Microplastic Pollution in High Population Density Zones of Selected Rivers from Southeast Asia.

Southeast Asia (SEA) faces significant environmental challenges due to rapid population growth and economic activity. Rivers in the region are major sources of plastic waste in oceans. Concerns about their contribution have grown, but knowledge of microplastics in the area is still limited. This article compares microplastic levels in sediment and water from urban zones of three major rivers in SEA: Chao Phraya River (Thailand), Saigon River (Vietnam), and Citarum River (Indonesia). The study reveals that in all three rivers, microplastics were found, with the highest concentrations in Chao Phraya's water (80 ± 60 items/m3) and Saigon's sediment (9167 ± 4559 items/kg). The variations in microplastic sizes and concentrations among these rivers may be attributed to environmental factors and the exposure duration of plastic to the environment. Since these rivers are important water supply sources, rigorous land-use regulations and raising public awareness are crucial to mitigate plastic and microplastic pollution.

Unraveling the mechanism of iodate adsorption by anthocyanin-rich fruit waste as green adsorbents for Applications of radioactive iodine remediation in water environment.

In aquatic settings, radioactive iodine from nuclear waste can exist as iodate (IO3-). This study explored the efficiency and mechanism of IO3- adsorption by minimally modified anthocyanin-based adsorbents. Pomegranate peels and mangosteen pericarps were selected from an initial screening test and could remove over 70% of 10 mg/L IO3-. The adsorbents yielded adsorption capacity (q) of 9.59 mg/g and 2.31 mg/g, respectively, at room temperature. At 5 °C, q values increased to 14.5 and 5.13 mg/g, respectively. Pomegranate peels showed superior performance, with approximately 4 times the anthocyanin content of mangosteen pericarps. Both adsorbents took 120 min to reach adsorption equilibrium, and no desorption was observed after 8 days (I-131 half-time). Confirmation of physisorption was indicated by the fit of the pseudo-first-order reaction model, negative entropy (exothermic), and negative activation energy (Arrhenius equation). IO3- inclusion was confirmed through adsorbent surface modifications in scanning electron microscope images, the increased iodine content post-adsorption in energy-dispersive X-ray spectroscopy analysis, and alterations in peaks corresponding to anthocyanin-related functional groups in Fourier transform infrared spectroscopy analysis. X-ray absorption near-edge spectroscopy at 4564.54 eV showed that iodine was retained in the form of IO3-. Through the computational analysis, electrostatic forces, hydrogen bonds, and π-halogen interactions were deduced as mechanisms of IO3- adsorption by anthocyanin-based adsorbents. Anthocyanin-rich fruit wastes emerged as sustainable materials for eliminating IO3- from water.

Preparation of heterogeneous cation exchange membrane and its contributions in enhancing the removal of Ni2+ by capacitive deionization system.

Capacitive deionization (CDI), an emerging method to eliminate ions from water at a low cost, has garnered significant interest in recent years. This study evaluates the implication of cation exchange resin loading on the membrane via the nonsolvent-induced phase inversion method. After determining the quantity of resins efficiently loaded on the membrane, it was subsequently utilized as a cation exchange membrane in the membrane capacitive deionization (MCDI) unit to examine the performance removal of Ni2+. The results show that the amount of resins influenced the membrane structure and significantly improved the efficiency of Ni2+ removal. The sulfonic acid group show a strong intensity directly proportional to the quantity of resins based on the FTIR measurement. In conjunction with the enhanced resin amount, ion exchange capacity and water content were increased. Simultaneously, there was an observed elevation in the water contact angle and the roughness of the membrane surface with increased resin amount. In the MCDI unit, membrane M20 (20% by weight resin) was employed to elucidate its roles in the CDI unit, encompassing an examination of various concentrations and flow rates, with Ni2+ utilized as a test contaminant. The results demonstrated that using membrane M20 in the MCDI (MCDI-M20) unit consistently exhibited higher adsorption levels than the CDI unit, reaching 19.80 mg g-1 ACC in the MCDI-M20 unit, while CDI unit achieved 10.27 mg g-1 ACC at 200 mg L-1 Ni2+ concentration and a flow rate of 10 mL min-1 at 1.2 V. Additionally, Ni2+ concentrations and flow rates in CDI system had an evident impact on the duration of adsorption due to the mechanisms of ions transport on the membrane. This study suggests that employing the prepared membrane in the MCDI unit enhanced the removal of Ni2+ from the solution, contributing to sustainable development goals.

