ABSTRACT
Many values of the observed conductivity percolation exponent t cannot be explained by the classical universal theory or by the existing nonuniversal theories. In particular, the 1.3≤t≤4.0 clustering of t values, in both composite materials and porous media has not been accounted for. In this work we were concerned with a pseudononuniversal percolation behavior that, unlike the genuine nonuniversal behavior, explains the statistics of the experimentally observed percolation conductivity exponents in continuum systems.
ABSTRACT
For quite a few systems in the continuum, such as carbon nanotube polymer composites and segregated composites, percolation electrical conductivity exponents that are much smaller than the universal value have been reported. This is unexpected in view of the classical lattice percolation theory. Here we provide a simple general phenomenological model that accounts for such observations within the framework of universality. We suggest that these small value exponents are due to the interplay between the connectivity and the structural variations that follow the increase of the fractional volume content of the conducting phase.
ABSTRACT
We have applied scanning tunneling spectroscopy in studies of the electronic level structure of surface-functionalized colloidal Si nanocrystals (Si-NCs) as a function of their size for various capping ligands. The energy gaps extracted from the tunneling spectra increase with decreasing NC size, manifesting the effect of quantum confinement. This is consistent with the blueshift revealed by photoluminescence (PL) from dodecene functionalized Si-NCs. The tunneling spectra measured on NCs functionalized with NH4Br or allylamine show band-edge shifts toward higher energies, akin to p-type doping. This behavior can be accounted for by the combined contributions of the ligands' dipole moments and charge transfer between a Si-NC and its surface groups. Concomitantly, size-independent PL spectra, which cannot be associated with NC band gap variations, were observed for the latter Si-NCs.
ABSTRACT
We have followed the effects of heavy ion irradiation on the structural, electrical, and photoluminescence properties of ensembles of silicon nanocrystallites embedded in a dielectric (SiO(2)) matrix. This was done as a function of the irradiation dose and the content of the Si phase. The results obtained can be accounted for self-consistently assuming that a relatively small dose of the irradiation enhances the crystallization while for higher doses the irradiation enhances the amorphization. The corresponding processes suggest that tuning of the above properties can be achieved by swift heavy ion irradiation.
Subject(s)
Crystallization/methods , Nanostructures/chemistry , Nanostructures/ultrastructure , Nanotechnology/methods , Silicon Dioxide/chemistry , Heavy Ions , Luminescent Measurements , Macromolecular Substances/chemistry , Macromolecular Substances/radiation effects , Materials Testing , Molecular Conformation/radiation effects , Nanostructures/radiation effects , Particle Size , Radiation Dosage , Silicon Dioxide/radiation effects , Surface Properties/radiation effectsABSTRACT
Modification of films containing Si nanocrystallites embedded in SiO2 by irradiation with high-energy ions was found to induce peaks in their low-frequency capacitance-voltage characteristics. Considering the nanocrystallite spatial distribution that follows the ion tracks we interpret these peaks as due to the charge transfer along these tracks, similar to the process that was reported previously for two-dimensional arrays of such crystallites. The ion irradiation of the above three-dimensional system appears to be useful then for the fabrication of nanostructures, which have also the properties of low-dimensional arrays.
Subject(s)
Models, Chemical , Nanotechnology/methods , Quantum Dots , Silicon/chemistry , Computer Simulation , Heavy Ions , Macromolecular Substances/chemistry , Macromolecular Substances/radiation effects , Materials Testing , Molecular Conformation/radiation effects , Particle Size , Radiation Dosage , Surface Properties/radiation effectsABSTRACT
We report on Monte Carlo simulations of continuum percolation thresholds, by implementing highly efficient algorithms for very large samples. Our work, which includes percolation of hyperspheres, hypercubes, and boxes, in various dimensions, sizes, and shapes, has confirmed the expected dependence of the threshold on Vex, the total excluded volume, and on Bc, the average number of bonds per site. We have further confirmed that Vex=Bc, and that Bc is dependent on the objects shape, for which we offer a possible explanation. In particular we find that, counterintuitively, one can have Bc<1, as we have found for hyperspheres of dimension > or =12. From our many results for differently sized hyperspheres, we were also able to derive the correlation length exponent v solely from the behavior of the thresholds using finite-size scaling.
ABSTRACT
The values obtained experimentally for the conductivity critical exponent in numerous percolation systems, in which the interparticle conduction is by tunneling, were found to be in the range of t0 and about t0 + 10, where t0 is the universal conductivity exponent. These latter values are, however, considerably smaller than those predicted by the available "one-dimensional"-like theory of tunneling percolation. In this Letter, we show that this long-standing discrepancy can be resolved by considering the more realistic "three-dimensional" model and the limited proximity to the percolation threshold in all the many available experimental studies.
ABSTRACT
A striking correlation between infrared photoinduced absorption spectra and the photoluminescence from silicon nanocrystals indicates that quantized electronic sublevels of the nanocrystals are resonantly coupled to surface vibrational modes via a polarization field produced by coherent longitudinal polar vibrations. Our experimental results and model support the assumption that the mechanism responsible for the efficient photoluminescence from silicon nanocrystals should be assigned to inhibition of nonradiative channels rather than enhancement of radiative channels.
Subject(s)
Crystallization/methods , Electrochemistry/methods , Models, Chemical , Models, Molecular , Nanostructures/chemistry , Silicon/chemistry , Computer Simulation , Electric Conductivity , Electronics , Luminescence , Macromolecular Substances/chemistry , Materials Testing , Molecular Conformation , VibrationABSTRACT
Following the lack of microscopic information about the intriguing well-known electrical-thermal switching mechanism in carbon-black-polymer composites, we applied atomic force microscopy in order to reveal the local nature of the process and correlated it with the characteristics of the widely used commercial switches. We conclude that the switching events take place in critical interparticle tunneling junctions that carry most of the current. The macroscopic switched state is then a result of a dynamic-stationary state of fast switching and slow reconnection of the corresponding junctions.
