ABSTRACT
Over the past several decades, the fabrication of novel ceramic nanofibers applicable in different areas has been a frequent focus of scientists around the world. Aiming to introduce novel ceramic core-shell nanofibers as a magnetic solid acid catalyst, Fe2O3@SiO2-SO3H magnetic nanofibers were prepared in this study using a modification of Fe2O3@SiO2 core-shell nanofibers with chlorosulfonic acid to increase the acidic properties of these ceramic nanofibers. The products were characterized by scanning electron microscope (SEM), transmission electron microscope (TEM), energy dispersive X-ray spectroscope (EDS), vibrating sample magnetometer (VSM), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR). The prepared nanofibers were used as catalysts in formamide and formamidine synthesis. The treatment of aqueous formic acid using diverse amines with a catalytic amount of Fe2O3@SiO2-SO3H nanofibers as a reusable, magnetic and heterogeneous catalyst produced high yields of corresponding formamides at room temperature. Likewise, the reaction of diverse amines with triethyl orthoformate led to the synthesis of formamidine derivatives in excellent yields using this novel catalyst. The catalytic system was able to be recovered and reused at least five times without any catalytic activity loss. Thus, novel core-shell nanofibers can act as efficient solid acid catalysts in different organic reactions capable of being reused several times due to their easy separation by applying magnet.
ABSTRACT
This study aimed to investigate parameters affecting the electrospinning of poly (vinyl alcohol) (PVA)/kefiran composite nanofibers. Accordingly, PVA/kefiran composite nanofibers were produced using the electrospinning of PVA, kefiran blend solutions under various electrospinning parameters (such as applied voltage, nozzle-to-collector distance, and polymer injection rate), and solution parameters (such as the ratio of polymers). PVA and kefiran solutions were prepared in 8% and 6% w/w, respectively. Kefiran was blended with PVA solution in different proportions: 70:30, 60:40, 50:50, 40:60, and 30:70. According to the scanning electron microscope (SEM) images, kefiran mixed with PVA in 40:60 ratios produced the best result in nanofiber production. Then, device parameters such as voltage (12, 15, 18, and 20 kV), distance (120, 150, 170, and 200 mm), and polymer injection rates (1, 1.5, 2, and 2.5 mL/h) were changed. The investigation of SEM images showed that the optimal condition for the fabrication of nanofibers was 18 kV, 200 mm, and 1 mL/h. The nanofibers produced in the optimal condition were uniform without knots or adhesion in a small diameter. It was also found that concentration can be regarded as the most effective parameter affecting the diameter of nanofibers. Moreover, the transmission electron microscopy (TEM) image proved that phase separation did not occur between the two polymers. Graphical abstract: Kefiran biopolymer extracted from fermented milk was used in fabrication of PVA/kefiran composite nanofibers using the electrospinning method.
ABSTRACT
Electrospinning is one of the most successful and efficient techniques for the fabrication of one-dimensional nanofibrous materials as they have widely been utilized in multiple application fields due to their intrinsic properties like high porosity, large surface area, good connectivity, wettability, and ease of fabrication from various materials. Together with current trends on energy conservation and environment remediation, a number of researchers have focused on the applications of nanofibers and their composites in this field as they have achieved some key results along the way with multiple materials and designs. In this review, recent advances on the application of nanofibers in the areas-including energy conversion, energy storage, and environmental aspects-are summarized with an outlook on their materials and structural designs. Also, this will provide a detailed overview on the future directions of demanding energy and environment fields.