Microplastic contamination in Thai vinegar crabs (Episesarma mederi), giant mudskippers (Periophthalmodon schlosseri), and their surrounding environment from the Bang Pu mangrove forests, Samut Prakan province, Thailand.

The mangrove ecosystem becomes the receptacle for both land- and marine-based plastic waste. This study examines MPs contamination in the Bang Pu mangrove forests (BPMFs) in the inner Gulf of Thailand. For this, Thai vinegar crabs (TVCs) (Episesarma mederi) and giant mudskippers (GMs) (Periophthalmodon schlosseri) were investigated with their surrounding environment in both rainy and dry seasons. Two-step digestion was employed for biota samples. MPs abundance ranged from 7.5 ± 3.8 to 15.9 ± 6.7 items/individual in TVCs and 6.2 ± 5.0 to 10.6 ± 2.6 items/individual in GMs. MPs in small-size ranges (<0.5 mm) were predominant. Fiber MPs were mostly detected in the rainy season. Most MPs were transparent with polyethylene and polypropylene as dominant polymers in all samples. Bioaccumulation was not observed in GMs. The results indicated the imperiled status of MPs contamination in TVCs and GMs with contaminated surrounding environments.

Waste management developments in the last five decades: Asian perspective.

Solid waste management was explored in Asia's last five decades, and the issues and challenges were identified. Waste generation has increased in all nations in the previous 50 years, although more recently, a declining trend has been observed in Japan and Korea. The composition has been predominantly organic, with 45-50% being kitchen waste. Material extraction and productivity to sustain the most populous part of the globe are explained. Waste management technologies have evolved, with more nations slowly transitioning from landfills to using waste-to-energy options. However, landfilling and open dumps are still the major disposal choice in most developing countries in Asia. Thus, the issues of concern include dumpsites management, the informal sector, waste collection, open burning and food waste. Changes (increasing trends) in the recycling technologies and quantum are evident, as seen in several country reports from India, Indonesia, Japan, Malaysia, Singapore, South Korea, Thailand and Vietnam. There are several issues and challenges for recycling, which are explored in the text. Lastly, the drivers that propel the whole scenario of waste management in Asia and the evolution of these drivers over time are discussed. Several recommendations are included to achieve sustainable waste management in Asia.

Examining the endpoint impacts, challenges, and opportunities of fly ash utilization for sustainable concrete construction.

Fly ash has been widely used as a cement substitute to improve the sustainability of concrete. Although the advantages of fly ash have been extensively documented, there is a gap in understanding why its use in mass concrete applications remains low in some countries, such as the Philippines. Thus, this work aims to understand the issues that impede waste utilization, particularly fly ash in the concrete construction industry, quantify the impact of the current practice, and identify opportunities for sustainable fly ash utilization. Endpoint impact analysis was conducted through the life cycle using SimaPro 9.3 to quantify the impacts on human health, ecosystem, and resources of 31 concrete mixtures of low, normal, and high strength design with 0 to 20% fly ash as cement replacement. In-depth, semi-structured interviews with key stakeholders were undertaken to determine the institutional, economic, social, and technological challenges related to the utilization of waste materials in large-scale concrete construction. More than 90% of the total impact of concrete contributes to damage to human health, primarily caused by global warming and fine particulate matter. The use of fly ash at 20% replacement by weight of cement benefits resources more significantly than human health and the ecosystem. The use of chemical admixture to improve strength has a significant impact on resources. High fly ash replacement for normal and high-strength concrete has a greater reduction in all endpoint categories than for low-strength design. Recommendations are proposed to maximize the beneficial impact of using fly ash in the concrete industry.

