1.
J Org Chem
; 69(5): 1598-602, 2004 Mar 05.
Article
in English
| MEDLINE
| ID: mdl-14987016
ABSTRACT
An entirely two-directional synthesis of (+/-)-perhydrohistrionicotoxin is presented, utilizing a tandem oxime formation/Michael addition/[3 + 2] cycloaddition as the key step. This approach also constitutes formal syntheses of (+/-)-histrionicotoxin and (+/-)-histrionicotoxin 235A.
