Efficiency improvement by using metal-insulator-semiconductor structure in InGaN/GaN micro-light-emitting diodes.

InGaN/GaN micro-light-emitting diodes (micro-LEDs) with a metal-insulator-semiconductor (MIS) structure on the sidewall are proposed to improve efficiency. In this MIS structure, a sidewall electrode is deposited on the insulating layer-coated sidewall of the device mesa between a cathode on the bottom and an anode on the top. Electroluminescence (EL) measurements of fabricated devices with a mesa diameter of 10 µm show that the application of negative biases on the sidewall electrode can increase the device external quantum efficiency (EQE). In contrast, the application of positive biases can decrease the EQE. The band structure analysis reveals that the EQE is impacted because the application of sidewall electric fields manipulates the local surface electron density along the mesa sidewall and thus controls surface Shockley-Read-Hall (SRH) recombination. Two suggested strategies, reducing insulator layer thickness and exploring alternative materials, can be implemented to further improve the EQE of MIS micro-LEDs in future fabrication.

Pesticide Efficiency of Environment-Friendly Transition Metal-Doped Magnetite Nanoparticles.

This study explored the potential of Fe3O4, SnFe2O4, and CoFe2O4 nanoparticles as larvicidal and adulticidal agents against Aedes aegypti (A. aegypti) larvae and adults, which are vectors for various diseases. This research involved the synthesis of these nanoparticles using the coprecipitate method. The results indicate that CoFe2O4 nanoparticles are the most effective in both larvicidal and adulticidal activities, with complete mortality achieved after 96 h of exposure. SnFe2O4 nanoparticles also showed some larvicidal and adulticidal efficacy, although to a lesser extent than the CoFe2O4 nanoparticles. Fe3O4 nanoparticles exhibited minimal larvicidal and adulticidal effects at low concentrations but showed increased efficacy at higher concentrations. The study also revealed the superparamagnetic nature of these nanoparticles, making them potentially suitable for applications in aquatic environments, where A. aegypti larvae often thrive. Additionally, the nanoparticles induced observable damage to the gut structure of the mosquitoes and larvae, which could contribute to their mortality. Overall, this research suggests that CoFe2O4 nanoparticles, in particular, hold promise as environment-friendly and effective agents for controlling A. aegypti mosquitoes, which are responsible for the transmission of diseases such as dengue fever, Zika virus, and Chikungunya. Further studies and field trials are needed to validate their practical use in mosquito control programs.

Physical probing of quantum energy levels in a single indium arsenide (InAs) quantum dot.

Indium arsenide (InAs) quantum dots (QDs) grown by molecular beam epitaxy (EBM) on gallium arsenide (GaAs) substrates have exhibited quantized charge-trapping characteristics. An electric charge can be injected in a single QD by a gold-coated AFM nano-probe placed directly on it using a conductive-mode atomic force microscope (C-AFM). The results revealed separate current-voltage (I-V) curves during consecutive measurements, where the turn-on voltages measured at the subsequent voltage sweeps are incrementally lower than that at the initial sweep. We demonstrate that the charge state of the QD can change over a long enough time by measuring the I-V data on the same QD at different time intervals. Discrete energy states (here, five states) have been observed due to the quantized charge leakage from the QD into the surrounding materials. These quantum states with five energy levels have been verified using quantum theory analysis of the quantum-well with the help of a numerical simulation model, which depends on the QD dimensions. The size of the quantum-well in the model is in good agreement with the actual QD size, whose lateral dimension is confirmed using a scanning electron microscope. At the same time, the height is estimated from the atomic force microscope topography.

Nano Groove and Prism-Structured Triboelectric Nanogenerators.

Enhancing the output power of triboelectric nanogenerators (TENGs) requires the creation of micro or nano-features on polymeric triboelectric surfaces to increase the TENGs' effective contact area and, therefore, output power. We deploy a novel bench-top fabrication method called dynamic Scanning Probe Lithography (d-SPL) to fabricate massive arrays of uniform 1 cm long and 2.5 µm wide nano-features comprising a 600 nm deep groove (NG) and a 600 nm high triangular prism (NTP). The method creates both features simultaneously in the polymeric surface, thereby doubling the structured surface area. Six thousand pairs of NGs and NTPs were patterned on a 6×5 cm2 PMMA substrate. It was then used as a mold to structure the surface of a 200 µm thick Polydimethylsiloxane (PDMS) layer. We show that the output power of the nano-structured TENG is significantly more than that of a TENG using flat PDMS films, at 12.2 mW compared to 2.2 mW, under the same operating conditions (a base acceleration amplitude of 0.8 g).

