Green synthesize of nano-MOF-ethylcellulose composite fibers for efficient adsorption of Congo red from water.

Two novel MOF- ethyl cellulose (EC)- based nanocomposites have been designed and synthesized in water by electrospinning and applied for adsorption of congo red (CR) in water. Nano- Zeolitic Imidazolate Framework-67 (ZIF-67), and Materials of Institute Lavoisier (MIL-88A) were synthesized in aqueous solutions by a green method. To enhance the dye adsorption capacity and stability of MOFs, they have been incorporated into EC nanofiber to prepare composite adsorbents. The performance of both composites in the absorption of CR, a common pollutant in some industrial wastewaters, has then been investigated. Various parameters including initial dye concentration, the dosage of the adsorbent, pH, temperature and contact time were optimized. The results indicated 99.8 and 90.9% adsorption of CR by EC/ZIF-67 and EC/MIL-88A, respectively at pH = 7 and temperature at 25 °C after 50 min. Furthermore, the synthesized composites were separated conveniently and successfully reused five times without significant loss of their adsorption activity. For both composites, the adsorption behavior can be explained by pseudo-second-order kinetics, Intraparticular diffiusion and Elovich models demonstrated that the experimental data well matched to the pseudo-second-order kinetics. Intraparticular diffiusion model showed that the adsorption of CR on EC/ZIF-67 and EC/MIL-88a took place in one and two steps, respectively. Freundlich isotherm models and thermodynamic analysis indicated exothermic and spontaneous adsorption.

Preparation and characterization of stable core/shell Fe3O4@Au decorated with an amine group for immobilization of lipase by covalent attachment.

The self-assembly approach was used for amine decoration of core/shell Fe3O4@Au with 4-aminothiophenol. This structure was used for covalent immobilization of lipase using a Ugi 4-component reaction. The amine group on the structure and carboxylic group from lipase can react in the Ugi reaction and a firm and stable covalent bond is created between enzyme and support. The synthesized structure was fully characterized and its activity was explored in different situations. The results showed the pH and temperature stability of immobilized lipase compared to free lipase in a wide range of pH and temperature. Also after 60 days, it showed excellent activity while residual activity for the free enzyme was only 10%. The synthesized structure was conveniently separated using an external magnetic field and reused 6 times without losing the activity of the immobilized enzyme.

Preparation and characterization of nanofibrous metal-organic frameworks as efficient catalysts for the synthesis of cyclic carbonates in solvent-free conditions.

Environmental concerns, particularly global warming, represent serious threats to public health globally. Metal-organic frameworks (MOFs) are innovative materials with prominent features such as ultrahigh surface area, high porosity and tunable cavities, which make them unique materials both in adsorption of carbon dioxide and catalysis. The design of new nanocomposites by using metal-organic frameworks as building materials has received broad attention recently. Here, nanocrystals of two unique MOF structures (UiO-66 and ZIF-67) were incorporated into electrospun polyvinyl alcohol (PVA) and polystyrene (PS) fibers (noted as MOFibers) by an ex situ method, to transform non-toxic, abundant, economical and renewable CO2 gas to cyclic carbonates in a solvent-free medium. In order to improve the composites' performance, different electrospinning parameters, including applied voltage, flow rate, collection distance, PVA and PS weight fraction in solution, and MOF weight fraction relative to the polymer, were intensively investigated. The synthesized samples were characterized by multiple techniques, such as FTIR, XRD, SEM, UV-vis and TGA, as well as N2 and CO2 adsorption measurement. It was found that all of the composites show properties combining the advantages of MOFs and polymers, such as thermal, chemical, and mechanical stability, structural flexibility, lightweight, adsorption performance and catalytic properties. Additionally, all systems were environment-friendly and the PVA/MOF fibers were easily separated and recycled for consecutive cycles.

Ultrafine Pt nanoparticles supported on a dendrimer containing thiol groups: an efficient catalyst for the synthesis of benzimidazoles and benzothiazoles from benzyl alcohol derivatives in water.

A novel and unique platform was prepared based on a dendrimer containing thiol groups supported on nanosilica (nSTDP), and ultrafine platinum nanoparticles were synthesized and immobilized on the thiol decorated branches of nSTPD. The new catalyst, (Ptnp@nSTDP), was characterized by different techniques such as FE-SEM, TEM, ICP, XPS and DR UV-vis. This heterogeneous catalyst presented an outstanding performance for the synthesis of benzimidazole and benzothiazole derivatives through a reaction between benzyl alcohol derivatives and 2-aminothiophenol or 1,2-phenylenediamine. No requirement for the pre-reduction of catalysts and using water as a green solvent make it an individual catalyst for these reactions. Furthermore, the catalyst can be easily recovered and reused five consecutive times in the production of benzimidazoles and benzothiazoles without significant leaching of Pt and loss of its activity which illustrated the chemical stability of the catalyst during the reaction.