Your browser doesn't support javascript.
loading
Show: 20 | 50 | 100
Results 1 - 20 de 22
Filter
Add more filters










Publication year range
1.
Rev Sci Instrum ; 89(10): 10J109, 2018 Oct.
Article in English | MEDLINE | ID: mdl-30399836

ABSTRACT

The WEST tokamak consists of a major upgrade of the superconducting medium size tokamak Tore Supra aiming at testing ITER divertor components. Such modification has required rebuilding a full set of magnetic diagnostics. The project was started in 2013 and completed in 2016. The diagnostic consists of a set of 469 sensors (421 pick-up coils, 36 flux loops, and 12 Rogowski coils) installed in the WEST vacuum vessel. New analog integrators have been developed in order to obtain the magnetic field and flux from the raw signal of the sensors. During the startup phase of WEST, plasma currents of the order of a few kilo amperes were measured despite much larger current of the order of hundreds of kilo amperes flowing in nearby conducting structures. The diagnostic is now fully operational and exhibits a noise level of about 0.5 mT on the magnetic field, and 2.0 mWb on flux loops allowing identifying the plasma boundary with an accuracy of a few millimeters on a 2 ms time cycle.

2.
Food Chem ; 208: 150-60, 2016 Oct 01.
Article in English | MEDLINE | ID: mdl-27132835

ABSTRACT

Olive oil blends (OOBs) are complex matrices combining different cultivars at variable proportions. Although qualitative determinations of OOBs have been subjected to several chemometric works, quantitative evaluations of their contents remain poorly developed because of traceability difficulties concerning co-occurring cultivars. Around this question, we recently published an original simplex approach helping to develop predictive models of the proportions of co-occurring cultivars from chemical profiles of resulting blends (Semmar & Artaud, 2015). Beyond predictive model construction and validation, this paper presents an extension based on prediction errors' analysis to statistically define the blends with the highest predictability among all the possible ones that can be made by mixing cultivars at different proportions. This provides an interesting way to identify a priori labeled commercial products with potentially high traceability taking into account the natural chemical variability of different constitutive cultivars.


Subject(s)
Chromatography, Gas/methods , Fatty Acids/analysis , Olive Oil/chemistry , Models, Theoretical
3.
Food Chem ; 173: 122-32, 2015 Apr 15.
Article in English | MEDLINE | ID: mdl-25466003

ABSTRACT

Six Tunisian virgin olive oil (VOO) varieties, Chemlali Sfax, Chetoui, Chemchali, Oueslati, Zarrazi and Zalmati, were characterised by two analytical methods. The gas chromatography allowed the determination of 14 fatty acids and squalene amounts. With fatty acids of each variety, a characteristic "morphotypes" for each oil variety was established. Chemlali Sfax and Zalmati showed strong similarities. Gas chromatography of fatty acid methyl esters (FAME) and near infrared (NIR) spectra of oils, associated to chemometric treatment, allowed the study of the inter-varietal variability and the verification of the variety origins of some Tunisian commercial VOOs. The specificity of Tunisian VOOs was evaluated by comparing the samples to Algerian, Moroccan and French Protected Designation of Origin VOOs. Classification in varietal origins by SIMCA used the FAME compositions and NIR spectra of the most represented varieties (Chemlali Sfax, Chetoui and Oueslati) showed a high potential to authenticate the varietal origin of Tunisian VOOs.


Subject(s)
Fatty Acids/analysis , Food Contamination/analysis , Plant Oils/chemistry , Africa, Northern , Chromatography, Gas , France , Olive Oil , Spectroscopy, Near-Infrared , Tunisia
4.
Phys Rev Lett ; 111(26): 265001, 2013 Dec 27.
Article in English | MEDLINE | ID: mdl-24483800

ABSTRACT

Particle transport has been studied in the Tore Supra tokamak by using modulated ion cyclotron resonance heating to generate perturbations of density and temperature. For the first time, a reversal of the particle convective velocity and a strong increase in the turbulent particle flux have been clearly observed. When the mixed critical gradient ζc=R/L(T)+4(R/L(n))=22 is exceeded, the particle flux increases sharply and the convective velocity reverses from inward to outward. These observations are in agreement with quasilinear, gyrokinetic calculations. The critical gradient corresponds to a transition from an instability driven by the ion temperature gradient to the onset of another instability caused by trapped electrons.