Progress and Perspectives of Mid-Infrared Photoacoustic Spectroscopy for Non-Invasive Glucose Detection.

The prevalence of diabetes is rapidly increasing worldwide and can lead to a range of severe health complications that have the potential to be life-threatening. Patients need to monitor and control blood glucose levels as it has no cure. The development of non-invasive techniques for the measurement of blood glucose based on photoacoustic spectroscopy (PAS) has advanced tremendously in the last couple of years. Among them, PAS in the mid-infrared (MIR) region shows great promise as it shows the distinct fingerprint region for glucose. However, two problems are generally encountered when it is applied to monitor real samples for in vivo measurements in this MIR spectral range: (i) low penetration depth of MIR light into the human skin, and (ii) the effect of other interfering components in blood, which affects the selectivity of the detection system. This review paper systematically describes the basics of PAS in the MIR region, along with recent developments, technical challenges, and data analysis strategies, and proposes improvements for the detection sensitivity of glucose concentration in human bodies. It also highlights the recent trends of incorporating machine learning (ML) to enhance the detection sensitivity of the overall system. With further optimization of the experimental setup and incorporation of ML, this PAS in the MIR spectral region could be a viable solution for the non-invasive measurement of blood glucose in the near future.

Control of Halogen Atom in Inorganic Metal-Halide Perovskites Enables Large Piezoelectricity for Electromechanical Energy Generation.

Regulating the strain of inorganic perovskites has emerged as a critical approach to control their electronic and optical properties. Here, an alternative strategy to further control the piezoelectric properties by substituting the halogen atom (I/Br) in the CsPbX3 perovskite (X = Cl, Br) structure is adopted. A series of piezoelectric materials with excellent piezoelectric coefficients (d33 ) are unveiled. Iodine-incorporated CsPbBr2 I demonstrates the record intrinsic piezoelectric response (d33 ≈47 pC N-1 ) among all inorganic metal halide perovskites. This leads to an excellent electrical output power of ≈ 0.375 mW (24.8 µW cm-2 N-1 ) in the piezoelectric energy generator (PEG) which is higher than those of the pristine/mixed perovskite references with CsPbX3 (X = I, Br, Cl). With its structural phase remaining unchanged, the strained CsPbBr2 I retains its superior piezoelectricity in both thin film and nanocrystal powder forms, further demonstrating its repeatability and versatility of applications. The origin of high piezoelectricity is found to be due to halogen-induced anisotropic lattice strain in the unit-cell along the c-axis, and octahedral distortion. This study reveals an avenue to design new piezoelectric materials by modifying their halide constituents and paves the way to design efficient PEGs for improved electromechanical energy conversion.

Dual quantum cascade lasers for noninvasive glucose detection using photoacoustic spectroscopy.

The combination of mid-infrared and photoacoustic spectroscopy has shown promising developments as a substitute for invasive glucose detection technology. A dual single-wavelength quantum cascade laser system has been developed using photoacoustic spectroscopy for noninvasive glucose monitoring. Biomedical skin phantoms with similar properties to human skin have been prepared with blood components at different glucose concentrations as test models for the setup. The detection sensitivity of the system has been improved to ± 12.5 mg/dL in the hyperglycemia blood glucose ranges. An ensemble machine learning classifier has been developed to predict the glucose level in the presence of blood components. The model, which was trained with 72,360 unprocessed datasets, achieved a 96.7% prediction accuracy with 100% of the predicted data located in zones A and B of Clarke's error grid analysis. These findings fulfill both the US Food and Drug Administration and Health Canada requirements for glucose monitors.

Large piezoelectric response in a Jahn-Teller distorted molecular metal halide.

Piezoelectric materials convert between mechanical and electrical energy and are a basis for self-powered electronics. Current piezoelectrics exhibit either large charge (d33) or voltage (g33) coefficients but not both simultaneously, and yet the maximum energy density for energy harvesting is determined by the transduction coefficient: d33*g33. In prior piezoelectrics, an increase in polarization usually accompanies a dramatic rise in the dielectric constant, resulting in trade off between d33 and g33. This recognition led us to a design concept: increase polarization through Jahn-Teller lattice distortion and reduce the dielectric constant using a highly confined 0D molecular architecture. With this in mind, we sought to insert a quasi-spherical cation into a Jahn-Teller distorted lattice, increasing the mechanical response for a large piezoelectric coefficient. We implemented this concept by developing EDABCO-CuCl4 (EDABCO = N-ethyl-1,4-diazoniabicyclo[2.2.2]octonium), a molecular piezoelectric with a d33 of 165 pm/V and g33 of ~2110 × 10-3 V m N-1, one that achieved thusly a combined transduction coefficient of 348 × 10-12 m3 J-1. This enables piezoelectric energy harvesting in EDABCO-CuCl4@PVDF (polyvinylidene fluoride) composite film with a peak power density of 43 µW/cm2 (at 50 kPa), the highest value reported for mechanical energy harvesters based on heavy-metal-free molecular piezoelectric.

