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One-Step Conversion of Potassium Organotrifluoroborates to Metal Organoborohydrides.
Bateman, Christopher M; Beal, Hailey; Barker, Joshua E; Thompson, Brena L; Donovan, Drake; Grant, Bradley J; Shooter, Jesse; Arakawa, Jordan H; Johnson, Spencer; Allen, Caleb J; Yates, James L; Kato, Ryota; Tinsley, Colby W K; Zakharov, Lev N; Abbey, Eric R.
Org Lett ; 20(13): 3784-3787, 2018 07 06.
Article in English | MEDLINE | ID: mdl-29944380

ABSTRACT

This letter describes the one-step conversion of heteroatom-substituted potassium organotrifluoroborates (KRBF3) to metal monoorganoborohydrides (MRBH3) using alkali metal aluminum hydrides. The method tolerates a variety of functional groups, expanding MRBH3 diversity. Hydride removal with Me3SiCl in the presence of dimethylaminopyridine (DMAP) affords the organoborane·DMAP (RBH2·DMAP) adducts.

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