Ultraflexible Corrugated Monocrystalline Silicon Solar Cells with High Efficiency (19%), Improved Thermal Performance, and Reliability Using Low-Cost Laser Patterning.

Flexible solar cells have received growing attention recently because of their ever-increasing range of applications. Here, the development of ultraflexible, lightweight, and high efficiency (19%) monocrystalline silicon solar cells with excellent reliability, mechanical resilience, and thermal performance is demonstrated by applying a corrugation method combined with laser patterning. The flexing mechanism converts large-scale rigid photovoltaic cells with interdigitated back contacts (IBCs) into a flexible version with a preserved efficiency. The corrugation technique is based on the formation of patterned grooves in active silicon to achieve ultraflexibility. As a result, islands of silicon with different shapes are obtained which are interconnected through the IBCs. Multiple corrugation patterns such as linear, honeycomb, and octagonal designs are studied, each resulting in different flexing capabilities in terms of flexing directionality and minimum bending radius, in addition to providing an atypical appearance with an aesthetic appeal. The corrugation method is shown to improve thermal dissipation (14.6% lower temperature) and to relieve the thermal mismatch challenge compared to the rigid cells because of the finlike architecture. Finally, encapsulation using a transparent polymeric material enables a robust performance of the flexible cells when exposed to different environmental conditions such as acid rain, snow, and mechanical shocks.

Solution processes for ultrabroadband and omnidirectional graded-index glass lenses with near-zero reflectivity in high concentration photovoltaics.

Concentrator photovoltaic (CPV) systems, where incident direct solar radiation is tightly concentrated onto high-efficiency multi-junction solar cells by geometric optical elements, exhibit the highest efficiencies in converting the sun's energy into electric power. Their energy conversion efficiencies are greatly limited, however, due to Fresnel reflection losses occurring at three air/optics interfaces in the most sophisticated dual-stage CPV platforms. This paper describes a facile one-step wet-etching process to create a nanoporous surface with a graded-index profile on both flat and curved glasses, with capabilities of achieving ~99% average transmission efficiency in a wide wavelength range from 380 nm to 1.3 µm and for a wide range of incident angles up to ±40° regardless of the polarization state of incident sunlight. The simplicity of the etching process remarkably increases their versatility in various optical elements that require unconventional form factors such as Fresnel lenses and microlens arrays, and/or demanding curvatures along with much reduced dimensions such as ball lenses. Etched glass surfaces on two-stage optical concentrating systems yield enhancements in total optical transmission efficiencies by 13.8% and in the photocurrent by 14.3%, as experimentally determined by measurements on microscale triple-junction solar cells. The presented strategy can be widely adapted in a variety of applications such as image sensors, display systems, and other optoelectronic devices.

Concentrator photovoltaic module architectures with capabilities for capture and conversion of full global solar radiation.

Emerging classes of concentrator photovoltaic (CPV) modules reach efficiencies that are far greater than those of even the highest performance flat-plate PV technologies, with architectures that have the potential to provide the lowest cost of energy in locations with high direct normal irradiance (DNI). A disadvantage is their inability to effectively use diffuse sunlight, thereby constraining widespread geographic deployment and limiting performance even under the most favorable DNI conditions. This study introduces a module design that integrates capabilities in flat-plate PV directly with the most sophisticated CPV technologies, for capture of both direct and diffuse sunlight, thereby achieving efficiency in PV conversion of the global solar radiation. Specific examples of this scheme exploit commodity silicon (Si) cells integrated with two different CPV module designs, where they capture light that is not efficiently directed by the concentrator optics onto large-scale arrays of miniature multijunction (MJ) solar cells that use advanced III-V semiconductor technologies. In this CPV+ scheme ("+" denotes the addition of diffuse collector), the Si and MJ cells operate independently on indirect and direct solar radiation, respectively. On-sun experimental studies of CPV+ modules at latitudes of 35.9886° N (Durham, NC), 40.1125° N (Bondville, IL), and 38.9072° N (Washington, DC) show improvements in absolute module efficiencies of between 1.02% and 8.45% over values obtained using otherwise similar CPV modules, depending on weather conditions. These concepts have the potential to expand the geographic reach and improve the cost-effectiveness of the highest efficiency forms of PV power generation.