Microplastics and heavy metals in a tropical river: Understanding spatial and seasonal trends and developing response strategies using DPSIR framework.

Microplastics (MPs) have become an increasingly popular topic in recent years due to the growing concern about their impact on human health and the environment. Rivers in Southeast Asia are the dominant source of plastics and MPs into the environment; however, research on MPs in rivers from the region is insufficient. This study aims to investigate the impacts of spatial and seasonal variations on the distribution of MPs with heavy metals in one of the top 15 rivers releasing plastics into oceans (Chao Phraya, Thailand). Findings from this study are analyzed using the Driver-Pressure-State-Impact-Response (DPSIR) framework for proposing strategies to minimize plastic and MPs in this tropical river. Spatially, most MPs were detected in the urban zone, while the lowest was in the agricultural zone. Also, MP levels in the dry season are higher than at the end but lower than at the beginning of the rainy season. MPs with fragment morphology were mainly found in the river (70-78 %). Polypropylene was found with the highest percentage (54-59 %). MPs in the river were mostly detected in the size range of 0.05-0.3 mm (36-60 %). Heavy metals were also found in all MPs collected from the river. Higher metal concentrations were detected in the agricultural and estuary zones in the rainy season. Potential responses, including regulatory and policy instruments, environmental education, and environmental cleanups, were drawn from the DPSIR framework.

Comparative environmental assessment of low and high CaO fly ash in mass concrete mixtures for enhanced sustainability: Impact of fly ash type and transportation.

The effect of fly ash type on the sustainability of concrete mixtures has yet to be quantified. This study aims to assess the environmental impacts of low calcium oxide (CaO) and high CaO fly ash in mass concrete mixtures from Thailand. The study analyzed 27 concrete mixtures with varying percentages of fly ash as a cement replacement (0%, 25%, and 50%) for 30 MPa, 35 MPa, and 40 MPa compressive strengths at specified design ages of 28 and 56 days. Sources of fly ash have been located between 190 km and 600 km away from batching plants. The environmental impacts were assessed using SimaPro 9.3 software. The global warming potential of concrete is reduced by 22-30.6% and 44-51.4% when fly ash, regardless of type, is used at 25% and 50%, respectively, in comparison with pure cement concrete. High CaO fly ash has more environmental benefits than low CaO fly ash when utilized as a cement substitute. The reduction in environmental burden was most significant for the midpoint categories of mineral resource scarcity (10.2%), global warming potential (8.8%), and water consumption (8.2%) for the 40 MPa, 56-day design with 50% fly ash replacement. The longer design age (56 days) for fly ash concrete showed better environmental performance. However, long-distance transport significantly affects ionizing radiation and ecotoxicity indicators for terrestrial, marine, and freshwater environments. Furthermore, the results show that a high cement replacement level (50%) may not always have a reduced environmental impact on mass concrete when considering long-distance transportation. The critical distance calculated based on ecotoxicity indicators was shorter than those calculated using global warming potential. The results of this study can provide insights for developing policies to increase concrete sustainability using different types of fly ash.

Occurrence and spatial distribution of microplastic contaminated with heavy metals in a tropical river: Effect of land use and population density.

Microplastics are of concern due to their potential environmental risks. This research aims to find the effect of land use (agriculture, urban, and aquaculture) and population density on the abundance of microplastics contaminated with heavy metals in surface water and sediment of the Chao Phraya River in Thailand. Results indicated that population density is directly correlated with increased microplastic abundance. Most microplastics were found in the urban zone (water: 80 ± 38 items/m3 and sediment: 62 ± 11 items/kg) and were small fragments (0.05 to 0.3 mm). Polymer types of polypropylene and polyethylene were commonly found. Heavy metals of Cr, Cu, Cd, Pb, Zn, Ni, and Ti were detected in microplastics in water and sediment, with Cu, Pb, and Zn being the most dominant. Heavy metals in microplastics were highest in the agriculture zone. In general, the presence of metals on microplastics may potentially impact the ecosystem and human health.

