ABSTRACT
Crop destruction organisms are an essential factor hindering cocoa plants' production yield. It is the biggest problem for cocoa farmers to resolve and reduce the impact of the P. palmivora fungus on cocoa pods. Herein, this study presents the optimization of inorganic pesticides based on nano-carbon self-doped TiO2 (C/TiO2) nanocomposites capable of disinfecting broad-spectrum P. palmivora microorganisms for the practical application of photodisinfection technology. C/TiO2 nanocomposite-based inorganic pesticide has been prepared by sol-gel method to produce nanospray and planted in media containing P. palmivora fungus. To identify the various composition of the C/TiO2 nanospray, they were evaluated by FTIR spectroscopy to observe the functional groups of the nano-carbon and TiO2, which clearly contained -OH (3446-3448 cm-1), C≡C (2366-2370 cm-1), C=O (1797-1799 cm-1), C-H (1425 cm-1), C-O (1163-1203 cm-1), C-H (875-877 cm-1), and Ti-O (875-877 cm-1) groups. Some researchers have reported that nano-carbon significantly changes the band gap energy of TiO2 under visible light and can also be active under dark conditions. This statement is relevant to our experimental results that 0.3% C/TiO2 nanocomposites can inhibit the fungus P. palmivora with a percentage inhibition value of 72.7%. However, the high-performance efficiency proved strong when subjected to visible light irradiation with an inhibition value of 98.6%. Our results indicate that C/TiO2 nanocomposites have great potential in agricultural plant pathogen disinfection. Supplementary Information: The online version contains supplementary material available at 10.1007/s12088-023-01076-7.
ABSTRACT
Research on the transformation of Oil Palm Empty Fruit Bunches (OPEFB) through pretreatment process using ionic liquid triethylammonium hydrogen sulphate (IL [TEA][HSO4]) was completed. The stages of the transformation process carried out were the synthesis of IL with the one-spot method, optimization of IL composition and pretreatment temperature, and IL recovery. The success of the IL synthesis stage was analyzed by FTIR, H-NMR and TGA. Based on the results obtained, it showed that IL [TEA][HSO4] was successfully synthesized. This was indicated by the presence of IR absorption at 1/λ = 2814.97 cm-1, 1401.07 cm-1, 1233.30 cm-1 and 847.92 cm-1 which were functional groups for NH, CH3, CN and SO2, respectively. These results were supported by H-NMR data at δ (ppm) = 1.217-1.236 (N-CH2-CH3), 3.005-3.023 (-H), 3.427-3.445 (N-H+) and 3.867 (N+H3). The TGA results showed that the melting point and decomposition temperature of the IL were 49 °C and 274.3 °C, respectively. Based on pretreatment optimization, it showed that the best IL composition for cellulose production was 85 wt%. Meanwhile, temperature optimization showed that the best temperature was 120 °C. In these two optimum conditions, the cellulose content was obtained at 45.84 wt%. Testing of IL [TEA][HSO4] recovery performance for reuse has shown promising results. During the pretreatment process, IL [TEA][HSO4] recovery effectively increased the cellulose content of OPEFB to 29.13 wt% and decreased the lignin content to 32.57%. The success of the recovery process is indicated by the increasing density properties of IL [TEA][HSO4]. This increase occurs when using a temperature of 80-100 °C. The overall conditions obtained from this work suggest that IL [TEA][HSO4] was effective during the transformation process of OPEFB into cellulose. This shows the potential of IL [TEA][HSO4] in the future in the renewable energy sector.
