Adsorption studies of tetracycline hydrochloride and diclofenac sodium on NH2-MIL-53(Al/Zr) sodium alginate gel spheres.

Metal-organic frameworks are emerging inorganic-organic hybrid materials that can be self-assembled from metal ions and organic ligands via coordination bonds. These materials possess large specific surface area, tunable pore structure, abundant active center, diversity of functional groups as well as high mechanical and thermal stability which promote their applications in adsorption and catalysis studies. In this study, NH2-MIL-53(Al/Zr) was prepared and embedded into sodium alginate gel spheres (NH2-MIL-53(Al/Zr)-SA) and its adsorption properties towards TC and DCF in solution were investigated. According to XRD and FTIR analysis, the structure of the raw material was not changed after making the gel spheres. The maximum adsorption towards TC (pH =3) and DCF (pH =5) reached 98.5 mg·g-1 and 192 mg·g-1, respectively. The process was consistent with Langmuir and Freundlich, suggesting that there was both monolayer and multilayer adsorption which infers the presence of physical adsorption (intra-particle diffusion) and non-homogeneous chemical adsorption. The thermodynamic parameters showed that the adsorption process was a spontaneous entropy increasing reaction. The regeneration rate of spent NH2-MIL-53(Al/Zr)-SA could still reach 99.1 % after three cycles, indicating good regeneration performance. This study can provide a basis for the application of NH2-MIL-53(Al/Zr)-SA in wastewater treatment.

CTAB-modified peanut husk pre-treated with KMnO4 as an eco-friendly adsorbent for the uptake of Congo red in solution: adsorption and mechanism study.

A cationic surfactant (cetyltrimethylammonium bromide, CTAB)-modified peanut husk pretreated with potassium permanganate (KMnO4) was developed and applied as an adsorbent for the removal of Congo red (CR) in aqueous solution. The surface morphology and physicochemical characteristics of the adsorbent labelled as PNK-CTAB were assessed using well-established analytical techniques. The efficiency of PNK-CTAB was assessed via the batch adsorption method using distilled water, tap water and river water as aqueous medium. Results of the batch study showed that the adsorption capacity of PNK-CTAB could reach 70.5 mg g-1 at 313 K due to its improved surface properties and functionalities. Furthermore, the uptake of CR onto PNK-CTAB was found to be best described by the Elovich model thus suggesting adsorption on a heterogeneous surface, whereas fitting of intraparticle diffusion model indicated the significant role of mass transfer mechanism in the process. The equilibrium data was found to be well described by Langmuir, Temkin and Freundlich models albeit the latter was the best fit. Further analysis of the associated thermodynamics indicated the adsorption process to be endothermic, spontaneous in nature and likely mediated by physisorption processes. The excellent adsorption efficiency of PNK-CTAB toward CR within a wide pH range, negligible influence of some commonly occurring salts, good reusability efficiency, low cost (as confirmed by its cost analysis) and its ability to reduce the cytotoxicity of CR towards human embryonic kidney (HEK) 293 cells suggest the good prospects of this adsorbent for practical applications.

Study on adsorption of salicylic acid and sulfosalicylic acid by MOF-sodium alginate gel beads obtained in a green way.

A composite (ZS-UiO-66-NH2) zirconium crosslinked sodium alginate gel beads (ZS)-metal-organic skeleton (UiO-66-NH2) were prepared in this study through in-situ growth under simple, green and mild conditions for removal of the salicylic acid (SA) and sulfosalicylic acid (SSA) from water. The physicochemical properties of ZS-UiO-66-NH2 were characterized using various analytical methods. The influencing factors in the adsorption process including pH of solution, amount of adsorbent, coexisting ions, adsorption time, reaction temperature and equilibrium concentration of SA/SSA were performed in batch adsorption. The experimental results indicated that ZS-UiO-66-NH2 had high stability and could achieve efficient adsorption of SA/SSA in broad pH range (2-9) and salinity (0-0.2 mol·L-1). SA and SSA adsorbed on the composite at 293 K reached high values of 193 and 167 mg·g-1 from Langmuir model, respectively. Kinetic and isotherm studies demonstrated that the adsorption processes were mainly multilayer heterogeneous chemisorption. Thermodynamic data manifested that the two processes were exothermic and spontaneous with increasing entropy. ZS-UiO-66-NH2 can effectively remove SA/SSA from simulated wastewater under different pH and can be reused after elution with a NaHCO3 solution (5 mmol·L-1). The ZS-UiO-66-NH2 composite has great potential for removing SA/SSA from actual water bodies.

