Percussion drilling in glasses and process dynamics with femtosecond laser GHz-bursts.

We report for the first time to our knowledge on top-down percussion drilling of high-quality deep holes in different glasses with femtosecond laser pulses in GHz-burst mode. We reveal the dynamics of the percussion drilling process by pump-probe shadowgraphy and thermal camera imaging demonstrating that the drilling process in GHz-burst mode is fundamentally different from single-pulse processing and confirming the presence of thermal accumulation. Moreover, we show a comparison to drilling by femtosecond single-pulses containing an equal laser fluence in sodalime, alkali-free alumina-borosilicate, fused silica, and sapphire.

Systematic study of laser ablation with GHz bursts of femtosecond pulses.

We report on crater formation, line scribing and cavity milling experiments on Silicon, Copper, Aluminum and stainless steel with GHz bursts of femtosecond pulses. The intra-burst repetition rate has been varied between 0.88 and 3.52 GHz, the number of pulses per burst between 50 and 3200, the burst fluence between 8 and 80 J/cm2. For these experiments, a 100-W femtosecond GHz-burst laser has been developed on an industrial laser basis, delivering a total burst energy up to 1 mJ at 100 kHz, with an adjustable number of pulses per burst. The results highlight the conditions to obtain high-ablation efficiency, show how to optimize the machining quality and point out the burst duration as the relevant parameter for femtosecond GHz machining.

High-efficiency femtosecond ablation of silicon with GHz repetition rate laser source.

We report on silicon ablation with a 20 W GHz amplified femtosecond laser source. This novel laser delivers burst energies up to 400 µJ, providing flexible intra-pulse repetition rates of 0.88 or 3.52 GHz, up to 200 pulses with ∼350 fs pulse duration. High-efficiency, high-quality ablation can be achieved through optimally determining the number of pulses, intra-pulse repetition, and average pulse energy within a burst. Due to such optimization, we demonstrate a specific ablation rate of 2.5 mm3/min/W with a burst containing 200 pulses at 0.88 GHz, which is the highest one reported so far for fs laser ablation, to the best of our knowledge. GHz ablation is sensitive to the selection of laser parameters. We conceptually discuss the contributions of the pulses within a burst to heat-accumulation-based incubation and material ablation.

Multiscale grooved titanium processed with femtosecond laser influences mesenchymal stem cell morphology, adhesion, and matrix organization.

The femtosecond laser processing enabled the structuring of six types of surfaces on titanium-6aluminium-4vanadium (Ti-6Al-4V) plates. The obtained hierarchical features consisted of a combination of microgrooves and oriented nanostructures. By adjusting beam properties such as laser polarization, the width of the microgrooves (20 or 60 µm) and the orientation of the nanostructures (parallel or perpendicular to the microgrooves) can be precisely controlled. Mesenchymal stem cells (MSCs) grown on these structured surfaces produced cytoplasmic extensions with focal contacts, while on the smooth titanium, the cells were found to be well spread and without any focal contact 12 h postseeding. The 600-nm wide nanostructures on their own were sufficient to orient the MSCs. For the multiscale structured areas, when the orientation of the nanostructures was orthogonal in relation to the microgrooves, there was an important decrease in or even a loss of cell alignment signifying that cells were sensitive to the directional nanostructures in the microgrooves. At 7 days, cell proliferation was not affected but the direction of nanostructures controlled the matrix organization. The ultrafast laser, as a new method for producing micro-nanohybrid surfaces, is a promising approach to promote desired tissue organization for tissue engineering.

Electrochemical boron-doped diamond film microcells micromachined with femtosecond laser: application to the determination of water framework directive metals.

Planar electrochemical microcells were micromachined in a microcrystalline boron-doped diamond (BDD) thin layer using a femtosecond laser. The electrochemical performances of the new laser-machined BDD microcell were assessed by differential pulse anodic stripping voltammetry (DPASV) determinations, at the nanomolar level, of the four heavy metal ions of the European Water Framework Directive (WFD): Cd(II), Ni(II), Pb(II), Hg(II). The results are compared with those of previously published BDD electrodes. The calculated detection limits are 0.4, 6.8, 5.5, and 2.3 nM, and the linearities go up to 35, 97, 48, and 5 nM for, respectively, Cd(II), Ni(II) Pb(II), and Hg(II). The detection limits meet with the environmental quality standard of the WFD for three of the four metals. It was shown that the four heavy metals could be detected simultaneously in the concentration ratio usually measured in sewage or runoff waters.

Time-resolved imaging of laser-induced refractive index changes in transparent media.

We describe a method to visualize ultrafast laser-induced refractive index changes in transparent materials with a 310 fs impulse response and a submicrometer spatial resolution. The temporal profile of the laser excitation sequence can be arbitrarily set on the subpicosecond and picosecond time scales with a pulse shaping unit, allowing for complex laser excitation. Time-resolved phase contrast microscopy reveals the real part of the refractive index change and complementary time-resolved optical transmission microscopy measurements give access to the imaginary part of the refractive index in the irradiated region. A femtosecond laser source probes the complex refractive index changes from the excitation time up to 1 ns, and a frequency-doubled Nd:YAG laser emitting 1 ns duration pulses is employed for collecting data at longer time delays, when the evolution is slow. We demonstrate the performance of our setup by studying the energy relaxation in a fused silica sample after irradiation with a double pulse sequence. The excitation pulses are separated by 3 ps. Our results show two dimensional refractive index maps at different times from 200 fs to 100 µs after the laser excitation. On the subpicosecond time scale we have access to the spatial characteristics of the energy deposition into the sample. At longer times (800 ps), time-resolved phase contrast microscopy shows the appearance of a strong compression wave emitted from the excited region. On the microsecond time scale, we observe energy transfer outside the irradiated region.

Periodic nanoscale structures on polyimide surfaces generated by temporally tailored femtosecond laser pulses.

A strong influence of different pulse durations and double pulse delay times on the formation of periodic surface structures on polyimide were observed employing ultrashort laser pulses tailored on a sub-picosecond and picosecond time scale. Multi-photon, defect-related excitation mechanisms and thermal expansion of the polymer lattice correlated to a loss of long range order and polarisation memory were considered.

10 kHz water-cooled Ti :Sapphire femtosecond laser.

We demonstrate operation of a simple and reliable water-cooled femtosecond laser running at 10 kHz suitable for industrial micromachining applications. A laser geometry involving only a regenerative amplifier and delivering 3.5 W average power 60-fs pulses is compared to a more conventional architecture using an additional multi-pass amplifier. Both laser systems require a moderate pumping laser of ~30 W average power and deliver high-quality beams (M2<1.2).

Programmable focal spot shaping of amplified femtosecond laser pulses.

We describe the programmable spatial beam shaping of 100-kHz, 4-microJ amplified femtosecond pulses in a focal plane by wave-front modulation. Phase distributions are determined by a numerical iterative procedure. A nonpixelated optically addressed liquid-crystal light valve is used as a programmable wave-front tailoring device. Top-hat, doughnut, square, and triangle shapes of 20-microm size are obtained in a focal plane. Their suitability for femtosecond laser machining is demonstrated.