Using the Radial Shear Rolling Method for Fast and Deep Processing Technology of a Steel Ingot Cast Structure.

In advancing special materials, seamless integration into existing production chains is paramount. Beyond creating improved alloy compositions, precision in processing methods is crucial to preserve desired properties without drawbacks. The synergy between alloy formulation and processing techniques is pivotal for maximizing the benefits of innovative materials. By focusing on advanced deep processing technology for small ingots of modified 12% Cr stainless steel, this paper delves into the transformation of cast ingot steel structures using radial shear rolling (RSR) processing. Through a series of nine passes, rolling ingots from a 32 mm to a 13 mm diameter with a total elongation factor of 6.02, a notable shift occurred. This single-operation process effectuated a substantial change in sample structure, transitioning from a coarse-grained cast structure (0.5-1.5 mm) to an equiaxed fine-grained structure with peripheral grain sizes of 1-4 µm and an elongated rolling texture in the axial part of the bar. The complete transformation of the initial cast dendritic structure validates the implementation of the RSR method for the deep processing of ingots.

Modeling of Closure of Metallurgical Discontinuities in the Process of Forging Zirconium Alloy.

This article presents the results of testing the conditions of closing foundry voids during the hot forging operation of an ingot made of zirconium with 1% Nb alloy and use of physical and numerical modeling, continuing research presented in a previous thematically related article published in the journal Materials. The study of the impact of forging operation parameters on the rheology of zirconium with 1% Nb alloy was carried out on a Gleeble 3800 device. Using the commercial FORGE®NxT 2.1 program, a numerical analysis was performed of the influence of thermo-mechanical parameters of the hot elongation operation in trapezoidal flat and rhombic trapezoidal anvils on the closure of foundry voids. The analysis of the obtained test results was used to formulate recommendations on the technology of hot forging and the anvilgeometry, ensuring closure of foundry voids. Based on their research, the authors conclude that the shape of the deformation basin and the value and hydrostatic pressure have the greatest influences on the closure of foundry voids.

The Effect of Radial-Shear Rolling Deformation Processing on the Structure and Properties of Zr-2.5Nb Alloy.

The rheological properties of the Zr-2.5Nb alloy by the strain rate range of 0.5-15 s-1 and by the temperature range of 20-770 °C was studied. The dilatometric method for phase states temperature ranges was experimentally determined. A material properties database for computer FEM simulation regards the indicated temperature-velocity ranges were created. Using this database and DEFORM-3D FEM-softpack, the radial shear rolling complex process numerical simulation was carried out. The contributed conditions for the ultrafine-grained state alloy structure refinement were determined. Based on the simulation results, a full-scale experiment of Zr-2.5Nb rod rolling a on a radial-shear rolling mill RSP-14/40 was carried out. It takes in seven passes from a diameter of 37-20 mm with a total diameter reduction ε = 85%. According to this case simulation data, the total equivalent strain in the most processed peripheral zone 27.5 mm/mm was reached. Due to the complex vortex metal flow, the equivalent strain over the section distribution was uneven with a gradient reducing towards the axial zone. This fact should have a deep effect on the structure change. Changes and structure gradient by sample section EBSD mapping with 2 mm resolution were studied. The microhardness section gradient by the HV 0.5 method was also studied. The axial and central zones of the sample by the TEM method were studied. The rod section structure has an expressed gradient from the formed equiaxed ultrafine-grained (UFG) structure on a few outer millimeters of the peripheral section to the elongated rolling texture in the center of the bar. The work shows the possibility of processing with the gradient structure obtaining and enhanced properties for the Zr-2.5Nb alloy, and a database for this alloy FEM numerical simulations are also presents.

Investigation of the Influence of Hot Forging Parameters on the Closing Conditions of Internal Metallurgical Defects in Zirconium Alloy Ingots.

In this article, we present research results on the closing conditions of internal metallurgical discontinuities during the hot elongation operation of a Zr-1%Nb alloy ingot using physical and numerical modeling. Research on the influence of thermal and deformation parameters of elongation operations on the rheological behavior of a Zr-1% Nb alloy was conducted using the Gleeble 3800 metallurgical process simulator. Modeling of the influence of thermal-mechanical parameters of hot elongation operations in combinations of rhombic and flat anvils on the closure of metallurgical discontinuities was performed with the help of the FORGE®NxT 2.1 program. Based on the results of the research, recommendations were made regarding forging elongation technology and the geometry of working tools in order to ensure the closure of metallurgical discontinuities during hot elongation operations of Zr-1% Nb alloy ingots.

Obtaining an Equiaxed Ultrafine-Grained State of the Longlength Bulk Zirconium Alloy Bars by Extralarge Shear Deformations with a Vortex Metal Flow.

