ABSTRACT
Sansevieria trifasciata fibre (STF) is a lignocellulosic material which could be utilised for reinforcement composites. Surface modification is often needed to improve the compatibility of hydrophilic STF and hydrophobic resin. In this study, treatments for natural fibres to attain superhydrophobic properties were carried out using silica nanoparticles and fluorosilane. Sansevieria trifasciata fibres (STF) were subjected to treatment by deposition of silica (SiO2) nanoparticles which were prepared by the sol-gel method, then followed by modification with fluorosilane, namely 1H, 1H, 2H, 2H-perfluorooctyltriethoxysilane (PFOTS). The presence of SiO2 nanoparticles and PFOTS were evaluated using Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDX). The crystallisation properties and thermal behaviour of STF were studied through X-ray diffraction (XRD) and thermogravimetric (TGA) analysis, respectively. The hydrophobicity of STF was determined by water contact angle (WCA) measurement. The results show that nanoscale SiO2 particles were deposited on the STF surface, and PFOTS were covalently linked to them. The SiO2 nanoparticles provide surface roughness to the fibres, whereas the long-chain fluorine on PFOTS lowered the surface free energy, and their combination in these treatments has successfully modified the STF surface from hydrophilic into superhydrophobic with a WCA of 150° and sliding angle of less than 10°. Altogether, a non-toxic, simple, and promising method of imparting hydrophobicity on natural fibres was developed, opening new opportunities for these fibres as reinforcement for composite parts.
ABSTRACT
It is of significant concern that the buildup of non-biodegradable plastic waste in the environment may result in long-term issues with the environment, the economy and waste management. In this study, low-density polyethylene (LDPE) was compounded with different contents of poly(butylene succinate) (PBS) at 10-50 wt.%, to evaluate the potential of replacing commercial plastics with a biodegradable renewable polymer, PBS for packaging applications. The morphological, mechanical and thermal properties of the LDPE/PBS blends were examined in relation to the effect of polyethylene-graft-maleic anhydride (PE-g-MA) as a compatibilizer. LDPE/PBS/PE-g-MA blends were fabricated via the melt blending method using an internal mixer and then were compression molded into test samples. The presence of LDPE, PBS and PE-g-MA individually in the matrix for each blend presented physical interaction between the constituents, as shown by Fourier-transform infrared spectroscopy (FTIR). The morphology of LDPE/PBS/PE-g-MA blends showed improved compatibility and homogeneity between the LDPE matrix and PBS phase. Compatibilized LDPE/PBS blends showed an improvement in the tensile strength, with 5 phr of compatibilizer providing the optimal content. The thermal stability of LDPE/PBS blends decreased with higher PBS content and the thermal stability of compatibilized blends was higher in contrast to the uncompatibilized blends. Therefore, our research demonstrated that the partial substitution of LDPE with a biodegradable PBS and the incorporation of the PE-g-MA compatibilizer could develop an innovative blend with improved structural, mechanical and thermal properties.
ABSTRACT
The biodegradability problem of polymer waste is one of the fatal pollutFions to the environment. Enzymes play an essential role in increasing the biodegradability of polymers. In a previous study, antistatic polymer film based on poly(lactic acid) (PLA) as a matrix and polyaniline (PAni) as a conductive filler, was prepared. To solve the problem of polymer wastes pollution, a crazing technique was applied to the prepared polymer film (PLA/PAni) to enhance the action of enzymes in the biodegradation of polymer. This research studied the biodegradation test based on crazed and non-crazed PLA/PAni films by enzymes. The presence of crazes in PLA/PAni film was evaluated using an optical microscope and scanning electron microscopy (SEM). The optical microscope displayed the crazed in the lamellae form, while the SEM image revealed microcracks in the fibrils form. Meanwhile, the tensile strength of the crazed PLA/PAni film was recorded as 19.25 MPa, which is almost comparable to the original PLA/PAni film with a tensile strength of 20.02 MPa. However, the Young modulus decreased progressively from 1113 MPa for PLA/PAni to 651 MPa for crazed PLA/PAni film, while the tensile strain increased 150% after crazing. The significant decrement in the Young modulus and increment in the tensile strain was due to the craze propagation. The entanglement was reduced and the chain mobility along the polymer chain increased, thus leading to lower resistance to deformation of the polymer chain and becoming more flexible. The presence of crazes in PLA/PAni film showed a substantial change in weight loss with increasing the time of degradation. The weight loss of crazed PLA/PAni film increased to 42%, higher than that of non-crazed PLA/PAni film with only 31%. The nucleation of crazes increases the fragmentation and depolymerization of PLA/PAni film that induced microbial attack and led to higher weight loss. In conclusion, the presence of crazes in PLA/PAni film significantly improved enzymes' action, speeding up the polymer film's biodegradability.
ABSTRACT
An anti-static polymer film was prepared using biodegradable poly(lactic acid) as a matrix and polyaniline (PAni) as an anti-static agent. It is aimed to be applied in packaging applications to dissipate the accumulated charges. The anti-static properties of PLA films were investigated with various PAni contents ranging from 0% to 20% through ex situ polymerisation by the solution casting method. PAni was synthesised in the solution form through chemical oxidation at 0 °C. The synthesis of PAni was confirmed by Fourier transform infrared (FTIR) spectroscopy and ultraviolet-visible (UV-Vis) absorption spectroscopy. The mechanical and anti-static properties of the samples were characterised using a Universal Testing Machine (UTM) and a resistivity meter, respectively. The experimental results indicated that incorporation of PAni into PLA films affected the morphology, anti-static and mechanical properties of the samples. PLA/PAni showed a compact surface with a porous structure, reflecting the interfacial interaction between PLA and PAni in the presence of a plasticiser. It was discovered and compared with other compositions, PLA with 15% PAni exhibited excellent anti-static performance with 2.45 × 1010 ohm/sq surface resistivity and the highest tensile strength, elongation at break and modulus of 29.3 ± 2.4 MPa, 60.1 ± 1.6% and 1364.0 ± 85.2 MPa respectively. Hence, PAni is a good candidate to be used in PLA/PAni systems by giving a suitable surface resistivity that can potentially be applied in anti-static packaging applications.