Three birds, one stone: Disinfecting and turning waste medical masks into valuable carbon dots for sodium hydrosulfite and Fe3+ detection enabled by a simple hydrothermal treatment.

Disposable medical masks are widely used to prevent respiratory infections due to their ability to block virus particles from entering the human body. The coronavirus disease 2019 (COVID-19) pandemic highlighted the importance of medical masks, leading to their widespread use around the world. However, a large number of disposable medical masks have been discarded, some carrying viruses, which have posed a grave threat to the environment and people's health, as well as wasting resources. In this study, a simple hydrothermal method was used for the disinfection of waste medical masks under high-temperature conditions as well as for their transformation into high-value-added carbon dots (CDs, a new type of carbon nanomaterial) with blue-emissive fluorescence, without high energy consumption or environmental pollution. Moreover, the mask-derived CDs (m-CDs) could not only be used as fluorescent probes for sensing sodium hydrosulfite (Na2S2O4), which is widely used in the food and textile industries but is seriously harmful to human health, but also be used for detecting Fe3+ which is harmful to the environment and human health due to its wide use in industries.

Remediation of water tainted with noxious hexavalent chromium using cetylpyridinium-modified bagasse biomass: adsorption and regeneration studies.

Herein, cetylpyridinium-modified bagasse (SB-CPC) biomass was synthesized and applied for removal of noxious Cr(VI) ions from aqueous matrix. Batch mode analyses were conducted, and the results showed that SB-CPC adsorbent has a maximum uptake capacity (qm) of 70.5 ± 3.2 mg g-1 at 303 K. The adsorption isotherms and kinetics for elimination of Cr(VI) by SB-CPC were better fitted by Langmuir model and pseudo-second-order model, respectively. The occurrence of pseudo-second-order kinetic could be mainly influenced by the intra-particle diffusion mass transfer. Electrostatic attraction was the dominant underlying reaction mechanism followed by pore filing effect (minor). Thermodynamic study affirms the endothermic behavior and occurrence of physical adsorption process. SB-CPC adsorbent had exhibited an outstanding desorption-regeneration performance using NaOH solution; accordingly, it can practically be applied for remediation of wastewater tainted with Cr(VI) ions.

Biocomposite based on zirconium and amine-grafted walnut shell with antibacterial properties for the removal of Alizarin red in water: batch and column studies.

Recent progress has been made in the application of novel zirconium-loaded amine-grafted walnut shells as multifunctional adsorbents for the remediation of Alizarin red (AR) and bacteria in aqueous solutions. The morphology and functional groups of ACWNS@Zr were studied using Brunauer-Emmett-Teller (BET) techniques, X-ray diffraction (XRD), pH point of zero charges (pHpzc), scanning electron microscopy (SEM), and Fourier transform infrared (FTIR) spectroscopy. Adsorption and regeneration tests were carried out in batch and column mode. The ACWNS@Zr had a Langmuir maximum capacity of 415.5 ± 6.1 mg g-1 at 303 K. The spread plate technique was used to evaluate the adsorbent's antimicrobial properties against Staphylococcus aureus and Escherichia coli. ACWNS@Zr exhibited inhibitory potential towards S. aureus and E. coli in the suspensions by 53.3% and 15.0%, respectively. Electrostatic interaction and complexation interaction could be the key mechanisms governing AR dye removal. Equilibrium isotherms fit Langmuir models better for both batch and column studies, while adsorption kinetics to pseudo-second-order and Thomas models for batch and column studies, respectively. Thermodynamic studies indicated that the adsorption process was endothermic and spontaneous. Furthermore, columns' mass transfer capacity (B) increased as the concentration increased due to the enhanced driving force for AR adsorption onto ACWNS@Zr. Regeneration with NaOH solution of AR-loaded ACWNS@Zr was remarkable.

Split-aptamer mediated regenerable temperature-sensitive electrochemical biosensor for the detection of tumour exosomes.

