1.
Acta Crystallogr Sect E Struct Rep Online
; 70(Pt 8): m301-2, 2014 Aug 01.
Article
in English
| MEDLINE
| ID: mdl-25249883
ABSTRACT
In the title compound, [CdCl2(C13H12N4S)]·CH3OH, the coord-ination geometry of the Cd(II) ion is slightly distorted square-pyramidal, as indicated by the τ index of 0.36â (8). The S atom, two N atoms from the pyridyl-azomethine moiety and one of the Cl atoms comprise the basal plane, while the other Cl atom occupies the apical position. The hydrazinecarbo-thio-amide moiety adopts an E conformation with respect to the azomethine bond. The solvate mol-ecule in the crystal lattice plays a major role in inter-connecting adjacent mol-ecules by means of O-Hâ¯Cl and N-Hâ¯O hydrogen-bonding inter-actions. A supra-molecular three-dimensional architecture is sustained in terms of further N-Hâ¯Cl and C-Hâ¯Cl hydrogen-bonding inter-actions.