5.
Anal Chim Acta ; 666(1-2): 23-31, 2010 May 07.
Article in English | MEDLINE | ID: mdl-20433960

ABSTRACT

This work investigates the potential use of simultaneously near-infrared (NIR) and mid-infrared (MIR) spectroscopies for the quantitative analysis of fatty acids and triacylglycerols and for identifying the Registered Designation of Origin (RDO) of extra virgin olive oils. The two spectral ranges were used separately using PLS and PLS-DA regressions. To combine both information, concatenated matrix was used at the first time, multiblock method using H-PLS models were constructed at the second time. The models were compared in terms of prediction errors. The results obtained with MIR spectroscopy are better than the ones obtained with NIR spectroscopy. The H-PLS methodology seems to be very interesting for quantitative analysis with the use of additional information in the NIR range, which is not present in the MIR one. For RDO identification by discriminant analysis, the use of multiblock method was less efficient.

6.
Phys Rev Lett ; 102(15): 155005, 2009 Apr 17.
Article in English | MEDLINE | ID: mdl-19518643

ABSTRACT

MHD instabilities driven by fast electrons identified as fishbonelike modes have been detected on Tore Supra during lower hybrid current drive discharges. Direct experimental evidence is reported of a novel feature: the regular redistribution of suprathermal electrons toward external tokamak regions which are correlated to periodic mode frequency jumps. Sharp drops of the electron temperature time trace are factually linked to the cyclical deterioration of the fast electron confinement.

7.
Talanta ; 77(5): 1748-56, 2009 Mar 15.
Article in English | MEDLINE | ID: mdl-19159793

ABSTRACT

One of the most suitable analytical techniques used for edible oil quality control is Fourier transform mid infrared spectroscopy (FT-MIR). FT-MIR spectroscopy was used to continuously characterize the aging of various edible oils thanks to a specific aging cell. There were differences in the spectra of fresh and aged oils from different vegetable sources, which provide the basis of a method to classify them according to the oxidative spectroscopic index value. The use of chemometric treatment such as multivariate curve resolution-alternative least square (MCR-ALS) made it possible to extract the spectra of main formed and degraded species. The concentration profiles gave interesting information about the ability of the various oils to support the oxidative treatment and showed that all oils present the same aging process. Both methods led to concordant results in terms of induction times determined by the oxidative spectroscopic index and the appearance of oxidation products revealed by MCR-ALS.


Subject(s)
Food Analysis , Plant Oils/standards , Spectroscopy, Fourier Transform Infrared/methods , Food Preservation , Oxidants , Oxidation-Reduction
8.
Phys Rev Lett ; 100(25): 255004, 2008 Jun 27.
Article in English | MEDLINE | ID: mdl-18643670

ABSTRACT

Burning tokamak plasmas with internal transport barriers are investigated by means of integrated modeling simulations. The barrier sustainment in steady state, differently from the barrier formation process, is found to be characterized by a critical behavior, and the critical number of the phase transition is determined. Beyond a power threshold, alignment of self-generated and noninductively driven currents occurs and steady state becomes possible. This concept is applied to simulate a steady-state scenario within the specifications of the International Thermonuclear Experimental Reactor.

9.
Appl Spectrosc ; 62(5): 583-90, 2008 May.
Article in English | MEDLINE | ID: mdl-18498701

ABSTRACT

The combination of mid-infrared (MIR) spectroscopy with multivariate analysis provides an original approach to study the profile of virgin olive oils (VOOs) in relation to composition and geographical origin. Chemometric treatment of mid-infrared spectra (n=402) is assessed for quantification of fatty acids (14 components) and triacylglycerols (19 components) in VOO samples and for classification into six very geographically closed registered designations of origin (RDOs) of French VOO ("Aix-en-Provence", "Haute-Provence", "Vallée des Baux de Provence", "Nice", "Nîmes", and "Nyons"). Spectroscopic interpretation of regression vectors has shown that each RDO is correlated to one specific component of VOO according to their cultivar compositions. The results are satisfactory, in spite of the similarity of cultivar compositions between two denominations of origin ("Aix-en-Provence" and "Vallée des Baux de Provence"). Chemometric treatment of MIR spectra makes it possible to obtain similar results to those obtained by time-consuming analytical techniques such as gas chromatography (GC) and high-performance liquid chromatography (HPLC) and constitutes a fast and robust tool for authentication of these French VOOs.


