Enhancing electrochemical carbon dioxide reduction efficiency through heat-induced metamorphosis of copper nanowires into copper oxide/copper nanotubes with tunable surface.

Electrochemical CO2 reduction reaction (CO2RR) presents a unique opportunity to convert carbon dioxide (CO2) to value-added products while simultaneously storing renewable energy in the form of chemical energy. However, particle applications of this technology are limited due to the poor efficiency and product selectivity of the existing catalyst. In this study, we demonstrate a facile method for the heat-induced transformation of copper nanowires into CuOx/Cu nanotubes with defect-enriched surfaces. During this transformation, the outward migration of copper results in the formation of tubular structures encased within nanosized oxide grains. Notably, the hydrogen faradaic efficiency (FE) decreases with extended heat treatment, while carbon monoxide (CO) FE increases. As compared to Cu NWs, Cu NTs exhibit lower selectivity towards H2 and single-carbon (C1) products and favor the formation of multi-carbon (C2+) products. Consequently, a 2-fold increase in the single pass CO2 conversion (SPCC) and C2+ half-cell energy efficiency (EEhalf cell) was noted after heat treatment. The Cu NT-4 variant, synthesized under optimized conditions, exhibits the highest FE of 72.1 % for C2+ products at an operating current density (ID) of 500 mA cm-2.

FeCx-coated biochar nanosheets as efficient bifunctional catalyst for electrochemical detection and reduction of 4-nitrophenol.

Herein, we present the exceptional performance of FeCx-coated carbon sheets (FC) derived from the pyrolysis of waste biomass as a bifunctional catalyst for electrochemical detection and catalytic reduction of 4-nitrophenol (4-NP). Despite having a lower surface area, larger particle size, and lesser N content, the FC material prepared at a calcination temperature of 900 °C (FC900) outperforms the other samples. Deeper investigations revealed that the FC900 efficiently facilitates the charge transfer process and enhances the diffusion rate of 4-NP, leading to increased surface coverage of 4-NP on the surface of FC900. Additionally, relatively weaker interactions between 4-NP and FC900 allow the facile adsorption and desorption of reaction intermediates. Due to the synergetic interplay of these factors, FC900 exhibited a linear response to changes in 4-NP concentration from 1 µM to 100 µM with a low limit of detection (LOD) of 84 nM (S/N = 3) and high sensitivity of 12.15 µA µM-1 cm-2. Importantly, it selectively detects 4-NP in the presence of five times more concentrated 2-aminophenol, 4-aminophenol, catechol, resorcinol, and hydroquinone and ten times more concentrated metal salts such as Na2SO4. NaNO3, KCl, CuCl2, and CaCl2. Moreover, FC900 can accurately detect micromolar levels of 4-NP in river water with high recovery values (99.8-103.5 %). In addition, FC900 exhibited outstanding catalytic activity in reducing 4-NP to 4-aminophenol (4-AP), achieving complete conversion within 8 min with a high-rate constant of 0.42 min-1. FC900 also shows high recyclability in six consecutive catalytic reactions due to Fe magnetic property.

In situ construction of Fe3O4@FeOOH for efficient electrocatalytic urea oxidation.

Substituting water oxidation half of water splitting with anodic oxidation of urea can reduce the cost of H2 production and provide an avenue for treating urea-rich wastewater. However, developing an efficient and stable electrocatalyst is necessary to overcome the indolent kinetics of the urea oxidation reaction (UOR). Accordingly, we have used the Schikorr reaction to deposit Fe3O4 particles on the nickel foam (Fe3O4/NF). Results from the various analysis indicated that under the operational conditions, Fe3O4 underwent surface reconstruction to produce a heterolayered structure wherein a catalytically active FeOOH layer encased a conducting Fe3O4. Fe3O4/NF outperformed RuO2 as a UOR catalyst and delivered a current density of 10 50 and 100 mA cm-2 at low applied potentials of 1.38 1.42 and 1.46 V, respectively, with a Tafel slope of 28 mV dec-1. At the applied potential of 1.4 V, Fe3O4/NF demonstrated a turnover frequency (TOF) of 2.8 × 10-3 s-1, highlighting its superior intrinsic activity. In addition, a symmetrical urea electrolyzer constructed using Fe3O4/NF produced the current density of 10 mA cm-2 at a cell voltage of 1.54 V.

Critical Review, Recent Updates on Zeolitic Imidazolate Framework-67 (ZIF-67) and Its Derivatives for Electrochemical Water Splitting.

Design and construction of low-cost electrocatalysts with high catalytic activity and long-term stability is a challenging task in the field of catalysis. Metal-organic frameworks (MOF) are promising candidates as precursor materials in the development of highly efficient electrocatalysts for energy conversion and storage applications. This review starts with a summary of basic concepts and key evaluation parameters involved in the electrochemical water-splitting reaction. Then, different synthesis approaches reported for the cobalt-based Zeolitic imidazolate framework (ZIF-67) and its derivatives are critically reviewed. Additionally, several strategies employed to enhance the electrocatalytic activity and stability of ZIF-67-based electrocatalysts are discussed in detail. The present review provides a succinct insight into the ZIF-67 and its derivatives (oxides, hydroxides, sulfides, selenides, phosphide, nitrides, telluride, heteroatom/metal-doped carbon, noble metal-supported ZIF-67 derivatives) reported for oxygen evolution reaction (OER), hydrogen evolution reaction (HER), and overall water splitting applications. Finally, this review concludes with the associated challenges and the perspectives on developing the best economic, durable electrocatalytic materials.

Recent Trends in Electrochemical Sensors for Vital Biomedical Markers Using Hybrid Nanostructured Materials.

This work provides a succinct insight into the recent developments in electrochemical quantification of vital biomedical markers using hybrid metallic composite nanostructures. After a brief introduction to the biomarkers, five types of crucial biomarkers, which require timely and periodical monitoring, are shortlisted, namely, cancer, cardiac, inflammatory, diabetic and renal biomarkers. This review emphasizes the usage and advantages of hybrid nanostructured materials as the recognition matrices toward the detection of vital biomarkers. Different transduction methods (fluorescence, electrophoresis, chemiluminescence, electrochemiluminescence, surface plasmon resonance, surface-enhanced Raman spectroscopy) reported for the biomarkers are discussed comprehensively to present an overview of the current research works. Recent advancements in the electrochemical (amperometric, voltammetric, and impedimetric) sensor systems constructed with metal nanoparticle-derived hybrid composite nanostructures toward the selective detection of chosen vital biomarkers are specifically analyzed. It describes the challenges involved and the strategies reported for the development of selective, sensitive, and disposable electrochemical biosensors with the details of fabrication, functionalization, and applications of hybrid metallic composite nanostructures.