In this paper, a split-aptamer mediated regenerable temperature-sensitive (SMRT) electrochemical biosensor was constructed for the detection of exosomes. The split-aptamer used in this SMRT biosensor was composed of two fragments, one of which was immobilized on the surface of an electrode via sulfhydryl groups and named split-a and the other was labelled with methylene blue and named split-b. The two fragments could form sandwich structures at the electrode surface via target-induced self-assembly in the presence of target exosomes at 4 °C in PBS, and then realizing the detection of exosomes via voltammetry. In addition, due to the temperature sensitivity of the split-aptamer, the electrode could be regenerated through temperature-induced disassembly of the sandwich structures. Consequently, the SMRT biosensor realized sensitive and specific analysis of target exosomes with a limit of detection of 1.5 × 106 particles/mL and could be quickly and easily regenerated by washing with PBS at 37 °C for 30 s without any additives. This is the first study on the construction of a reproducible electrochemical biosensor using a split-aptamer for the specific detection of tumour exosomes, and may provide an innovative strategy for the economical and efficient design of regenerable electrochemical biosensors.

Mechanisms for carbon dots-based chemosensing, biosensing, and bioimaging: A review.

Due to the favorable biocompatibility, photostability and fluorescence emissions, carbon dots (CDs) are being widely investigated as fluorescent probes. Current CD-based fluorescent probe designs depend largely on conventional fluorescence sensing mechanisms, for e.g. the inner filter effect, photoinduced electron transfer, and Förster resonance energy transfer. Although these mechanisms have been successful, it is still desirable to introduce new sensing mechanisms. In recent years, emerging mechanisms such as aggregation-induced emission, hydrogen-bond induced emission, and intramolecular charge transfer have been developed for CD-based probes. This review summarizes both conventional and emerging mechanisms, and discuss CDs in the context of chemosensing, biosensing, and bioimaging. We provide an outlook for several other mechanisms such as CN isomerization, the short-wavelength inner filter technique, excited-state intramolecular proton transfer, and twisted intramolecular charge transfer, which have been applied to organic fluorescent probes design but not as much in CD-based sensing systems. We envision that this review will provide insights that inspire further development of CD-based fluorescent probes as for biological applications.

Efficient removal of 2,4-D from solution using a novel antibacterial adsorbent based on tiger nut residues: adsorption and antibacterial study.

We engineered a tiger nut residue (TNR, a low-cost agricultural waste material) through a facile and simple process to take advantage of the introduced functional groups (cetylpyridinium chloride, CPC) in the removal of 2,4-dichlorophenoxyacetic acid (2,4-D) in batch mode and further investigated its impingement on bacterial growth in a yeast-dextrose broth. The surface characterizations of the adsorbent were achieved through Fourier-transform infrared spectroscopy (FTIR), Brunauer-Emmett-Teller method (BET), X-ray diffraction analysis (XRD), and X-ray photoelectron spectroscopy (XPS). The batch adsorption studies revealed that solution pH, adsorbent dose, temperature, and salt affected the adsorptive capacity of TNR-CPC. The equilibrium data were best fitted by Langmuir isotherm model with a maximum monolayer adsorption capacity of 90.2 mg g-1 at 318 K and pH 3. Pseudo-second-order model best fitted the kinetics data for the adsorption process. Physisorption largely mediated the adsorption system with spontaneity and a shift in entropy of the aqueous solid-solute interface reflecting decreased randomness with an exothermic character. TNR-CPC demonstrated a good reusability potential making it highly economical and compares well with other adsorbents for decontamination of 2,4-D. The adsorption of 2,4-D proceeded through a probable trio-mechanism; electrostatic attraction between the carboxylate anion of 2,4-D and the pyridinium cation of TNR-CPC, hydrogen bonding between the hydroxyl (-OH) group inherent in the TNR and the carboxyl groups in 2,4-D and a triggered π-π stacking between the benzene structures in the adsorbate and the adsorbent. TNR-CPC reported about 99% inhibition rate against both gram-positive S. aureus and gram-negative E. coli. It would be appropriate to investigate the potential of TNR-CPC as a potential replacement to the metal oxides used in wastewater treatment for antibacterial capabilities, and its effects against airborne bacteria could also be of interest.

Amine-grafted walnut shell for efficient removal of phosphate and nitrate.

