Drop splashing after impact onto immiscible pools of different viscosities.

Droplet impact onto liquid pools is a canonical scenario relevant to numerous natural phenomena and industrial processes. However, despite their ubiquity, multi-fluid systems with the drop and pool consisting of different liquids are far less well understood. Our hypothesis is that the post-impact dynamics greatly depends on the pool-to-droplet viscosity ratioµp/µd, which we explore over a range of six orders of magnitude using a combination of experiments and theoretical approaches (mathematical modelling and direct numerical simulation). Our findings indicate that in this scenario the splashing threshold and the composition of the ejecta sheet are controlled by the viscosity ratio. We uncover that increasing the pool viscosity decreases the splashing threshold for high viscosity pools (µp/µd≳35) when the splash comes from the droplet. By contrast, for low viscosity pools, the splash sheet comes from the pool and increasing the pool viscosity increases the splashing threshold. Surprisingly, there are conditions for which no splashing is observed under the conditions attainable in our laboratory. Furthermore, considering the interface velocity together with asymptotic arguments underlying the generation of the ejecta has allowed us to understand meaningful variations in the pressure during impact and rationalise the observed changes in the splashing threshold.

Acoustic Sensing of Forces Driving Fast Capillary Flows.

The popping sound of a bursting soap bubble is acquired using microphone arrays and analyzed using spherical harmonics decomposition. Using the theoretical framework of aeroacoustics, we demonstrate that this acoustic emission originates mainly from the capillary stresses exerted by the liquid soap film on the air and that it quantitatively reflects the out-of-equilibrium evolution of the flowing liquid film. This constitutes the proof of concept that the acoustic signature of violent events of physical or biological origin could be used to measure the forces at play during these events.

Shape of a recoiling liquid filament.

We study the capillary retraction of a Newtonian semi-infinite liquid filament through analytical methods. We derive a long-time asymptotic-state expansion for the filament profile using a one-dimensional free-surface slender cylindrical flow model based on the three-dimensional axisymmetric Navier-Stokes equations. The analysis identifies three distinct length and time scale regions in the retraction domain: a steady filament section, a growing spherical blob, and an intermediate matching zone. We show that liquid filaments naturally develop travelling capillary waves along their surface and a neck behind the blob. We analytically prove that the wavelength of the capillary waves is approximately 3.63 times the filament's radius at the inviscid limit. Additionally, the waves' asymptotic wavelength, decay length, and the minimum neck size are analysed in terms of the Ohnesorge number. Finally, our findings are compared with previous results from the literature and numerical simulations in Basilisk obtaining a good agreement. This analysis provides a full picture of the recoiling process going beyond the classic result of the velocity of retraction found by Taylor and Culick.

Extraction of Silicone Uncrosslinked Chains at Air-Water-Polydimethylsiloxane Triple Lines.

Silicone elastomers such as polydimethylsiloxane (PDMS) are convenient materials routinely used in laboratories that combine ease of preparation, flexibility, transparency, and gas permeability. However, these elastomers are known to contain a small fraction of uncrosslinked low-molecular-weight oligomers, the effects of which are not completely understood, particularly when used in contact with liquids. Here, we show that triple lines involving air, water, and PDMS elastomers are responsible for the contamination of water-air interfaces by uncrosslinked silicone oligomers through a capillarity-induced extraction mechanism. We investigate both the case of static and moving contact lines and study various geometries ranging from partially immersed PDMS plates to water droplets or air bubbles deposited on PDMS plates, all involving air-water-elastomer triple lines. We demonstrate experimentally that the contamination timescale is strikingly shorter for moving contact lines than in the static case. Eventually, we propose a simple poroelastic model capturing the main features of contamination observed in experiments.

Capillarity-induced folds fuel extreme shape changes in thin wicked membranes.

Soft deformable materials are needed for applications such as stretchable electronics, smart textiles, or soft biomedical devices. However, the design of a durable, cost-effective, or biologically compatible version of such a material remains challenging. Living animal cells routinely cope with extreme deformations by unfolding preformed membrane reservoirs available in the form of microvilli or membrane folds. We synthetically mimicked this behavior by creating nanofibrous liquid-infused tissues that spontaneously form similar reservoirs through capillarity-induced folding. By understanding the physics of membrane buckling within the liquid film, we developed proof-of-concept conformable chemical surface treatments and stretchable basic electronic circuits.

