Self-Powered Monitoring of Ammonia Using an MXene/TiO2/Cellulose Nanofiber Heterojunction-Based Sensor Driven by an Electrospun Triboelectric Nanogenerator.

Real-time monitoring of harmful gases is of great significance to identify the environmental hazards to people's lives. However, this application scenario requiring low-power consumption, superior sensitivity, portability, and self-driven operation of gas sensors remains a challenge. Herein, an electrospun triboelectric nanogenerator (TENG) is synthesized using highly electronegative and conducting MXene nanofibers (NFs) paired with biodegradable cellulose acetate NFs (CA-NFs) as triboelectric layers, which supports a sufficient power density (∼1361 mW/m2@2 MΩ) and shows a self-powered ability to operate the chemiresistive gas sensor fabricated in this work. Further, by using cellulose nanofibers (C-NFs) as a substrate, a new kind of MXene/TiO2/C-NFs heterojunction-based sensory component is developed for detection of NH3. This sensor exhibits excellent reproducibility, high selectivity, and sensitivity toward NH3 (1-100 ppm) along with a fast response/recovery time (76 s/62 s) at room temperature. Finally, a monitoring system comprising a TENG-powered sensor, an equivalent circuit, and an LED visualizer has been assembled and successfully demonstrated as a fully self-powered device for NH3 leakage detection. Thus, this work pushes forward the intelligent gas sensing network self-driven by human motion energy, dispensing the external battery dependence for environment monitoring to reduce the possible health effects.

Black-body radiation shifts and theoretical contributions to atomic clock research.

A review of theoretical calculations of black-body radiation (BBR) shifts in various systems of interest to atomic clock research is presented. Calculations for monovalent systems, such as Ca(+), Sr(+), and Rb are carried out using a relativistic all-order single-double method, where all single and double excitations of the Dirac-Fock wave function are included to all orders of perturbation theory. A recently developed method for accurate calculations of BBR shifts in divalent atoms such as Sr is discussed. This approach combines the relativistic allorder method and the configuration interaction method. The evaluation of uncertainties in theoretical values of BBR shifts is discussed in detail.