Assessment of the environmental sustainability of municipal solid waste valorization by anaerobic digestion and by composting in Sri Lanka.

Municipal solid waste management (MSWM) remains a major concern in Sri Lanka, and various treatment methods have been deployed. Though both composting and anaerobic digestion have been effective in environmental decontamination, there are other environmental issues that should be assessed. This study aimed to evaluate the environmental impacts of a full-scale composting plant and an anaerobic digestion plant for managing the organic fraction of municipal solid waste (OFMSW) in Sri Lanka using life cycle assessment (LCA). The results show that OFMSW composting causes unfavourable environmental impacts on damage categories such as human health (6.77 × 10-4 disability-adjusted life years (DALY) tonne-1 OFMSW), ecosystem quality (1.90 × 10-6 species.year tonne-1 OFMSW), and resource scarcity (3.66 × 10-1 United States Dollar (USD) tonne-1 OFMSW). Anaerobic digestion also leads to unfavourable impacts on human health (2.13 × 10-4 DALY tonne-1 OFMSW) and ecosystem quality (6.46 × 10-7 species.year tonne-1 OFMSW). However, the impact on resource scarcity (-3.85 × 10-2 USD tonne-1 OFMSW) was avoided due to electricity production via anaerobic digestion. Specifically, the treatment of OFMSW by anaerobic digestion resulted in a reduction by 68.3% in the total environmental load as compared to composting. It can be concluded that out of the two existing systems investigated, anaerobic digestion has a more favourable environmental impact than composting.

Unraveling microplastics removal in wastewater treatment plant: A comparative study of two wastewater treatment plants in Thailand.

Wastewater treatment plants (WWTPs) are considered as a problematic pathway for microplastics (MPs) entering the oceans. This study compares the efficiency of MP removal in two different WWTPs (A1 and A2) with a conventional treatment system located in Bangkok, Thailand. WWTP-A2 is equipped with a pilot-scale ultrafiltration (UF) as a final polishing step. The number of MPs in the influent entering A1 and A2 was 16.55 ± 9.92 and 77.00 ± 7.21 MP/L, respectively. The average of 3.52 ± 1.43 and 10.67 ± 3.51 particles per L was found in the effluent discharged from A1 and A2, respectively, to nearby canals. The removal efficiency of WWTP-A2 built as a closed underground system was shown to be up to 86.14% which is more efficient than the conventional WWTP (A1). MPs were subsequently removed by a UF unit which resulted in a removal efficiency of 96.97%. However, when a large volume of treated wastewater volume is considered, a high concentration of MPs is discharged daily with the final effluent if the efficiency remains the same. The size fraction of 0.5-0.05 mm contributed to the largest proportion of MPs, and fibers were detected as the dominant group at both study sites. Results from a Fourier Transform Infrared Spectroscopy (FT-IR) confirmed that most fibers were polyethylene terephthalate (PET) derived from clothes. MPs retained in the sludge ranged from 2.63 × 104 to 4.74 × 104 particles per kilogram of dry sludge. A significant number of MPs can spread further to the environment by soil application. The results of the study indicate that the design of WWTPs and the addition of advanced tertiary treatment can improve MP removal efficiency of a WWTP. Moreover, the absence of a primary sedimentation tank in both treatment plants may influence the removal efficiency.

Investigation of microplastic contamination in blood cockles and green mussels from selected aquaculture farms and markets in Thailand.