Auxiliary soft beam for the amplification of the elasto-capillary coiling: Towards stretchable electronics.

A flexible fiber carrying a liquid drop may coil inside the drop thereby creating a drop-on-fiber system with an ultra-extensible behavior. During compression, the excess fiber is spooled inside the droplet and capillary forces keep the system taut. During subsequent elongation, the fiber is gradually released and if a large number of spools is uncoiled a high stretchability is achieved. This mechanical behaviour is of interest for stretchable connectors but information, may it be electronic or photonic, usually travels through stiff functional materials. These high Young's moduli, leading to large bending rigidity, prevent in-drop coiling. Here we overcome this limitation by attaching a beam of soft elastomer to the functional fiber, thereby creating a composite system which exhibits in-drop coiling and carries information while being ultra-extensible. We present a simple model to explain the underlying mechanics of the addition of the soft beam and we show how it favors in-drop coiling. We illustrate the method with a two-centimeter long micronic PEDOT:PSS conductive fiber joined to a PVS soft beam, showing that the system conveys electricity throughout a 1900% elongation.

Drop-on-coilable-fibre systems exhibit negative stiffness events and transitions in coiling morphology.

We investigate the mechanics of elastic fibres carrying liquid droplets. In such systems, buckling may localize inside the drop cavity if the fibre is thin enough. This so-called drop-on-coilable-fibre system exhibits a surprising liquid-like response under compression and a solid-like response under tension. Here we analyze this unconventional behavior in further detail and find theoretical, numerical and experimental evidence of negative stiffness events. We find that the first and main negative stiffness regime owes its existence to the transfer of capillary-stored energy into mechanical curvature energy. The following negative stiffness events are associated with changes in the coiling morphology of the fibre. Eventually coiling becomes tightly locked into an ordered phase where liquid and solid deformations coexist.

Role of uncrosslinked chains in droplets dynamics on silicone elastomers.

We report an unexpected behavior in wetting dynamics on soft silicone substrates: the dynamics of aqueous droplets deposited on vertical plates of such elastomers exhibits two successive speed regimes. This macroscopic observation is found to be closely related to microscopic phenomena occurring at the scale of the polymer network: we show that uncrosslinked chains found in most widely used commercial silicone elastomers are responsible for this surprising behavior. A direct visualization of the uncrosslinked oligomers collected by water droplets is performed, evidencing that a capillarity-induced phase separation occurs: uncrosslinked oligomers are extracted from the silicone elastomer network by the water-glycerol mixture droplet. The sharp speed change is shown to coincide with an abrupt transition in surface tension of the droplets, when a critical surface concentration in uncrosslinked oligomer chains is reached. We infer that a droplet shifts to a second regime with a faster speed when it is completely covered with a homogeneous oil film.

It's Harder to Splash on Soft Solids.

Droplets splash when they impact dry, flat substrates above a critical velocity that depends on parameters such as droplet size, viscosity, and air pressure. By imaging ethanol drops impacting silicone gels of different stiffnesses, we show that substrate stiffness also affects the splashing threshold. Splashing is reduced or even eliminated: droplets on the softest substrates need over 70% more kinetic energy to splash than they do on rigid substrates. We show that this is due to energy losses caused by deformations of soft substrates during the first few microseconds of impact. We find that solids with Young's moduli ≲100 kPa reduce splashing, in agreement with simple scaling arguments. Thus, materials like soft gels and elastomers can be used as simple coatings for effective splash prevention. Soft substrates also serve as a useful system for testing splash-formation theories and sheet-ejection mechanisms, as they allow the characteristics of ejection sheets to be controlled independently of the bulk impact dynamics of droplets.

In-drop capillary spooling of spider capture thread inspires hybrid fibers with mixed solid-liquid mechanical properties.

