ABSTRACT
The possibility of using less expensive and nontoxic metals, such as copper, as substitutes for more expensive heavy metals in the synthesis of new transition-metal complexes to be used as sensitizers in dye-sensitized solar cells (DSSCs) has stimulated research in this field. The novel photoluminescent copper(I) complex bis(triphenylphosphane-κP)[trans-(±)-2,4,5-tris(pyridin-2-yl)-2-imidazoline-κ2N2,N3]copper(I) hexafluorophosphate, [CuI(C18H15N5)(C18H15P)2]PF6, has been successfully synthesized and characterized by IR and 1H NMR spectroscopy, as well as by single-crystal X-ray diffraction and thermogravimetric analysis. The complex showed interesting photophysical properties, which were studied experimentally in solution and in the solid state by UV-Vis and fluorescence spectroscopy. Density functional theory (DFT) calculations with dichloromethane as solvent reproduced reasonably well the HOMO and LUMO orbitals of the title compound.
ABSTRACT
The asymmetric unit of the title compound, (C12H16N3O)2[PdCl4]3, consists of a 4,4'-(1-aza-niumyl-2-hy-droxy-ethane-1,2-di-yl)dipyridinium dication and one and a half tetra-chloridopalladate(II) anions; the latter has inversion symmetry. In the cation, the pyridinium rings attached to the central 1-aza-niumyl-2-hy-droxy-ethane fragment show an anti conformation, as indicated by the central C-C-C-C torsion angle of -178.1â (4)°, and they are inclined to one another by 25.7â (2)°. In the crystal, the cations and anions are linked through N-Hâ¯Cl and O-Hâ¯Cl hydrogen bonds. There are also π-π contacts [centroid-centroid distance = 3.788â (3)â Å] and a number of C-Hâ¯O and C-Hâ¯Cl inter-actions are present, consolidating the formation of a three-dimensional structure.
ABSTRACT
In the crystal structure of the title complex, [YbCl(2)(C(18)H(15)N(5))(CH(3)OH)(2)]Cl, the pseudo-penta-gonal-bipyramidal coordination geometry of the Yb(III) cation is composed of three N atoms from one cis-(±)-2,4,5-tris-(pyridin-2-yl)imidazoline (HL) ligand, two O atoms from two methanol mol-ecules and two Cl(-) anions. Chains are formed along [010] through N-Hâ¯Cl, O-Hâ¯Cl and O-Hâ¯N hydrogen bonds.
ABSTRACT
The binuclear title compound, [Cu(2)(CH(3)CO(2))(4)(C(6)H(5)NO)], is located about a center of inversion. The Cu(II) atoms are connected [Cu-Cu = 2.6134â (5)â Å] and bridged by four acetate ligands. Their distorted octa-hedral coordination geometry is completed by a terminal pyridine N atom of a 3-pyridincarboxaldehyde ligand. In the crystal, the complex mol-ecules are linked by C-Hâ¯O hydrogen bonds, forming two-dimensional networks lying parallel to the ab plane. These networks are linked via C-Hâ¯O hydrogen bonds involving inversion-related 3-pyridinecarboxaldehyde ligands, forming a three dimensional supra-molecular architecture.