MEDLINE | ID: mdl-37966049

ABSTRACT

A series of halogen-substitute carbazole TTM radicals was synthesized. The effect of halogen substituents on radical luminescence was systematically evaluated. It was found that the well-known heavy atom effect does not work in the emission of radicals and that halogen substitution of the donor carbazole can change the HOMO and alter the absorption and emission wavelengths. In addition, the photostability was found to be improved with respect to TTM but not significantly different from that of closed-shell fluorescent molecules.

3.
Chem Commun (Camb) ; 58(97): 13443-13446, 2022 Dec 06.
Article in English | MEDLINE | ID: mdl-36373670

ABSTRACT

Stable organic luminescent radicals have attracted much attention, but their stability under light irradiation is not yet satisfactory. New luminescent radicals (TTMs) based on terminal benzene ring modified carbazole donors were synthesized and evaluated. Their photostability (half-life under continuous laser irradiation) has improved by 1 order of magnitude compared to simple carbazole donors. This is a new molecular design strategy to improve the photostability of luminescent radicals without reducing other photophysical properties.

SELECTION OF CITATIONS
SEARCH DETAIL
...