The presence of emerging pollutants such as PO43- and NO3- in water bodies has attracted worldwide concern about their severe effects on water bodies and the health of humankind in general. Therefore, to preserve the health of humankind and environmental safety, it is of the essence that industrial effluents are treated before they are discharged into water bodies. Amine functionalized walnut shells (ACWNS) were synthesized, characterized, and then tested as a novel adsorbent for PO43- and NO3- removal. The effects of pH, dosage, initial phosphate concentration, interference ions, and temperature on the removal of phosphate and nitrate were investigated. Notably, the adsorption of PO43- and NO3- was exothermic and spontaneous, with a maximum uptake capacity of phosphate and nitrate, at 293 K, 82.2 and 35.7 mg g-1, respectively. The mechanism by which these ions were adsorbed onto ACWNS could be electrostatic interactions and hydrogen bonding. Pseudo-second-order kinetic model fitted the PO43- and NO3- adsorption, while Freundlich and Langmuir models best fitted the PO43- and NO3- adsorption, respectively. Furthermore, in the binary system, the uptake capacity of phosphate decreased by 14.4% while nitrate witnessed a reduction in its uptake capacity of 10.4%. ACWNS has a higher attraction towards both ions and this could be attributed to the existence of a variety of active areas on ACWNS that exhibit a degree of specificity for the individual ions. Results obtained from real water sample analysis confirmed ACWNS as highly efficient to be utilized for practical remediation processes.

Magnetic biocomposite based on peanut husk for adsorption of hexavalent chromium, Congo red and phosphate from solution: Characterization, kinetics, equilibrium, mechanism and antibacterial studies.

A biocomposite (PN-Fe3O4-PEI) was synthesized via the chemical modification of peanut husk (a low-cost adsorbent) with Fe3O4 particles and polyethyleneimine under benign environmental conditions. The modification agents used in this study were observed to overcome the challenges associated with the use pristine peanut husk with a concomitant enhancement in its efficiency as an adsorbent. Results from the characterization studies employed in this study confirmed PN-Fe3O4-PEI to be a crystalline magnetic adsorbent with a mesoporous structure. The adsorption property of the developed material (PN-Fe3O4-PEI) for wastewater treatment was investigated using Chromium (VI), Phosphates (PO43-) and Congo red (CR) as model pollutants. Using the batch method, PN-Fe3O4-PEI exhibited a maximum monolayer adsorption capacity of 58.4, 13.5 and 71.3 mg g-1 for Cr(VI), PO43- (as P g L-1) and CR, respectively and was dependent on temperature and initial adsorbate concentration. Kinetic studies revealed that the Elovich equation, the pseudo-second order kinetic model and double constant equation well described the uptake of Cr(VI), PO43- and CR onto PN-Fe3O4-PEI, respectively. These results may confirm the uptake of these pollutants to be mainly driven by chemical forces. In addition, PN-Fe3O4-PEI was observed to be efficient for the decontamination of the studied pollutants in real water samples as well as exhibit antibacterial properties towards the growth of S. aureus. These properties of PN-Fe3O4-PEI with its other excellent features such as high stability in solution, good regeneration properties and its facile retrieval from the solution using a magnet promote its suitability for practical wastewater treatment.

Lighting up Individual Organelles With Fluorescent Carbon Dots.

Cell organelles play crucial roles in the normal functioning of an organism, therefore the disruption of their operation is associated with diseases and in some cases death. Thus, the detection and monitoring of the activities within these organelles are of great importance. Several probes based on graphene oxide, small molecules, and other nanomaterials have been developed for targeting specific organelles. Among these materials, organelle-targeted fluorescent probes based on carbon dots have attracted substantial attention in recent years owing to their superior characteristics, which include facile synthesis, good photostability, low cytotoxicity, and high selectivity. The ability of these probes to target specific organelles enables researchers to obtain valuable information for understanding the processes involved in their functions and/or malfunctions and may also aid in effective targeted drug delivery. This review highlights recently reported organelle-specific fluorescent probes based on carbon dots. The precursors of these carbon dots are also discussed because studies have shown that many of the intrinsic properties of these probes originate from the precursor used. An overview of the functions of the discussed organelles, the types of probes used, and their advantages and limitations are also provided. Organelles such as the mitochondria, nucleus, lysosomes, and endoplasmic reticulum have been the central focus of research to date, whereas the Golgi body, centrosome, vesicles, and others have received comparatively little attention. It is therefore the hope of the authors that further studies will be conducted in an effort to design probes with the ability to localize within these less studied organelles so as to fully elucidate the mechanisms underlying their function.