An essential element in the web-trap architecture, the capture silk spun by ecribellate orb spiders consists of glue droplets sitting astride a silk filament. Mechanically this thread presents a mixed solid-liquid behavior unknown to date. Under extension, capture silk behaves as a particularly stretchy solid, owing to its molecular nanosprings, but it totally switches behavior in compression to now become liquid-like: It shrinks with no apparent limit while exerting a constant tension. Here, we unravel the physics underpinning the unique behavior of this "liquid wire" and demonstrate that its mechanical response originates in the shape-switching of the silk filament induced by buckling within the droplets. Learning from this natural example of geometry and mechanics, we manufactured programmable liquid wires that present previously unidentified pathways for the design of new hybrid solid-liquid materials.

Evaporation of droplets in a Champagne wine aerosol.

In a single glass of champagne about a million bubbles nucleate on the wall and rise towards the surface. When these bubbles reach the surface and rupture, they project a multitude of tiny droplets in the form of a particular aerosol holding a concentrate of wine aromas. Based on the model experiment of a single bubble bursting in idealized champagnes, the key features of the champagne aerosol are identified. In particular, we show that film drops, critical in sea spray for example, are here nonexistent. We then demonstrate that compared to a still wine, champagne fizz drastically enhances the transfer of liquid into the atmosphere. There, conditions on bubble radius and wine viscosity that optimize aerosol evaporation are provided. These results pave the way towards the fine tuning of flavor release during sparkling wine tasting, a major issue for the sparkling wine industry.

Adhesion of dry and wet electrostatic capture silk of uloborid spider.

We demonstrate the impressive adhesive qualities of uloborid spider orb-web capture when dry, which are lost when the nano-filament threads are wetted. A force sensor with a 50 nN-1 mN detection sensitively allowed us to measure quantitatively the stress-strain characteristics of native silk threads in both the original dry state and after wetting by controlled application of water mist with droplet sizes ranging between 3 and 5 µm and densities ranging between 10(4) and 10(5) per mm(3). Stress forces of between 1 and 5 µN/µm(2) in the native, dry multifilament thread puffs were reduced to between 0.1 and 0.5 µN/µm(2) in the wetted collapsed state, with strain displacements reducing from between 2 and 5 mm in the dry to 0.10-0.12 mm in the wetted states. We conclude that wetting cribellate threads reduce their van der Waals adhesion with implications on the thread's adhesive strength under tension. This should be considered when discussing the evolutionary transitions of capture silks from the ancestral dry-state nano-filaments of the cribellate spider taxa to the wet-state glue-droplets of the ecribellate taxa.

Elastocapillary snapping: capillarity induces snap-through instabilities in small elastic beams.

We report on the capillarity-induced snapping of elastic beams. We show that a millimeter-sized water drop gently deposited on a thin buckled polymer strip may trigger an elastocapillary snap-through instability. We investigate experimentally and theoretically the statics and dynamics of this phenomenon and we further demonstrate that snapping can act against gravity, or be induced by soap bubbles on centimeter-sized thin metal strips. We argue that this phenomenon is suitable to miniaturization and design a condensation-induced spin-off version of the experiment involving a hydrophilic strip placed in a steam flow.

Large bubble rupture sparks fast liquid jet.

This Letter presents the novel experimental observation of long and narrow jets shooting out in disconnecting large elongated bubbles. We investigate this phenomenon by carrying out experiments with various viscosities, surface tensions, densities and nozzle radii. We propose a universal scaling law for the jet velocity, which unexpectedly involves the bubble height to the power 3/2. This anomalous exponent suggests an energy focusing phenomenon. We demonstrate experimentally that this focusing is purely gravity driven and independent of the pinch-off singularity.

Instant fabrication and selection of folded structures using drop impact.

A drop impacting a target cutout in a thin polymer film is wrapped by the film in a dynamic sequence involving both capillary forces and inertia. Different 3D structures can be produced from a given target by slightly varying the impact parameters. A simplified model for a nonlinear dynamic Elastica coupled with a drop successfully explains this shape selection and yields detailed quantitative agreement with experiments. This first venture into the largely unexplored dynamics of elastocapillary assemblies opens up the perspective of mass production of 3D packages with individual shape selection.