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Synthesis of a D3-symmetric "trefoil" knotted cyclophane.

Arias, Karla I; Zysman-Colman, Eli; Loren, Jon C; Linden, Anthony; Siegel, Jay S.

Chem Commun (Camb) ; 47(34): 9588-90, 2011 Sep 14.

Article in English | MEDLINE | ID: mdl-21607236

ABSTRACT

A D(3)-symmetric knotted cyclophane, with a subgraph of trefoil topology, was synthesized by cyclization of a D(3)-symmetric scaffold. Control of configuration at the three metal-based stereocenters arises from a bascule/pivot mechanism.

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Chemistry Techniques, Synthetic , Ethers, Cyclic/chemistry , Ethers, Cyclic/chemical synthesis , Models, Molecular , Molecular Conformation , Stereoisomerism , Substrate Specificity

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