Simultaneous detection of the spike and nucleocapsid proteins from SARS-CoV-2 based on ultrasensitive single molecule assays.

Nucleic acid detection technology based on polymerase chain reaction (PCR) and antibody detection based on immunochromatography still have many problems such as false negatives for the diagnosis of coronavirus disease 2019 (COVID-19). Therefore, it is of great importance to develop new techniques to improve the diagnostic accuracy of COVID-19. We herein developed an ultrasensitive, rapid, and duplex digital enzyme-linked immunosorbent assay (dELISA) for simultaneous detection of spike (S-RBD) and nucleocapsid (N) proteins of SARS-CoV-2 based on a single molecule array. This assay effectively combines magnetic bead encoding technology and the ultrasensitive detection capability of a single molecule array. The detection strategies of S-RBD protein and N-protein exhibited wide response ranges of 0.34-1065 pg/mL and 0.183-338 pg/mL with detection limits of 20.6 fg/mL and 69.8 fg/mL, respectively. It is a highly specific method for the simultaneous detection of S-RBD protein and N-protein and has minimal interference from other blood proteins. Moreover, the spike assay showed a satisfactory and reproducible recovery rate for the detection of S-RBD protein and N-protein in serum samples. Overall, this work provides a highly sensitive method for the simultaneous detection of S-RBD protein and N-protein, which shows ultrasensitivity and high signal-to-noise ratio and contributes to improve the diagnosis accuracy of COVID-19.

Adsorption performance of modified agricultural waste materials for removal of emerging micro-contaminant bisphenol A: A comprehensive review.

This review is an attempt to assess the adsorption performance of different green adsorbents derived from agricultural waste materials (AWMs) that were used for the elimination of bisphenol A (BPA) from aqueous matrices. Different processes including grafting, polymerization, activation and chemical treatment have been applied to functionalize and modify agricultural waste materials for the purposes of increasing their adsorptive performances toward BPA. The highest reported adsorption capacity of adsorbent from agricultural waste for the uptake of BPA is the highly microporous carbon adsorbent derived from Argan nut shell (1408 mg g-1). Hydrogen bonding, hydrophobic and π-π interactions were reported in most studies as the main mechanisms governing the adsorption of BPA onto agricultural waste adsorbents. Equilibrium isotherm and kinetic studies for the uptake of BPA onto agricultural waste adsorbents were best described by Langmuir/Freundlich model and pseudo-second order model, respectively. Despite the effective elimination of BPA by various agricultural waste adsorbents, an appropriate selection of elution solvent is important for effective desorption of BPA from spent adsorbent. To date, ethanol, diethyl ether-methanol, methanol-acetic acid, mineral acids and sodium hydroxide are the most eluents applied for desorption of BPA molecules loaded onto AW-adsorbents. Looking toward the future, studies on the agricultural waste adsorbents based on polymers, activated carbons, nanoparticles and highly microporous carbons should be mostly considered by the researchers toward removing BPA. These future studies should be performed both in laboratory, pilot and industrial scales, and also should report the sustainable techniques for disposal of the spent AW-adsorbents after lose their adsorption performance on BPA.

One novel composite based on functionalized magnetic peanut husk as adsorbent for efficient sequestration of phosphate and Congo red from solution: Characterization, equilibrium, kinetic and mechanism studies.

