ABSTRACT
The effect of the novel composite material LiNbO3@Fe3O4 on the nitrate removal, and Mn2+ oxidation efficiency by autotrophic denitrification strain Achromobacter sp. A14 was investigated in this study. The optimum conditions were tested by using five levels of initial Mn2+ concentrations (40, 60, 80, 100 and 120â mg/L), initial pH (5.0, 6.0, 7.0, 8.0 and 9.0) and temperature (20, 25, 30, 35 and 40°C). A maximal nitrate removal ratio of nearly 100% and a maximal Mn2+ oxidation ratio of 71.59% were simultaneously achieved at pH 7.0, 80â mg/L Mn2+ and 30°C by bacteria A14 with 300â mg/L LiNbO3@Fe3O4 as catalytic material. Biomaterial cycle testing indicated that the denitrification efficiency of bacteria A14 with LiNbO3@Fe3O4 remained steady after 10 batches.
Subject(s)
Achromobacter , Denitrification , Achromobacter/genetics , Autotrophic Processes , Bacteria , NitratesABSTRACT
This study investigated the factors influencing the simultaneous removal of Cd2+, NO3-N and hardness from water by the bacterial strain CN86. Optimum conditions were determined experimentally by varying the type of organic matter used, initial Cd2+ concentration, and pH. Under the optimum conditions, the maximum removal ratios of Cd2+, NO3-N and hardness were 100.00, 89.85 and 71.63%, respectively. The mechanism of Cd2+ removal is a combination of co-precipitation with calcium carbonate and pH. Further confirmation that Cd2+ can be removed by strain CN86 was provided by XRD and XPS analyses. Meteorological chromatography analysis showed that N2 was produced as an end product. These results demonstrate that the bacterial strain CN86 is a suitable candidate for simultaneously removing Cd2+, NO3-N, and hardness during in wastewater treatment.
Subject(s)
Acinetobacter/growth & development , Cadmium/metabolism , Denitrification , Nitrates/metabolism , Wastewater/microbiology , Water Purification , Aerobiosis , Cadmium/chemistry , Calcium Carbonate/chemistry , Calcium Carbonate/metabolism , Nitrates/chemistryABSTRACT
In this study, zero-valent iron (ZVI), nanoscale zero-valent iron (nZVI), Fe(II), and Mn(II) were investigated for their effects on mixotrophic denitrification coupled with cadmium (Cd(II)) adsorption process by Acinetobacter sp. SZ28. The removal rates of nitrate were 0.228 mg L-1 h-1 (ZVI), 0.133 mg L-1 h-1 (nZVI), 0.309 mg L-1 h-1 (Fe(II)) and 0.234 mg L-1 h-1 (Mn(II)), respectively. The Cd(II) removal efficiencies were 97.23% (ZVI), 95.79% (nZVI), 80.63% (Fe(II)), and 84.58% (Mn(II)), respectively. Meteorological chromatography analysis indicated that the characteristics of gas composition were different under different electron donor conditions. Moreover, characterization of bacterial metabolites produced by strain SZ28 under different conditions was analyzed. Sequence amplification identified the presence of the nitrate reductase gene (napA) and Mn(II)-oxide gene (cumA) in strain SZ28. The results of XRD and SEM indicated that ZVI, nZVI, Fe(II), and Mn(II) were oxidized into corresponding oxides. XPS spectra indicated that the Cd(II) was adsorbed onto biogenic precipitation.
