Applications of biochar in sulfate radical-based advanced oxidation processes for the removal of pharmaceuticals and personal care products.

Recently, biochar (BC) has been increasingly used as a catalyst for the degradation of 'emerging pollutants' (EPs). Pharmaceuticals and personal care products (PPCPs), which come under 'EPs', can be harmful to the aquatic ecosystem despite being present in very low concentrations (ng/L-µg/L). Advanced oxidation processes (AOPs), which produce sulfate radical (SR-AOPs), show a great potential to degrade PPCPs effectively from wastewater. It is mainly due to the higher stability, long half-lives and better non-selectivity of SO4• - compared with AOPs with •OH generation. Furthermore, research focus is now given on AOPs coupled with BC-supported catalyst to enhance the degradation of PPCPs because of quicker generation of radicals (•OH, SO4•-) by the activation of persulfate (PS) and peroxymonosulfate (PMS). This article sheds light on the catalytic ability of BC after its physical and chemical modifications such as acid/alkali treatment and metal doping. The role of persistent free radicals (PFRs) in the BC for effective removal of PPCPs has been elaborated. Its potential applications in synthetic as well as real wastewater have also been discussed.