Accessibility to quality and clean water has in recent times been compromised due to the presence of pollutants, thus posing as a threat to the survival of living organisms. The adsorption technique in this regard has been observed to be useful in the remediation process with the material used as the adsorbent playing an integral role. In this study, a novel biocomposite (PN-Fe3O4-IDA-Al) based on peanut husk (a low-cost material) was developed by functionalization with aluminum (Al), iminodiacetic acid (IDA) and Fe3O4. The efficiency of PN-Fe3O4-IDA-Al as an adsorbent for the remediation of wastewater was evaluated using Congo red (CR) and phosphates (PO43-) as model pollutants. The results from the characterization studies confirmed PN-Fe3O4-IDA-Al to have superparamagnetic properties which ensures its easy retrieval. Adsorption studies indicated that PN-Fe3O4-IDA-Al had a maximum monolayer capacity of 79.0 ± 2.0 and 16.8 ± 2.5 mg g-1 for CR and PO43- (according to P), respectively, which was significantly dependent on factors such as reaction time, solution pH, temperature and the presence of some common anions. The Freundlich model was observed to better describe both adsorption processes with chemisorption being the principal underlying mechanism. Results from using real water samples confirmed PN-Fe3O4-IDA-Al to be highly efficient for practical remediation processes. These results coupled with the synthesis of PN-Fe3O4-IDA-Al under benign conditions using low-cost materials help to expound the knowledge on the use of low cost materials as the basis for the development of highly efficient adsorbents for wastewater remediation.

Selective removal of anionic dyes in single and binary system using Zirconium and iminodiacetic acid modified magnetic peanut husk.

A novel adsorbent (PN-Fe3O4-IDA-Zr) was developed from the chemical modification of peanut husk (a low cost material) with Fe3O4, iminodiacetic acid (IDA) and zirconium (Zr) and its efficacy for the sequestration of wastewater assessed using Alizarin red (AR) and Acid chrome blue K (AK) as model pollutants. To elucidate the characteristics of the formed adsorbent, analytical techniques such as the Bruauner-Emmet-Teller (BET) method, X-ray photoelectron spectroscopy (XPS), Fourier-transform infrared (FTIR) spectroscopy, X-ray diffractive spectroscopy (XRD) and vibrating sample magnetometer (VSM) were applied. Results from these studies confirmed the formation of a crystalline mesoporous adsorbent with surface properties which enhanced its usefulness. From the adsorption studies, it was observed that factors such as pH, salts, temperature and contact time influenced the uptake of the anionic dyes. The maximum monolayer capacity of PN-Fe3O4-IDA-Zr for AR was 49.4 mg g-1 (at 313 K) and was well fitted by the Langmuir model with the chemisorption process being the dominant reaction mechanism. In binary systems, PN-Fe3O4-IDA-Zr exhibited higher affinity for AR as compared with AK. The significant removal efficiency exhibited by this novel adsorbent as well as other unique features such as easy retrieval and high regeneration promotes its prospects as an adsorbent for practical wastewater remediation processes.

Decontamination of bisphenol A and Congo red dye from solution by using CTAB functionalised walnut shell.

In this research, the eco-friendly cationic surfactant modified walnut shell (WNS-CTAB) was synthesised to enhance the uptake for bisphenol A (BPA) and Congo red (CR) from aqueous solution. The characterisation of WNS-CTAB was performed using Fourier-transform infrared (FTIR), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), etc. to know its physiochemical properties. The adsorption equilibrium results were best described by the Langmuir isotherm model, which confirmed the monolayer adsorption of the pollutant molecules onto the adsorbent's surface. The maximum monolayer adsorption quantity of WNS-CTAB was established to be 38.5 mg g-1 for BPA and 104.4 mg g-1 for CR at 303 K, respectively. Pseudo-second-order kinetic models described the adsorption kinetics of both BPA and CR. Furthermore, the intra-particle diffusion was applied to analyse the kinetic results and was established that the rate was not solely controlled by diffusion. The mechanisms associated with BPA and CR adsorption onto the WNS-CTAB may include van der Waals interaction, hydrophobic interaction, and electrostatic force. WNS-CTAB demonstrated a good reusability potential with desorption through three successive adsorption-desorption cycles performed in both experiments. Moreover, in the binary system, the adsorption capacity of BPA witnessed a 66% decrease while CR saw marginal reduction of 8.0 %. This suggests that WNS-CTAB had a higher affinity for binding to CR with higher selectivity as compared with BPA. Therefore, WNS-CTAB has exhibited huge potential to serve as a functional material for practical use in the treatment of wastewater.

Fe3O4 and iminodiacetic acid modified peanut husk as a novel adsorbent for the uptake of Cu (II) and Pb (II) in aqueous solution: Characterization, equilibrium and kinetic study.