A Hydrogel Microneedle Assay Combined with Nucleic Acid Probes for On-Site Detection of Small Molecules and Proteins.

Point-of-care testing (POCT) of clinical biomarkers is critical to health monitoring and timely treatment, yet biosensing assays capable of detecting biomarkers without the need for costly external equipment and reagents are limited. Blood-based assays are, specifically, challenging as blood collection is invasive and follow-upprocessing is required. Here, we report a versatile assay that employs hydrogel microneedles (HMNs) to extract interstitial fluid (ISF), in a minimally invasive manner integrated with graphene oxide-nucleic acid (GO.NA)-based fluorescence biosensor to sense the biomarkers of interest in situ. The HMN-GO.NA assay is supplemented with a portable detector, enabling a complete POCT procedure. Our system could successfully measure four clinically important biomarkers (glucose, uric acid (UA), insulin, and serotonin) ex vivo, in addition, to accurately detecting glucose and UA in vivo.

Visualization of localized facet Joule heating induced optical degradation on mid-infrared quantum cascade lasers.

Reversible lasing performance degradation is investigated on an uncoated actively- biased GaAs/Al0.45Ga0.55As mid-infrared quantum cascade laser (MIR-QCL) facet. The surface temperature rises (ΔT) on the MIR QCL are characterized before and after the device undergoes an accelerated aging burn-in test, followed by hydrogen plasma treatment. The data is visualized by spatially resolved time-domain thermoreflectance (SR-TDTR) microscopy. On the laser facet, ΔT decreases with a drop in lasing performance and ΔT increases with an increase in lasing performance. Along the laser cavity, the thermal property change is negligible before and after the aging test, independent of the optical performance change. The results verify that thermal-induced facet oxidation is the main reason for the rapid degradation of the lasing performance in the early aging stage.

Semiconductor nanowire metamaterial for broadband near-unity absorption.

The realization of a semiconductor near-unity absorber in the infrared will provide new capabilities to transform applications in sensing, health, imaging, and quantum information science, especially where portability is required. Typically, commercially available portable single-photon detectors in the infrared are made from bulk semiconductors and have efficiencies well below unity. Here, we design a novel semiconductor nanowire metamaterial, and show that by carefully arranging an InGaAs nanowire array and by controlling their shape, we demonstrate near-unity absorption efficiency at room temperature. We experimentally show an average measured efficiency of 93% (simulated average efficiency of 97%) over an unprecedented wavelength range from 900 to 1500 nm. We further show that the near-unity absorption results from the collective response of the nanowire metamaterial, originating from both coupling into leaky resonant waveguide and transverse modes. These coupling mechanisms cause light to be absorbed directly from the top and indirectly as light scatters from one nanowire to neighbouring ones. This work leads to the possible development of a new generation of quantum detectors with unprecedented broadband near-unity absorption in the infrared, while operating near room temperature for a wider range of applications.

Poly(vinylidene fluoride)-Stabilized Black γ-Phase CsPbI3 Perovskite for High-Performance Piezoelectric Nanogenerators.

Halide perovskite materials have been recently recognized as promising materials for piezoelectric nanogenerators (PENGs) due to their potentially strong ferroelectricity and piezoelectricity. Here, we report a new method using a poly(vinylidene fluoride) (PVDF) polymer to achieve excellent long-term stable black γ-phase CsPbI3 and explore the piezoelectric performance on a CsPbI3@PVDF composite film. The PVDF-stabilized black-phase CsPbI3 perovskite composite film can be stable under ambient conditions for more than 60 days and over 24 h while heated at 80 °C. Piezoresponse force spectroscopy measurements revealed that the black CsPbI3/PVDF composite contains well-developed ferroelectric properties with a high piezoelectric charge coefficient (d 33) of 28.4 pm/V. The black phase of the CsPbI3-based PVDF composite exhibited 2 times higher performance than the yellow phase of the CsPbI3-based composite. A layer-by-layer stacking method was adopted to tune the thickness of the composite film. A five-layer black-phase CsPbI3@PVDF composite PENG exhibited a voltage output of 26 V and a current density of 1.1 µA/cm2. The output power can reach a peak value of 25 µW. Moreover, the PENG can be utilized to charge capacitors through a bridge rectifier and display good durability without degradation for over 14 000 cyclic tests. These results reveal the feasibility of the all-inorganic perovskite for the design and development of high-performance piezoelectric nanogenerators.