The method of radial shear rolling makes it possible to achieve comparable to high pressure torsion (HPT) method ultrahigh degrees of total strain level in combination with the vortex metal flow character for long-length large bulk bars unable by HPT and many other processes of sever plastic deformation (SPD). Sequential rolling of the Zr-1%Nb alloy was carried out under extreme conditions on two radial shear rolling mills with a total diameter reduction ε = 185% and a maximum total strain level = 46 mm/mm. The strain level and its cross-section distribution assessment by finite element method (FEM) simulation was studied. The final bar cross-section structure type distribution detailed study 1 mm resolution by electron back scatter diffraction (EBSD) mapping was performed. A gradient structure with a predominance of the equiaxed ultrafine-grained (UFG) state was found. The deformation level rising did not allow to refine it in the periphery zone more than that obtained nearly middle of the processing, but it allows for significant change in the axial zone structure. The additional large warm deformations by radial shear rolling have no additional grain refinement effect for already 300-600 nm refined zone. An equiaxed UFG structure was obtained in a relatively large volume of the sample with a reduced gradient towards the non-UFG center zone in regard to known works.

Unraveling Device Physics of Dilute-Donor Narrow-Bandgap Organic Solar Cells with Highly Transparent Active Layers.

The charge generation-recombination dynamics in three narrow-bandgap near-IR absorbing nonfullerene (NFA) based organic photovoltaic (OPV) systems with varied donor concentrations of 40%, 30%, and 20% are investigated. The dilution of the polymer donor with visible-range absorption leads to highly transparent active layers with blend average visible transmittance (AVT) values of 64%, 70%, and 77%, respectively. Opaque devices in the optimized highly reproducible device configuration comprising these transparent active layers lead to photoconversion efficiencies (PCEs) of 7.0%, 6.5%, and 4.1%. The investigation of these structures yields quantitative insights into changes in the charge generation, non-geminate charge recombination, and extraction dynamics upon dilution of the donor. Lastly, this study gives an outlook for employing the highly transparent active layers in semitransparent organic photovoltaics (ST-OPVs).

Development of Alternative Method for Manufacturing Structural Zirconium Elements for Nuclear Engineering.

Zirconium is used as a structural material for use in aggressive environments, including the core of nuclear reactors. The traditional technology of manufacturing the structural elements of zirconium nuclear reactors is characterized by a long technological process and a significant amount of waste in the form of metal shavings. The paper presents the results of an alternative technology, spark plasma sintering, for manufacturing zirconium products. A complex of microstructural and mechanical studies of the obtained samples was carried out according to the ASTMB-351 standard. The sintering of zirconium powder and options for subsequent processing by various methods, including non-standard ones such as radial shear rolling, are justified.

How gap distance between gold nanoparticles in dimers and trimers on metallic and non-metallic SERS substrates can impact signal enhancement.

The impact of variation in the interparticle gaps in dimers and trimers of gold nanoparticles (AuNPs), modified with Raman reporter (2-MOTP), on surface-enhanced Raman scattering (SERS) intensity, relative to the SERS intensity of a single AuNP, is investigated in this paper. The dimers, trimers, and single particles are investigated on the surfaces of four substrates: gold (Au), aluminium (Al), silver (Ag) film, and silicon (Si) wafer. The interparticle distance between AuNPs was tuned by selecting mercaptocarboxylic acids of various carbon chain lengths when each acid forms a mixed SAM with 2-MOTP. The SERS signal quantification was accomplished by combining maps of SERS intensity from a Raman microscope, optical microscope images (×100), and maps/images from AFM or SEM. In total, we analysed 1224 SERS nanoantennas (533 dimers, 648 monomers, and 43 trimers). The average interparticle gaps were measured using TEM. We observed inverse exponential trends for the Raman intensity ratio and enhancement factor ratio versus gap distance on all substrates. Gold substrate, followed by silicon, showed the highest Raman intensity ratio (9) and dimer vs. monomer enhancement factor ratio (up to 4.5), in addition to the steepest inverse exponential curve. The results may help find a balance between SERS signal reproducibility and signal intensity that would be beneficial for future agglomerated NPs in SERS measurements. The developed method of 3 to 1 map combination by an increase in image transparency can be used to study structure-activity relationships on various substrates in situ, and it can be applied beyond SERS microscopy.

Using of Radial-Shear Rolling to Improve the Structure and Radiation Resistance of Zirconium-Based Alloys.

An overview of the prospects for the development of nuclear technologies and the conclusion of the relevant requirements for advanced structural materials, their classification and features were performed. In order to obtain a bar with a modified radiation-resistant outer layer, an experiment of radial-shear rolling under the most stringent conditions was carried out. For the same conditions, a FEM-simulation of sequential rolling in eight passes with a total compression of 70.7% (from a diameter of 37 mm to 20 mm) was conducted. For adequate simulation results a new material database for Zr-1%Nb alloy using plastometry investigations was generated. An experimental obtaining of a gradient-modified structure with an ultrafine-grained (UFG) periphery and an elongated rolling texture in the center of the bar was performed.