Recent studies have indicated that bivalves are bioindicators for microplastic pollution since they are filter feeders and accumulate microplastics (MPs) during their feeding process. This study focused on the investigation of MPs in blood cockles (Tegillarca granosa) and green mussels (Perna viridis) from selected aquaculture farms and markets in Thailand. The abundance of MPs was identified by fluorescence microscopy with Nile Red tagging and the polymer detection by micro-Fourier Transform Infrared Spectroscopy (micro-FTIR). The number of MPs in blood cockle samples from the Khlong Dan market and the BangBo aquaculture farm was 11 ± 5 and 6 ± 1 particles/individual, respectively. For green mussel samples, the number of MPs from the Talaad Thai market and the Sriracha fisheries research station was 96 ± 19 and 11 ± 7 particles/individual, respectively. The results of the study indicate that the number of MPs in bivalve samples from the markets is much higher than in the aquaculture farms. This probably is due to the contamination of MPs in bivalves during the packaging and transportation processes. However, further studies are needed to confirm this. The predominant MPs were fragments and fibres with a size range of 0.05-0.3 mm. Most polymers were polypropylene, polyethylene, copolymer, polyester, and nylon. In brief, this study showed the contamination of MPs in bivalves cultivated for human consumption. The accumulation of MPs in these marine bivalves can lead to the biomagnification of MPs along the food chain. This can impact food safety and human health.

Comparative study of the environmental impacts of used cooking oil valorization options in Thailand.

Used cooking oil (UCO) is a valuable resource that can be utilized in different ways. Appropriate management of UCO waste can provide environmental and economic benefits, compared to improper disposal practices. This study assessed the environmental impacts of potential UCO valorization options in Thailand. Altogether, 14 scenarios, including 10 for alternative energy recovering processes (S1-10) and other options such as soap production (S11), use in dry pig feed (DPF) production (S12), synthesis of plastics (S13) and polyol (S14), were considered. The defined system boundaries for each scenario include pretreatment, material and energy consumption, and waste treatment stages for the treatment of 1000 kg UCO. Environmental impacts in terms of global warming potential (GWP), freshwater eutrophication potential (FEP), fossil resource scarcity (FRS), and freshwater, terrestrial, and marine eco-toxicity (FE, TE, and ME, respectively) were analyzed using the ReCiPe Midpoint (H) method. The results revealed that all the current waste valorization options create an environmental burden and contribute towards GWP. Scenarios 7 and 10 showed environmental credits for FEP, FE, and ME indicators while scenario 9 did so for FRS. The processes direct energy consumption resulted in the highest contribution to GWP in Scenarios 1, 5-8, 10, 12, and 13. Environmental effects of material consumption and waste treatments were found to be the highest in bio-oil and DPF production, respectively. However, co-products produced could not offset the burden created by energy and material consumption. Overall, the results showed better environmental performance from energy recovery-based UCO management options compared to alternative processes.

Environmental impact assessment of organic fraction of municipal solid waste treatment by anaerobic digestion in Sri Lanka.

The management of organic fraction of municipal solid waste (OFMSW) has continued to be a significant challenge in Sri Lanka. Anaerobic digestion is one of the management options of OFMSW. However, it generates unavoidable environmental impacts that should be addressed. The present study focuses to assess the environmental impact of a full-scale anaerobic digestion plant in Sri Lanka from a life cycle perspective. The inventory data were obtained from direct interviews and field measurements. Environmental burdens were found to be in terms of global warming potential (230 kg CO2 eq) ozone formation on human health (6.15 × 10-6 kg NOx eq), freshwater eutrophication (2.92 × 10-3 kg P eq), freshwater ecotoxicity (9.27 × 10-5 kg 1,4 DCB eq), human carcinogenic toxicity (3.98 × 10-4 kg 1,4 DCB eq), land use (1.32 × 10-4 m2 a crop eq) and water consumption (2.23 × 10-2 m3). The stratospheric ozone depletion, fine particulate matter formation, ozone formation on terrestrial ecosystems, terrestrial acidification, marine eutrophication, ecotoxicity (terrestrial and marine), human non-carcinogenic toxicity, mineral resource scarcity and fossil resource scarcity, were avoided due to electricity production. Results show that the direct gaseous emissions and digestate generation should be addressed in order to reduce the burdens from the anaerobic digestion plant. Finally, the results of the study could help in policy formation and decision-making in selecting future waste management systems in Sri Lanka.

