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Phys Rev Lett ; 95(26): 268301, 2005 Dec 31.
Article in English | MEDLINE | ID: mdl-16486412

ABSTRACT

We examine the vitrification and melting of asymmetric star polymer mixtures by combining rheological measurements with mode coupling theory. We identify two types of glassy states, a single glass, in which the small component is fluid in the glassy matrix of the big one, and a double glass, in which both components are vitrified. Addition of small-star polymers leads to melting of both glasses, and the melting curve has a nonmonotonic dependence on the star-star size ratio. The phenomenon opens new ways for externally steering the rheological behavior of soft matter systems.


Subject(s)
Glass/chemistry , Microfluidics/methods , Models, Chemical , Polymers/chemistry , Computer Simulation , Phase Transition , Viscosity
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