Fractionation of heavy metals in sediments and assessment of their availability risk: A case study in the northwestern of Persian Gulf.

Sequential extraction procedure was applied to determine the chemical forms of heavy metals in sediments in order to assess their mobility and availability in the aquatic environment. The mean concentrations of Cr, Ni, Pb, Cd, Cu and Zn in exchangeable and carbonate fractions were 14.9, 30.9, 17, 0.37, 4.4 and 14.4mg/kg, respectively. Based on the sediments quality guidelines (SQGs), the adverse biological effects caused by Ni, can occur frequently across the study area. Risk assessment code (RAC) suggested that the Cd has the highest level of environmental risk compared with other studied metals. Modified risk assessment code (mRAC) demonstrated a high potential adverse effect in the many of sampling sites. According to the fractionation results, the concentration of Ni in exchangeable and carbonate fractions was very considerable and more than other metals, hence, the potential risk of nickel release can be much more than other investigated metals.

Management of unregulated agricultural nonpoint sources through water quality trading market.

Water quality trading (WQT) could be an innovative policy to incentivize farmers to implement best management practices (BMPs) for their activities. This study focused on assessment of involving unregulated agricultural nonpoint sources (NPS) into the WQT market in Gharesoo watershed in the west of Iran. It also proposes a methodology to determine location-based trading ratios as well as environmental penalty cost to achieve a more well-designed market structure. Trading activities in different scenarios were described by trading volume (TV), participation rate (PR), total exchanged value (TEV), and other market parameters in order to achieve a better comparison of market performance. Results showed that, by applying NPS to the Gharesoo watershed, total phosphorous (TP) trading market could increase TV, PR, and TEV up to 11, 1.7 and 7.5 times, respectively, depending on which level of BMPs are implemented by them. Additionally, it could save 29% of the total cost of implementing a TP total maximum daily load in this watershed compared to the 'command and control' approach. Furthermore, the agricultural sector could profit by $5.49 million (or $75/ha) by choosing solutions such as terrace systems and filter strips to register into the market. This profit can be allocated to the development of new agricultural technologies.

Soil washing of chromium- and cadmium-contaminated sludge using acids and ethylenediaminetetra acetic acid chelating agent.

In this research, the effect of soil washing in the removal of chromium- and cadmium-contaminated sludge samples collected from Pond 2 of the Tehran Oil Refinery was investigated. These metals are considered as hazardous substances for human health and the environment. The carcinogenicity of chromate dust has been established for a long time. Cadmium is also a potential environmental toxicant. This study was carried out by collecting sludge samples from different locations in Pond 2. Soil washing was conducted to treat the samples. Chemical agents, such as acetic acid, ethylenediaminetetra acetic acid (EDTA) and hydrochloric acid, were used as washing solutions to remove chromium and cadmium from sludge samples. The results of this study indicated that the highest removal efficiencies from the sludge samples were achieved using a 0.3 M HCl solution with 82.69% and 74.47% for chromium and cadmium, respectively. EDTA (0.1 M) in the best condition extracted 66.81% of cadmium and 72.52% of chromium from the sludges. The lowest efficiency values for the samples, however, were achieved using 3 M acetic acid with 41.7% and 46.96% removals for cadmium and chromium, respectively. The analysis of washed sludge indicated that the heavy metals removal decreased in the order of 3 M acetic acid < 0.1 M EDTA<0.3 M HCl, thus hydrochloric acid appears to offer a greater potential as a washing agent in remediating the sludge samples.

Surface water quality management using an integrated discharge permit and the reclaimed water market.

Water quality trading is a sustainable framework for surface water quality management. It uses discharge permits to reduce the total treatment costs. For example, the case of Gharesoo River in Iran shows that the nitrogen permit market between point and non-point sources is 37% more economical than the command and control framework. Nevertheless, the cost saving may be reduced to 6% by the end of the study period (2050). This depression may be due to the limited technical support for wastewater treatment plants. Therefore, an integrated market is recommended in which the discharge permits and the reclaimed water are traded simultaneously. In this framework, the allocation of secondary treated domestic wastewater for irrigation can provide capacity for other pollutants to discharge into the surface water. This innovative approach may decrease the total treatment costs by 63% at present, while 65%, may be achieved by the end of the study period. Furthermore, this market is able to determine the environmental penalty, trading permits, and reuse prices. For example, the maximum ratio of the average reuse price to the penalty cost is determined as 1 to 10. It is introduced as an incentive indicator for stakeholders to consider the integrated market. Consequently, the applicability and the efficiency of using this approach are verified long term.

Investigation of trihalomethanes formation potential in Karoon River water, Iran.

Organic matters in raw water have a potential to generate harmful disinfection by-products such as trihalomethanes (THMs) during the chlorination process. The objectives of this study were to investigate the trihalomethane formation potential (THMFP) in Karoon River water and to determine the effect of several factors including total organic carbon (TOC), pH, chlorine dosage, water temperature, and seasonal variation. The results showed that, among all factors, TOC and water temperature have a remarkable effect on THMFP. The experimental results from batch studies indicated that increasing of pH value yielded a greater THMFP concentration for Karoon River water. THMFP levels of Karoon River water in summer times, when water temperature exceeded 26°C, were 1.2-1.6 times higher than in the spring and fall seasons, when water temperature was below 15°C. It was found that the measured THMFP at Karoon River water in the spring and fall seasons were very rarely higher than 100 µg/L.

Application of cooperative and non-cooperative games in large-scale water quantity and quality management: a case study.

In this paper, two cooperative and non-cooperative methodologies are developed for a large-scale water allocation problem in Southern Iran. The water shares of the water users and their net benefits are determined using optimization models having economic objectives with respect to the physical and environmental constraints of the system. The results of the two methodologies are compared based on the total obtained economic benefit, and the role of cooperation in utilizing a shared water resource is demonstrated. In both cases, the water quality in rivers satisfies the standards. Comparing the results of the two mentioned approaches shows the importance of acting cooperatively to achieve maximum revenue in utilizing a surface water resource while the river water quantity and quality issues are addressed.

A game theoretic approach for interbasin water resources allocation considering the water quality issues.

In this paper, a new game theoretic methodology is developed for interbasin water transfer management with regard to economic, equity, and environmental criteria. The main objective is to supply the competing users in a fair way, while the efficiency and environmental sustainability criteria are satisfied and the utilities of water users are incorporated. Firstly, an optimization model is developed to proportionally allocate water to the competing users in water donor and receiving basins based on their water demands. Secondly, for different coalitions of water users, the water shares of the coalitions are determined using an optimization model with economic objectives regarding the physical and environmental constraints of the system. In order to satisfy water-quality requirements, the impacts of decreasing the instream flow in donor basin are estimated using a water-quality simulation model, and the required treatment levels for effluents discharged into the river, downstream of the water transfer point are determined. Finally, to achieve equity and to provide sufficient incentives for water users to participate in the cooperation, some cooperative game theoretic approaches are utilized for reallocation of net benefits to water users. This model is applied to a large-scale interbasin water allocation problem including two different basins struggling with water scarcity in Iran. The results show that this model can be utilized as an effective tool for optimal interbasin water allocation management involving stakeholders with conflicting objectives subject to physical and environmental constraints.