Bath-induced interactions and transient dynamics in open quantum systems at strong coupling: Effective Hamiltonian approach.

Understanding the dynamics of dissipative quantum systems, particularly beyond the weak coupling approximation, is central to various quantum applications. While numerically exact methods provide accurate solutions, they often lack the analytical insight provided by theoretical approaches. In this study, we employ the recently developed method dubbed the effective Hamiltonian theory to understand the dynamics of system-bath configurations without resorting to a perturbative description of the system-bath coupling energy. Through a combination of mapping steps and truncation, the effective Hamiltonian theory offers both analytical insights into signatures of strong couplings in open quantum systems and a straightforward path for numerical simulations. To validate the accuracy of the method, we apply it to two canonical models: a single spin immersed in a bosonic bath and two noninteracting spins in a common bath. In both cases, we study the transient regime and the steady state limit at nonzero temperature and spanning system-bath interactions from the weak to the strong regime. By comparing the results of the effective Hamiltonian theory with numerically exact simulations, we show that although the former overlooks non-Markovian features in the transient equilibration dynamics, it correctly captures non-perturbative bath-generated couplings between otherwise non-interacting spins, as observed in their synchronization dynamics and correlations. Altogether, the effective Hamiltonian theory offers a powerful approach for understanding strong coupling dynamics and thermodynamics, capturing the signatures of such interactions in both relaxation dynamics and in the steady state limit.

Hyperacceleration of quantum thermalization dynamics by bypassing long-lived coherences: An analytical treatment.

We develop a perturbative technique for solving Markovian quantum dissipative dynamics, with the perturbation parameter being a small gap in the eigenspectrum. As an example, we apply the technique and straightforwardly obtain analytically the dynamics of a three-level system with quasidegenerate excited states, where quantum coherences persist for very long times, proportional to the inverse of the energy splitting squared. We then show how to bypass this long-lived coherent dynamics and accelerate the relaxation to thermal equilibration in a hyper-exponential manner, a Markovian quantum-assisted Mpemba-like effect. This hyperacceleration of the equilibration process manifests if the initial state is carefully prepared, such that its coherences precisely store the amount of population relaxing from the initial condition to the equilibrium state. Our analytical method for solving quantum dissipative dynamics readily provides equilibration timescales, and as such it reveals how coherent and incoherent effects interlace in the dynamics. It further advises on how to accelerate relaxation processes, which is desirable when long-lived quantum coherences stagnate dynamics.

Quantum thermal transport beyond second order with the reaction coordinate mapping.

Standard quantum master equation techniques, such as the Redfield or Lindblad equations, are perturbative to second order in the microscopic system-reservoir coupling parameter λ. As a result, the characteristics of dissipative systems, which are beyond second order in λ, are not captured by such tools. Moreover, if the leading order in the studied effect is higher-than-quadratic in λ, a second-order description fundamentally fails even at weak coupling. Here, using the reaction coordinate (RC) quantum master equation framework, we are able to investigate and classify higher-than-second-order transport mechanisms. This technique, which relies on the redefinition of the system-environment boundary, allows for the effects of system-bath coupling to be included to high orders. We study steady-state heat current beyond second-order in two models: The generalized spin-boson model with non-commuting system-bath operators and a three-level ladder system. In the latter model, heat enters in one transition and is extracted from a different one. Crucially, we identify two transport pathways: (i) System's current, where heat conduction is mediated by transitions in the system, with the heat current scaling as jq ∝ λ2 to the lowest order in λ. (ii) Inter-bath current, with the thermal baths directly exchanging energy between them, facilitated by the bridging quantum system. To the lowest order in λ, this current scales as jq ∝ λ4. These mechanisms are uncovered and examined using numerical and analytical tools. We contend that the RC mapping brings, already at the level of the mapped Hamiltonian, much insight into transport characteristics.

Strong system-bath coupling effects in quantum absorption refrigerators.

We study the performance of three-level quantum absorption refrigerators, paradigmatic autonomous quantum thermal machines, and reveal central impacts of strong couplings between the working system and the thermal baths. Using the reaction coordinate quantum master equation method, which treats system-bath interactions beyond weak coupling, we demonstrate that in a broad range of parameters the cooling window at strong coupling can be captured by a weak-coupling theory, albeit with parameters renormalized by the system-bath coupling energy. As a result, at strong system-bath couplings the window of cooling is significantly reshaped compared to predictions of weak-coupling treatments. We further show that strong coupling admits direct transport pathways between the thermal reservoirs. Such beyond-second-order transport mechanisms are typically detrimental to the performance of quantum thermal machines. Our study reveals that it is inadequate to claim for either a suppression or an enhancement of the cooling performance as one increases system-bath coupling-when analyzed against a single parameter and in a limited domain. Rather, a comprehensive approach should be adopted so as to uncover the reshaping of the operational window.