Electrorotation of particle-coated droplets: from fundamentals to applications.

Electrically insulating objects immersed in a weakly conducting liquid may Quincke rotate when subjected to an electric field. Experimental and theoretical investigations of this type of electrorotation typically concern rigid particles and particle-free droplets. This work provides the basic features of electric field-induced rotation of particle-covered droplets that expand the current knowledge in this area. Compared to pure droplets, we show that adding particles to the droplet interface considerably changes the parameters of electrorotation. We study in detail deformation magnitude (D), orientation (ß) and rotation rate (ω) of a droplet subjected to a DC E-field. Our experimental results reveal that both the critical electric field (for electrorotation) and the rotational rate depend on droplet size, particle shell morphology (smooth vs. brush-like), and composition (loose vs. locked particles). We also demonstrate the importance of the electrical parameters of the surface particles by comparing the behavior of droplets covered by (insulating) polymeric particles and droplets covered by (non-ohmic) clay mineral particles. The knowledge acquired from the electrorotation experiments is directly translated into practical applications: (i) to form arrested droplets with shells of different permeability; (ii) to study solid-to-liquid transition of particle shells; (iii) to mix particles on shells; and (iv) to increase the formation efficiency of Pickering emulsions.

Wastewater as a resource: a unique approach to achieving energy sustainability.

A wastewater-treatment flowsheet was developed to integrate uniquely designed biological processes with physical-chemical unit processes, allowing conversion of the organic carbon in the wastewater to methane, the removal and recovery of phosphorus and nitrogen from the wastewater, and the production of water suitable for reuse. In the flowsheet, energy is derived from the wastewater by first shunting a large fraction of the organic carbon in the wastewater to a solids slurry which is treated via anaerobic digestion. The anaerobic digestion system consists of focused pulsed (FP) pretreatment coupled to anaerobic membrane bioreactors (MBRs). Computer modelling and simulation results are used to optimize design of the system. Energy generation from the system is maximized and costs are reduced by using modest levels of recycle flow from the anaerobic MBRS to the FP pretreatment step.

Evidence for multiple sites of ferricyanide reduction in chloroplasts.

Various sites of ferricyanide reduction were studied in spinach chloroplasts. It was found that in the presence of dibromothymoquinone a fraction of ferricyanide reduction was dibromothymoquinone sensitive, implying that ferricyanide can be reduced by photosystem I as well as photosystem II. To separate ferricyanide reduction sites in photosystem II, orthophenanthroline and dichlorophenyl dimethylurea inhibitions were compared at various pHs. It was noted that at low pH ferricyanide reduction was not completely inhibited by orothophenanthroline. At high pH's, however, inhibition of ferricyanide reduction by orthophenanthroline was complete. It was found that varying concentration of orthophenanthroline at a constant pH showed different degrees of inhibition. In the study of ferricyanide reduction by photosystem II various treatments affecting plastocyanin were performed. It was found that Tween-20 or KCN treatments which inactivated plastocyanin did not completely inactivate ferricyanide reduction. These data support the conclusion that ferricyanide accepts electrons both before and after plastoquinone in photosystem II.