Subject(s)
Lipids/analysis , Plant Oils/chemistry , Fatty Acids/analysis , France , Mediterranean Region , Olive Oil , Plant Oils/standards , Spectrophotometry, Infrared , Triglycerides/analysis
10.
Anal Chim Acta ; 595(1-2): 136-44, 2007 Jul 09.
Article in English | MEDLINE | ID: mdl-17605993

ABSTRACT

The authentication of virgin olive oil samples requires usually the use of sophisticated and time consuming analytical techniques. There is a need for fast and simple analytical techniques for the objective of a quality control methodology. Virgin olive oils present characteristic NIR spectra. Chemometric treatment of NIR spectra was assessed for the quantification of fatty acids and triacylglycerols in virgin olive oil samples (n=125) and for their classification (PLS1-DA) into five very geographically closed registered designations of origin (RDOs) of French virgin olive oils ("Aix-en-Provence", "Haute-Provence", "Nice", "Nyons" and "Vallée des Baux"). The spectroscopic interpretation of regression vectors showed that each RDO was correlated to one or two specific components of virgin olive oils according to their cultivar compositions. The results were quite satisfactory, in spite of the similarity of cultivar compositions between two denominations of origin ("Aix-en-Provence" and "Vallée des Baux"). Chemometric treatments of NIR spectra allow us to obtain similar results than those obtained by time consuming analytical techniques such as GC and HPLC, and constitute a help fast and robust for authentication of those French virgin olive oils.

11.
Phys Rev Lett ; 96(4): 045004, 2006 Feb 03.
Article in English | MEDLINE | ID: mdl-16486837

ABSTRACT

During fully noninductively driven discharges in the Tore Supra tokamak, large spontaneous oscillations of the core electron temperature (DeltaTe/Te>50%) have been observed for the first time. They occurred during the standard O regime, which is itself characterized by periodic oscillations of much smaller amplitude. The "giant" oscillations appear to involve distinct mechanisms with respect to the O regime and provide a spectacular example of the complex nonlinear interactions between energy confinement, noninductive current sources, and MHD that may occur in a tokamak plasma during steady-state operation.

12.
Environ Res ; 97(3): 300-11, 2005 Mar.
Article in English | MEDLINE | ID: mdl-15589239

ABSTRACT

In this study, we investigated, in vitro, the effects of petroleum hydrocarbons on the phospholipid ester-linked fatty acid composition of Corynebacterium sp. Strain 8. The usual ratio of monounsaturated fatty acids E/Z (or trans/cis) was calculated. This ratio led to unexpected results because we found similar values for growths on either a hydrophobic substrate (crude oil) or a soluble carbon source (rich medium). The use of such an indicator seemed limited for monitoring an environmental stress, so we proposed an index based on the homeoviscous adaptation theory. A membrane viscosity index was defined and applied to Corynebacterium sp. Strain 8 (in vitro growth) and to a sedimentary community (in situ experiment). The results allowed us to estimate the membrane fluidity of both an isolated strain and a bacterial community in accordance with the medium hydrophobicity.


Subject(s)
Corynebacterium/drug effects , Petroleum/toxicity , Phospholipids/metabolism , Biodegradation, Environmental , Corynebacterium/metabolism , Gas Chromatography-Mass Spectrometry , Humans , Membrane Fluidity
13.
Phys Rev Lett ; 93(13): 135003, 2004 Sep 24.
Article in English | MEDLINE | ID: mdl-15524729

ABSTRACT

Steady state full noninductive current tore supra plasmas offer a unique opportunity to study the local parametric dependence of particle pinch velocity, in order to discriminate among different theories. Magnetic field shear is found to generate an inward pinch which is dominant in the gradient region (normalized radius 0.3

14.
Phys Rev Lett ; 93(25): 255002, 2004 Dec 17.
Article in English | MEDLINE | ID: mdl-15697903

ABSTRACT

Improvement (up to a factor of approximately 4) of the electron-cyclotron (EC) current drive efficiency in plasmas sustained by lower-hybrid (LH) current drive has been demonstrated in stationary conditions on the Tore Supra tokamak. This was made possible by feedback controlled discharges at zero loop voltage, constant plasma current, and constant density. This effect, predicted by kinetic theory, results from a favorable interplay of the velocity space diffusions induced by the two waves: the EC wave pulling low-energy electrons out of the Maxwellian bulk, and the LH wave driving them to high parallel velocities.

15.
Phys Rev Lett ; 91(13): 135001, 2003 Sep 26.
Article in English | MEDLINE | ID: mdl-14525311

ABSTRACT

During noninductively driven discharges in the Tore Supra tokamak, steady sinusoidal oscillations of the central electron temperature, lasting as long as 2 min, have been observed for the first time. Having no helical structure, they cannot be ascribed to any known MHD instability. The most plausible explanation of this new phenomenon is that the plasma current density and the electron temperature evolve as a nonlinearly coupled predator-prey system. This interpretation is supported by the numerical solution of coupled resistive current diffusion and heat transport equations.