Insights on microbial fuel cells for sustainable biological nitrogen removal from wastewater: A review.

Microbial fuel cells (MFCs) have emerged as a promising technology for energy-efficient wastewater treatment. The feasibility of integrating biological nitrogen removal into MFC systems has been reported. However, better pollutant removal efficiency and power production need to be achieved at a lower cost for a sustainable wastewater treatment system. The objective of this paper is to critically review the nitrogen removal process in various MFC configurations, factors that influence this process, and challenges that should be overcome in future studies. Based on the results of the review, shortcut nitrification-autotrophic denitrification in an MFC is an option as it minimizes the aeration energy and C/N ratio requirement; however, it is necessary to evaluate the N2O emission further. Another attractive option is the heterotrophic anodic denitrification process as it demonstrates the potential for free-buffer MFCs, but the nitrogen removal efficiency at low C/N ratios needs improvement. Bacteria population in MFC system also plays an essential role in both contaminant removal and electricity generation. It can be concluded that MFCs can be a low cost, sustainable solution for the treatment of wastewater and removal of nitrogen. Moreover, selection of MFC configuration will depend on the nature of the wastewater.

Mechanistic understanding of the increased photoactivity of TiO2 nanosheets upon tantalum doping.

Anatase TiO2 is doped with Ta cations through a hydrothermal route. Based on X-ray photoelectron spectroscopy and X-ray absorption near-edge structure spectroscopy, the Ta dopants exist in the 5+-oxidation state. The oxidation state is insensitive to the Ta loading amount. Extended X-ray absorption fine structure spectroscopy confirms that the local structure around Ta cations is not identical between the Ta-doped samples. The Ta-O distance monotonically increases with the Ta loading amount due to a gradually expanding lattice. The Ta-doped samples show higher activity than pristine TiO2 for photomineralizing recalcitrant organics. The enhanced photocatalytic activity is proposed to be due to an enhanced population of photoexcited electrons, as probed using light-induced IR absorption spectroscopy, and an extended electron lifetime, as probed using time-resolved microwave conductivity, which are associated with the formation of Ti3+ defect states acting as shallow electron traps. The maximum photocatalytic activity is observed for TiO2 doped with 2 mol% of Ta, which shows enhancement of mineralization efficiency (about 3 times) and enhancement of electron population (up to 20 times), as compared to those of pristine TiO2. The fundamental question of why a proper metal doping into TiO2 increases photocatalytic activity is discussed in this study.

Microplastics Contamination in Commercial Green Mussels from Selected Wet Markets in Thailand.

Mussels have been identified as sentinel organisms (around the world) that indicate microplastic (MP) pollution. Since they are filter feeders, they easily uptake MPs. Mussels sold in commercial markets have been identified as an ideal way to directly quantify human exposure to MPs through seafood consumption. There are no studies reported on MP contamination of market-sold species in Thailand. This study investigates the level of MP contamination in market-sold green mussels, which is a popular seafood in Thailand. A total of 90 green mussels (Perna viridis) collected from three markets were analyzed for the number, polymer types, and morphology of the MPs. Fourier-Transform Infrared Micro-Spectroscopy (micro-FTIR) analysis was used for polymer identification. Nile Red (NR) tagging was used for the enumeration of MPs. MPs were widely discovered in green mussels from all three markets with 100% detection frequency. The average abundance of MPs in green mussels was quantified as 7.32 ± 8.33 items/mussel and 1.53 ± 2.04 items/g (wet weight). Ethylene/propylene copolymer followed by low-density polyethylene (PE-LD), polypropylene (PP), and polyethylene terephthalate (PET) were found. Fragments (75.4%) were the most common morphotype, followed by fibers (24.6%). Results indicate that the consumption of green mussels as a food can be one of the exposure pathways for the Thai population. Moreover, smaller size MPs were predominant, which are reported to cause higher impacts.

