Surface-Initiated, Catechol-Containing Polymer Films for Effective Chelation of Aluminum Ions.

We present a new route for obtaining surface-tethered polymer films containing pendant catechol functional groups via surface-initiated activators regenerated by electron-transfer atom-transfer radical polymerization (SI-ARGET ATRP) of glycidyl methacrylate (GMA) and post-polymerization modification of the resulting poly(glycidyl methacrylate) (pGMA) films with dopamine. This method enables a high degree of functionalization of pGMA films with catechol groups at a controlled level, depending on the duration of the post-polymerization modification reaction. The dopamine-pGMA films readily absorbs Al3+ and Zn2+ ions, as verified by quartz crystal microbalance with dissipation (QCM-D) under continuous flow conditions, and demonstrates a four-fold molar selectivity to Al3+ over Zn2+. The ions desorb from the films upon rinsing with pure deionized (DI) water, which regenerates the catechol sites in the dopamine-pGMA film. Subsequent exposure to metal ions after rinsing steps yields reproducible levels of loading.

The Influence of Training on New Army Recruits' Energy and Macronutrient Intakes and Performance: A Systematic Literature Review.

BACKGROUND: New army recruits undertake initial training to develop their skillset and physical and mental preparedness for military service. Recruits experience a range of stressors both physical and psychological, often at extremes, and in combination. These stressors place recruits at risk of suboptimal energy and macronutrient intakes, which may negatively influence their performance. OBJECTIVE: The objectives of this systematic literature review are to examine, against the Military Recommended Dietary Intakes (MRDIs), the energy, carbohydrate, protein, and fat intakes of army recruits and trainees undertaking initial training internationally, and identify any associated influence on their performance. DESIGN: A systematic literature review was conducted in accordance with the preferred reporting items for systematic reviews and meta-analyses guidelines. Information sources were searched from their inception until May 2019. MAIN OUTCOME MEASURES: Outcome data included dietary intakes of energy, carbohydrate, protein, and fat before, during, and/or after army initial training, as well as measures of physical fitness and performance. A custom tool was used to assess the quality of included studies. RESULTS: The results of 14 studies were synthesized. Six were conducted in the United States and four in each of Australia and Israel. Average energy intake represented 69% to 120% of the MRDIs before training commencement, 69% to 106% of the MRDIs in the early weeks of training and 56% to 77% of the MRDIs in the later weeks of training. Average carbohydrate and protein intakes represented 49% to 121% and 64% to 143% of the MRDIs, respectively, across the various time points. Three studies measured physical fitness and/or performance outcomes, with one showing a significant improvement in push-up performance when extra protein was provided. CONCLUSIONS: The novel findings of this systematic literature review are that army recruits, internationally, are likely to be underconsuming energy for extended periods of their initial training, with greater deficits in carbohydrate intake compared with other macronutrients. Only a handful of studies investigated the subsequent influents on performance, with no definitive conclusions drawn in most instances. Further research is needed to understand the influence of suboptimal dietary intake on military relevant performance indicators to help better inform key stakeholders when devising nutrition guidance and strategies for army recruits in the future.

Body weight and body composition changes during military training and deployment involving the use of combat rations: a systematic literature review.

Dismounted military personnel operate in physically and psychologically demanding environments, with energy intake from combat rations often falling short of their requirements, leading to reductions in body weight and changes in body composition, which can impact both their health and performance. This review systematically investigated the effects of the continual use of combat rations for periods of 3-40 d on body weight and/or body composition in military personnel engaged in training or deployment. In all, ten databases were searched from their inception until October 2016. Outcome data were described narratively, with studies assessed for quality and risk of bias. A total of thirty studies undertaken over 3-34 d were included. Studies were rated positive, neutral or negative in quality according to the Academy of Nutrition and Dietetics Quality Checklist, with many at risk of bias. Reductions in mean body weight varied, from a negligible decrease of 0·1 % during 8 d of combat training to a substantial decrease of approximately 8·3 % during 12 d of energy restriction during a US Army Ranger course. Decreases in fat mass, fat-free mass and percentage body fat were also reported. There is thus evidence that the continual use of combat rations for periods of 3-34 d results in reductions in body weight and body composition changes which, in some scenarios, may impact on the performance of troops. Body weight and composition should be routinely monitored before and after field activities, and at more regular intervals depending on the length, intensity and type of activity being undertaken.