16.
Phys Rev Lett ; 90(15): 155002, 2003 Apr 18.
Article in English | MEDLINE | ID: mdl-12732041

ABSTRACT

Recently, plasmas exceeding 4 min have been obtained with lower hybrid current drive (LHCD) in Tore Supra. These LHCD plasmas extend for over 80 times the resistive current diffusion time with zero loop voltage. Under such unique conditions the neoclassical particle pinch driven by the toroidal electric field vanishes. Nevertheless, the density profile remains peaked for more than 4 min. For the first time, the existence of an inward particle pinch in steady-state plasma without toroidal electric field, much larger than the value predicted by the collisional neoclassical theory, is experimentally demonstrated.

17.
Chemosphere ; 44(4): 519-28, 2001 Aug.
Article in English | MEDLINE | ID: mdl-11482638

ABSTRACT

This study concerns the effects of various long-chain n-alkanes, n-alkane mixtures and Arabian Light crude oil on the fatty acid (FA) composition of a sedimentary marine bacteria (Marinobacter hydrocarbonoclasticus strain 617), growing under aerobic conditions. The cultures with n-alkanes, as compared with soluble carbon sources, led to greater amounts of saturated and methyl branched FA (mainly belonging to a delta10 series). We observed the appearance or increase of saturated and unsaturated FA with the same carbon chain length (CCL) as the n-alkane carbon source (maximum for n-alkane CCL corresponding to the 'range' of the de novo synthesized fatty acids). We also observed a strong control of the oddness/evenness of the CCL of the FA by the oddness/evenness of the n-alkane. A n-alkane utilization index, (saturated + branched)/monounsaturated fatty acids (SAFA + BFA/MUFA) enabled discriminating between soluble carbon sources and hydrocarbons.


Subject(s)
Alkanes/chemistry , Bacteria/chemistry , Fatty Acids/biosynthesis , Petroleum/adverse effects , Water Pollution/adverse effects , Fatty Acids/analysis
18.
Lipids ; 19(9): 643-8, 1984 Sep.
Article in English | MEDLINE | ID: mdl-6503627

ABSTRACT

The liver oil content of seven Mediterranean Centrophorus spp. were studied together with the oil of one unfertilized egg and one yolk bag. The relative weight of the liver ranges from 15 to 29% of total body weight; 63 to 89% of the liver weight is oil. Squalene, the major component (49-89% in oil) of the unsaponifiable fraction, is directly quantified by GLC following TLC separation. The squalene level increases with the age of the animals. More than 50 fatty acid species were identified. Among them, the most abundant are: 16:0 (22-27%), 18:1 omega 9 (21-36%) and 22:6 omega 3 (2-18%). The level of omega 3-fatty acids, essential in the fishes, shows a maximum in the egg (26%), decreases to a minimum in the young (5%) and stabilizes to an intermediate level in the adult (12%).


Subject(s)
Fatty Acids/analysis , Fish Oils/analysis , Liver/growth & development , Ovum/analysis , Sharks/growth & development , Squalene/analysis , Aging , Animals , Chromatography, Gas , Female , Gas Chromatography-Mass Spectrometry , Male
19.
J Radiol ; 61(4): 243-9, 1980 Apr.
Article in French | MEDLINE | ID: mdl-7392001

ABSTRACT

Six cases of recessive hepatorenal polycystic disease in infants and young children were explored by intravenous urography and ultrasonography. Sufficient specific ultrasonography findings for making a diagnosis were obtained. The kidneys are large and produce strong echos, with inversion of the normal strength of medullary when compared to cortical echos, and poor definition of the renal sinus. Strong echos are also obtained from the liver, especially in the juvenile forms, because of the large amount of fibrosis. Large intrahepatic biliary ectasias were discovered in a 3-year-old child.


Subject(s)
Cysts/genetics , Liver Diseases/genetics , Polycystic Kidney Diseases/genetics , Ultrasonography , Adolescent , Child , Child, Preschool , Cysts/complications , Cysts/diagnosis , Female , Humans , Infant , Infant, Newborn , Liver Diseases/complications , Liver Diseases/diagnosis , Male , Polycystic Kidney Diseases/complications , Polycystic Kidney Diseases/diagnosis
20.
J Radiol ; 60(8-9): 537-40, 1979.
Article in French | MEDLINE | ID: mdl-536964

ABSTRACT

The authors describe a case of urethroperineal fistula in the lateropostion. It is a rare malformation, with a varied symptomatology, which requires radiological investigations for its morphological and topographical study. Surgical treatment varies as a function of the site and size of the fistula. Basing their comments on the studies by STEPHENS [12], the authors try to give an embryological explanation of this affection.


Subject(s)
Fistula/diagnostic imaging , Perineum/diagnostic imaging , Urethral Diseases/diagnostic imaging , Urinary Fistula/diagnostic imaging , Child, Preschool , Humans , Male , Radiography
SELECTION OF CITATIONS
SEARCH DETAIL
...