A Single Wavelength Mid-Infrared Photoacoustic Spectroscopy for Noninvasive Glucose Detection Using Machine Learning.

According to the International Diabetes Federation, 530 million people worldwide have diabetes, with more than 6.7 million reported deaths in 2021. Monitoring blood glucose levels is essential for individuals with diabetes, and developing noninvasive monitors has been a long-standing aspiration in diabetes management. The ideal method for monitoring diabetes is to obtain the glucose concentration level with a fast, accurate, and pain-free measurement that does not require blood drawing or a surgical operation. Multiple noninvasive glucose detection techniques have been developed, including bio-impedance spectroscopy, electromagnetic sensing, and metabolic heat conformation. Nevertheless, reliability and consistency challenges were reported for these methods due to ambient temperature and environmental condition sensitivity. Among all the noninvasive glucose detection techniques, optical spectroscopy has rapidly advanced. A photoacoustic system has been developed using a single wavelength quantum cascade laser, lasing at a glucose fingerprint of 1080 cm-1 for noninvasive glucose monitoring. The system has been examined using artificial skin phantoms, covering the normal and hyperglycemia blood glucose ranges. The detection sensitivity of the system has been improved to ±25 mg/dL using a single wavelength for the entire range of blood glucose. Machine learning has been employed to detect glucose levels using photoacoustic spectroscopy in skin samples. Ensemble machine learning models have been developed to measure glucose concentration using classification techniques. The model has achieved a 90.4% prediction accuracy with 100% of the predicted data located in zones A and B of Clarke's error grid analysis. This finding fulfills the US Food and Drug Administration requirements for glucose monitors.

Anhydride-Terminated Solid-State Carbon Dots with Bright Orange Emission Induced by Weak Excitonic Electronic Coupling.

In this work, fluorescent solid carbon dots (CDs) welcome a new member, namely anhydride-terminated CDs, which have a photoluminescence quantum yield (PLQY) of 28% for orange-emitted CDs at 580 nm in powder form. For the first time, we revealed that the electronic coupling of the functional groups should be a crucial factor affecting the optical properties of solid CDs. Due to the negligible hydrogen bonding interaction between the anhydride groups, the electronic coupling of excitons between neighboring anhydride groups is weak, leading to a high PLQY of 28% and an immobile emission peak at 580 nm in solid state. Anhydride-terminated CDs can be partly converted into carboxyl-terminated CDs after dispersion in ethanol. However, the strong electronic coupling of carboxyl groups at high concentration generates the stacking mode of J-aggregates, giving rise to a red-shifted emission from 450 to 515 nm as well as quenched fluorescence in solid state. In comparison, a useful blue emission for solid-state CDs occurs from low sp2 hybridized carbon atoms, which possess weak electronic coupling and a stationary emission band at 450 nm in both solution and solid state. By adjusting the feed ratio of the reactants, the relevant intensities between the emission from low sp2 hybridized carbon atoms at 450 nm and the emission from anhydride groups at 580 nm can be controlled. As a result, single-component anhydride-terminated CD powder with tunable emission color from orange to white light can be achieved. As-prepared anhydride-terminated CDs can be used for fabricating light-emitting diodes (LEDs), white LEDs, and luminescent solar concentrators (LSCs).

Performance-Improved Highly Integrated Uniaxial Tristate Hybrid Nanogenerator for Sustainable Mechanical Energy Harvesting.

Despite advances in the development of individual nanogenerators, the level of output energy generation must be increased to meet the demands of commercial electronic systems and to broaden their scope of application. To harvest low-frequency ambient mechanical energy more efficiently, we proposed a highly integrated hybridized piezoelectric-triboelectric-electromagnetic (tristate) nanogenerator in a uniaxial structure. In its highly integrated approach, a piezoelectric nanogenerator (PENG) based on CsPbBr3 (cesium lead bromide) nanoparticles (NPs) and poly(dimethylsiloxane) (PDMS) nanocomposite was fabricated on a triboelectrically negative nanostructured polyimide (PI) substrate. A cylindrical aluminum electrode grooved with permanent magnets was directed to move along a spring-less metallic guide bounded by these nanocomposites, thus essentially forming two single-electrode mode triboelectric nanogenerators (TENGs). By its optimized material design and novel integration approach of the PENGs, TENGs, and electromagnetic generators (EMGs), this uniaxial tristate hybrid nanogenerator (UTHNG) can synergistically produce an instantaneous electrical power of 49 mW at low-frequency ambient vibration (5 Hz). The UTHNG has excellent charging characteristics, ramping up the output voltage of a 22 µF capacitor to 2.7 V in only 12 s, which is much faster than individual nanogenerators. This work will be a superior solution for harvesting low-frequency ambient energies by improving the performance of hybrid nanogenerators, potentially curtailing the technology gap for self-powered micro/nanosystems for the Internet of Things.