Reuse of waste sludge from water treatment plants and fly ash for manufacturing of adobe bricks.

Reuse of sludge from a water treatment plant and fly ash for the manufacturing of adobe brick is a feasible approach for practical applications due to the numerous benefits from the cost savings of construction materials and the reduction of environmental pollution. In this study, sludge from a groundwater treatment plant and fly ash from a thermal power plant were used as alternative aggregates to replace clay, a traditional component for brick making. The main objective of this study is to produce adobe bricks by using hydraulic press technology. The optimum aggregate composition was investigated by determining the compressive strength according to Vietnam national standard TCVN 6355:1-2009. Other supplementary materials, including cement, liquid glass, and polypropylene fibers, were used as additives and adhesives. Results showed that a 2-hole brick product (8 × 4 × 8 cm) with strength M 4.0 satisfied the national quality standard, TCVN 6477-2016. In addition, the aggregate composition (wt%) as sludge: cement: fly ash: polypropylene fibers of 50 : 35: 15 : 0.5%/m3 aggregates was found to be the optimum ratio. This product shows a medium compressive strength that is appropriate in the construction of walls or fences in industrial factories or households. The results obtained in this study show a promising approach for the brick-making industry in Vietnam. A large amount of sludge can be reused as an alternative material to reduce the product price and achieve natural resource conservation.

Circulation of anodic effluent to the cathode chamber for subsequent treatment of wastewater in photosynthetic microbial fuel cell with generation of bioelectricity and algal biomass.

Synthetic wastewater containing 1500 mg L-1 of COD was treated in the anode chamber for 5, 10, and 20 d. An anode chamber was conducted under anaerobic conditions with mixed culture bacteria inoculum attached to the anode. Anodic effluent was transferred to the cathode chamber for further treatment for 5, 10, and 20 d as the growth medium of Chlorella vulgaris. The microalgal photosynthesis process provided oxygen for the cathodic reaction. In 5 d of anodic hydraulic retention time (HRT), the effluent contained high COD, resulting in low power generation in the P-MFC due to the heterotrophic metabolism carried out by microalgae diminishing photosynthesis. However, high biomass productivity up to 0.649 g L-1 d-1 was obtained in the subsequent treatment of 5 d in the cathode chamber. An anodic HRT of 10 d resulted in higher power generation (0.0254 kWh kg-1 COD), and higher COD removal efficiency up to 60%. A further 10 d treatment in the cathode chamber increased the COD removal efficiency up to 74%. Anode and cathode chambers combined removed 79% of NH4+-N concentration from the original synthetic wastewater within 20 d. This study demonstrated that the anodic effluent of the P-MFC can be utilized in the cathode chamber as a growth medium for microalgae if conducted with appropriate HRT in the anode. P-MFC provides a promising sustainable solution for wastewater treatment while generating electricity and algal biomass as by-products.

ZnO nanoparticles for photodegradation of humic acid in water.

Humic acid (HA) is the most important precursor of toxic disinfection byproducts upon chlorination. Removing HA from water body is therefore critical in drinking water acquisition. In this research, ZnO nanoparticles are employed for photocatalysis under UV light at neutral pH to remove HA from a water environment. Almost 100% degradation of HA was achieved using 0.3 g/L of ZnO in 180 min with UV-A and UV-C light. Under identical experimental conditions, total organic carbon (TOC) removals reach 67% and 21% with UV-A and UV-C light, respectively. A higher degree of mineralization of HA is achieved with UV-A light although the degradation of HA is slightly better with UV-C light. This indicates that ZnO/UV-A has relatively low selectivity to degrade different compounds, including various intermediates from HA degradation. The use of UV-A light is therefore recommended for ZnO as it possesses higher mineralization ability. Negligible TOC is observed on the ZnO surface after photocatalytic reactions. In contrast, the adsorption of HA in dark conditions reaches 42% in 180 min. This strongly indicates that the adsorption of HA plays an important role in the photocatalytic degradation of HA, but it is not the main process for HA removal.