ABSTRACT
Intense human activities have for years contributed to the pollution of the environment by many dangerous pollutants such as heavy metals, pesticides, or polycyclic aromatic hydrocarbons. There are many conventional methods used to control pollution, with practical and/or financial drawbacks. Therefore, in recent years, an innovative, easy-to-implement and inexpensive adsorption method has been developed to recover waste and clean up water from micropollutants. Firstly, this article aims to summarize the issues related to water remediation and to understand the advantages and disadvantages of the methods classically used to purify water. In particular, this review aims to provide a recent update of the bio-based adsorbents and their use. Differently from the majority of the reviews related to wastewater treatment, in this article several classes of pollutants are considered. Then, a discussion about the adsorption process and interactions involved is provided. Finally, perspectives are suggested about the future work to be done in this field.
ABSTRACT
In this study, HS-SPME/GC-MS and ICP-AES/MS methods are presented to extract and quantify pesticides and metals in palm wines. Various parameters affecting the extraction were investigated: SPME fiber, equilibrium and extraction time, extraction temperature, salinity, and stirring, through an experimental design with 45 trials. The developed method allowed to identify 35 pesticides and quantify 29 of them, from different families of pesticides in 32 palm wine samples. Method performance was evaluated in terms of linearity, repeatability, LOD, LOQ, and accuracy. Among the 32 samples analyzed in 3 replicates, 7 pesticides were detected in 10 samples. Dichlorvos was the only pesticide detected at levels above the European maximal limits. Additionally, 10 of the 19 metals explored by ICP-AES and ICP-MS were found in all samples. Six metals were detected in different samples at levels above the European or OIV maximal limits for drinking water or wine.
Subject(s)
Pesticides , Wine , Gas Chromatography-Mass Spectrometry/methods , Metals , Solid Phase Microextraction/methods , Wine/analysisABSTRACT
Leather industry plays an essential role in the world's economy; however, it also has a negative environmental impact due to the generation of significant quantities of wastes, some of which are classified as hazardous chemicals. Chrome tanning, the most popular tanning process, employs chromium salts, acids, and some other chemicals. Some dyes can be also a source of chromium. As a result, hexavalent chromium, a known carcinogenic and mutagenic, can be found in leather products and cause allergic dermatitis or trigger other diseases. For this reason, it is important to quantify the total amount of chromium in final leather goods, as well as the oxidation state in which this element is found. This paper aims to summarize chromium contamination due to the leather production processes, and to review the analytical methods that have been used to determine chromium's most abundant species: Cr(III) and Cr(VI) in leather and other matrices (foodstuffs, cosmetic products, environmental, and pharmaceutical samples). The international and European regulations are presented as well as the last academic developments to extract and quantify chromium species. The future outlook of pretreatment and quantification techniques are also discussed in this work, with a special focus on chromium interconversions.