Sensing of ultraviolet light: a transition from conventional to self-powered photodetector.

Clouds in the sky pass almost 80% of ultraviolet (UV) radiation to the earth's surface, which has a significant impact on humankind. Conventional UV photodetectors (PDs) require an external battery, which not only increases the device size but also has a limited life span and maintenance costs can be prohibitively expensive. An alternative and more technically-sound solution would be the use of self-powered UV PDs that can operate independently, eliminating the need for an external source. Although many exciting studies have been done and state-of-the-art research is underway to successfully fabricate self-powered UV PDs, periodic reviews on this topic are deemed essential so that the technology's readiness can be properly evaluated and critical challenges can be addressed in a timely manner. In this article, the key issues and most exciting developments made in recent years on built-in electric field assisted self-powered UV PDs based on p-n homojunctions, p-n heterojunctions, and Schottky junctions followed by energy harvester integrated UV PDs are extensively reviewed. Finally, a summary and comparison of different types of self-powered UV PDs as well as future challenges that need to be addressed are discussed. This review sets a foundation providing essential insights into the present status of self-powered UV PDs with which researchers can engage and deal with the major challenges.

Bi and Sb Codoped Cs2Ag0.1Na0.9InCl6 Double Perovskite with Excitation-Wavelength-Dependent Dual-Emission for Anti-Counterfeiting Application.

The growing demands for optical anti-counterfeiting technology require the development of new environmentally friendly materials with single component, multimodal fluorescence and high stability. Herein, the Bi/Sb codoped Cs2Ag0.1Na0.9InCl6 lead-free double perovskite material is reported as an efficient multimodal luminescence material with excitation-wavelength-dependent emission. When excited by 360 nm UV light, dual-emission is observed at 455 and 560 nm, which comes from the 3P1-1S0 transition of Sb3+ ions and self-trapped excitons (STEs), respectively. Under the 320 nm UV lamp, the microcrystals show only a blue emission centered at 455 nm. Therefore, the Bi/Sb codoped Cs2Ag0.1Na0.9InCl6 double perovskite emits blue and yellow lights under the 320 and 360 nm UV lamp, respectively. Moreover, the obtained double perovskite shows a high PLQY up to 41% and excellent stability against both air and high temperature, which make it a promising anti-counterfeiting material.

Ultrasonically-prepared copper-doped cesium halide nanocrystals with bright and stable emission.

All-inorganic cesium lead halide perovskite nanocrystals (NCs) are quite promising materials for emission-based applications. However, the intrinsic toxicity of lead, as well as the weak stability, remains to be resolved. Exploring more and more types of lead-free NCs with high photoluminescence quantum yields (PLQYs) and high stability is a fundamental task. This work gave the first example of copper doped cesium halide (Cu:CsX, X = Br, Cl/Br, Br/I) NCs with good stability and high PLQYs (∼31.2%), which could act as a new member of the lead-free NC family. A simple single-step ultrasonic method was applied for the synthesis of environmentally friendly Cu:CsX NCs. By varying the halide composition, the emission wavelength of Cu:CsX can be shifted within 450-505 nm. The as-prepared NCs show highly uniform size and excellent stability. Finally, UV pumped light-emitting diodes are demonstrated by using Cu:CsX NCs as a color conversion layer.

Dual-lasing channel quantum cascade laser based on scattering-assisted injection design: erratum.

We correct three typographical errors in our published paper [Opt. Express26, 9194 (2018)10.1364/OE.26.009194]. First, we correct the error in the Table 1. The injection coupling strength for the summarized device in the first raw is corrected to 1.5 meV. Second, we correct the listed reference 10 to "S. Kumar, C. W. I. Chan, Q. Hu, and J. L. Reno, "A 1.8-THz quantum cascade laser operating significantly above the temperature of ℏω/kB," Nat. Phys. 7(2), 166-171 (2011)." Third, we correct the typographical error in the quantum structure layer thickness description. The text description on quantum structure layer thickness is correct to 40.3/74.4/24.1/103.6/29.7/79.7/40.3/156.7, which is the correct number extracted from high-resolution X-ray diffraction (HRXRD) measurement and used in simulation through the manuscript. The corrections do not alter the figures and conclusions in manuscript.