The presence of higher concentrations of heavy metals in water affects its quality with a concomitant adverse effect on its users thus their removal is paramount. A novel adsorbent, PN-Fe3O4-IDA derived from the chemical modification of peanut husk (a low-cost agricultural biomass produced in significant quantities globally) using magnetic nanoparticles (Fe3O4) and iminodiacetic acid was utilized for the remediation of heavy metals in aqueous solution. Analytical techniques vis-à-vis the Fourier-Transform Infrared, Scanning Electron Microscope, Brunauer-Emmett-Teller, X-ray photoelectron spectroscopy and X-ray Diffraction were applied for the characterization of PN-Fe3O4-IDA. Results from the characterization studies showed that PN-Fe3O4-IDA possessed a mesoporous structure, a heterogeneous surface and functional groups such as carboxylic acid and a tertiary nitrogen atom which enhanced its adsorption capacities as well as magnetic properties which ensured its easy removal from the solution using a magnet. The maximum uptake of Pb and Cu onto PN-Fe3O4-IDA was 0.36 and 0.75 mmol g-1 (at 318 K) respectively with the chemisorption process being the major reaction pathway for the processes. The synthesized adsorbent exhibits significant adsorption capacity for the selected pollutants as well as some unique features which promotes its use as an adsorbent for wastewater remediation processes.

Iminodiacetic acid functionalized magnetic peanut husk for the removal of methylene blue from solution: characterization and equilibrium studies.

A novel adsorbent PN-Fe3O4-IDA was developed by the chemical modification of magnetic peanut husk with iminodiacetic acid (IDA) and its efficacy for the sequestration of cationic dyes assessed using methylene blue (MB) as a model. This modification process enhanced the adsorption capacity of peanut husk as an adsorbent for dye sequestration and at the same time greatly minimized the adverse effects associated with its use in the pristine state. Results from the batch adsorption studies indicated that the uptake of MB onto PN-Fe3O4-IDA increased with MB concentration, contact time, temperature and pH whereas it decreased in the presence of some common salts. The pseudo-second-order kinetic model was observed to best describe the adsorption process which may greatly be influenced by the intra particle diffusion mass transfer. A maximum monolayer adsorption capacity of 43.5 mg g-1 was observed at 313 K according to the Langmuir model. There was good property of regeneration for MB-loaded PN-Fe3O4-IDA. Based on these results, as well as other unique features such as easy separation and preparation under benign environmental conditions, PN-Fe3O4-IDA exhibits great potential for the removal of MB and other cationic pollutants in practical applications with easy separation from solution using external magnet. Graphical abstract.

Uptake of micropollutant-bisphenol A, methylene blue and neutral red onto a novel bagasse-ß-cyclodextrin polymer by adsorption process.

The presence of emerging micropollutants and dyes in water resource has raised global concern about their intense effects to aquatic environments, ecosystem and human health in general. So far, various adsorbents have been suggested for reducing the levels of bisphenol A, methylene blue and neutral red contamination in wastewaters. However, a number of these adsorbents seemed to have low adsorptive capacities and regeneration performances. In view of these, batch experiment was performed to decontaminate these pollutants from aqueous solutions using an optimized bagasse-ß-cyclodextrin polymer (SB-ß-CD). Characterization studies of SB-ß-CD were performed using FTIR, pH point of zero charge, XRD and BET methods. Adsorption of BPA, MB and NR was favored at lower temperature (298 K) and pH of 7.0, 9.0 and 6.0, respectively. The maximum adsorption capacity of BPA, MB and NR at 298 K was 121, 963 and 685 mg g-1, respectively. Hydrogen bonding through host-guest inclusion and electrostatic interactions could respectively attribute to uptake of BPA and MB/NR onto SB-ß-CD. Adsorption kinetics of three pollutants followed pseudo-second-order model. Langmuir and Freundlich models were fitted to describe the adsorption of BPA and MB/NR, respectively. Thermodynamic parameters confirmed the occurrence of physical adsorption which is spontaneous and exothermic in nature. SB-ß-CD loaded with BPA and MB/NR was certainly reused by 75% ethanol and 0.1 mol L-1 HCl solutions, respectively. Novel SB-ß-CD showed better adsorptive capacity and regeneration performances; consequently can offers practical application for removal of BPA, MB and NR from wastewaters.