Investigating and assessing the risk of remaining toxins in cucumbers grown in fields and greenhouses in Mazandaran Province.

To address concerns regarding the potential health risks associated with residual chemicals in food products, this study aimed to assess the concentrations of residual Benomyl, Malathion, and Diazinon in cucumbers and evaluate the associated health risks for consumers. This descriptive study involved the collection of 100 cucumber samples from both field and greenhouse cultivation in Mazandaran Province. These samples were subsequently sent to the laboratory for analysis. Following sample preparation and digestion, we determined the levels of residual Malathion, Benomyl, and Diazinon using HPLC. The results showed an average residual Malathion concentration of 2.1 ± 0.04 mg/kg in field-grown cucumbers and 2.04 ± 1.5 mg/kg in greenhouse-cultivated cucumbers. Meanwhile, the average residual Diazinon concentration was 5.1 ± 0.2 mg/kg in field samples and 4.99 ± 3.23 mg/kg in greenhouse samples. The average concentrations of residual Benomyl were found to be 0.94 ± 0.65 mg/kg in field-grown cucumbers and 0.39 ± 0.2 mg/kg in greenhouse-cultivated cucumbers. Furthermore, a health risk assessment model was employed to evaluate the cumulative risk of these residual pesticides in cucumbers. The analysis revealed that residual Benomyl levels ranged from 0 to 24.33 mg/kg, while Malathion ranged from 0 to 9.25 mg/kg, and Diazinon ranged from 0 to 6.8 mg/kg. Notably, in some areas, the average concentration of all three pesticides exceeded the guidelines set by the WHO and the European Union. Additionally, the cumulative risk assessment (represented by MOET value of 2655) indicated that the combined presence of residual Malathion, Benomyl, and Diazinon in field-cultivated cucumbers posed a health risk. Based on current per capita consumption rates, the study's health risk index results raised concerns about the safety of consuming these residual byproducts. Given the growing use of chemicals in agricultural and horticultural practices, it is imperative to monitor residual pesticides to assess dietary intake and ensure consumer safety in food production.

Investigating the effects of vermicomposting process using Eisenia Fetida earthworms on the reduction of parasites population.

PURPOSE: The existence of parasite agents in natural organic fertilizers can lead to health problems and infection transmission. The aim of the present study was to survey the parasites' population reduction during the vermicomposting of the mixtures of municipal sewage sludge (SS) and cow dung (CD) using E. fetida earthworms. METHODS: The vermicomposting process was performed by using earthworms of E. fetida species. The composting process was conducted in 27 pilots for 3 months. The identification and counting of the parasites' population were carried out by Mac Master Slide, according to Bailenger method. RESULTS: The results indicated that the type and number of parasite elements decreased with increasing vermicomposting time. The cumulative removal percent of parasites for sewage sludge (96.10%) was more than the SS + CD (93.65%) and CD (92.93%) treatments. The results showed that after 90 days of vermicomposting, the highest cumulative reduction in the number of parasites was obtained for the treatments with 40 earthworms (98.48%), while the corresponding value for the treatments without earthworms was (88.66%). The statistical analysis indicated that in terms of the parasite's population, a significant difference was observed for the three kinds of compostable materials (P < 0.05), however, this difference was not significant for the three levels of the earthworms (P > 0.05). CONCLUSION: The results showed that the mixture of sewage sludge and cow dung in combination with sawdust could lead to greater and faster reduction in the parasite's population. In addition, the bio-transformed product can be used as useful manure.

Data on wastewater treatment plant by using wetland method, Babol, Iran.

Date in this paper highlights the applications of constructed horizontal surface flow (HF-CW) wetland with two different local plants (Louis latifoila and Phragmites -australis (Cav.) Trin) at the wastewater treatment plant in Babol city. This system was designed as an advanced treatment unit in field scale after the treatment plant. Parameters such as Total Dissolved Solid (TDS), Total Suspended Solid (TSS), Turbidity, Biological Oxygen Demand (BOD) and Chemical Oxygen Demand (COD), were investigated. The result shows that treatment efficiency increases with the passage of time. The efficiency of Phragmites planted setups in open environment was fairly good for all studied parameters (28.6% of TDS, 94.4% for TSS, 79.8% for turbidity, 93.7% for BOD and 82.6% for COD). The efficiency of the latifoila set up was also good, but lower than that of Phragmites (26.5% of TDS, 76.9% for TSS, 71.5% for turbidity, 79.1 for BOD and 68.8% for COD). In brief, the obtained dates show that using local plants in (HF-CW) wetland not only effectively reduces various contaminants from the effluent of the wastewater according to Effluent Guideline regulations (WHO & EPA), but it is also a cost- effective and environmentally friendly method. Also, it was calculated that in full scale operation [time (1 day) and a depth (0.3 m)], 8 ha of wetland was needed.

Performance, kinetic, and biodegradation pathway evaluation of anaerobic fixed film fixed bed reactor in removing phthalic acid esters from wastewater.

Emerging and hazardous environmental pollutants like phthalic acid esters (PAEs) are one of the recent concerns worldwide. PAEs are considered to have diverse endocrine disrupting effects on human health. Industrial wastewater has been reported as an important environment with high concentrations of PAEs. In the present study, four short-chain PAEs including diallyl phthalate (DAP), diethyl phthalate (DEP), dimethyl phthalate (DMP), and phthalic acid (PA) were selected as a substrate for anaerobic fixed film fixed bed reactor (AnFFFBR). The process performances of AnFFFBR, and also its kinetic behavior, were evaluated to find the best eco-friendly phthalate from the biodegradability point of view. According to the results and kinetic coefficients, removing and mineralizing of DMP occurred at a higher rate than other phthalates. In optimum conditions 92.5, 84.41, and 80.39% of DMP, COD, and TOC were removed. DAP was found as the most bio-refractory phthalate. The second-order (Grau) model was selected as the best model for describing phthalates removal.

Influence of bioaugmentation on biodegradation of phenanthrene-contaminated soil by earthworm in lab scale.

BACKGROUND: Use of earthworm to eliminate the phenanthrene from the soil (bioaccumulation) is developed as an economical method. Bioaugmentation of microorganism was used for promotion of bioaccumulation by earthworm. The aim of this study was to determine the bioaccumulation or biodegradation of phenanthrene by Eisenia fetida and bacterial consortium in polluted soil. METHODS: The amount of 0.4 kg of the polluted soil in the ratio of 10 and 30 mg phenanthrene per kg of dry soil was transferred into each pot. Afterwards, bacteria and earthworms were added to each pot in separate and combination. The samples were kept under field conditions, and the retention concentrations of phenanthrene were analyzed after 8 weeks. RESULTS: Results showed that the Eisenia fetida was able to significantly remove phenanthrene from the polluted soil samples. Bioaccumulation and bioaugmentation alone have the removal efficiency of 60.24% and 50.3%, respectively. In the combined mode, phenanthrene removal efficiency was 63.81%. CONCLUSIONS: The current study indicated that the use of earthworms, could improve both phenanthrene bioavailability and microbial activity, which led to enhancing removal of carbon-based pollutants.