Biosorption of heavy metals: Transferability between batch and column studies.

The design of an industrial water treatment system using sorption is based on laboratory column tests. To verify the applicability of a column sorption system at industrial scale, it is necessary to determine the system's breakthrough time (BT) in a laboratory setting. In a laboratory column set-up, BT is referred to as the time taken by the adsorbate to appear at column outlet for the first time. This is when the mass transfer zone (MTZ), where the equilibrium sorption occurs, reaches the end of the sorbent bed. However, such laboratory set-up requires significant resources including laboratory space, time and multiple trials, which is the opposite to the batch experimental approach that is commonly used to assess efficiency of sorbents. This study identified batch sorption parameters that can be used to determine BT for a column sorption setting for three toxic heavy metals commonly found in industrial wastewater, namely, Pb2+, Cd2+ and Cu2+. The study conducted a comprehensive evaluation of the relationships between column BT and its key influential factors, namely, equilibrium sorption capacity (qe), pseudo second-order kinetic rate constant (k2) and initial sorption rate (h). The results revealed that BT can be better estimated using h compared to qe and k2. As such, a batch experiment which is more resource efficient could be undertaken for an initial estimation of the experimental BT of a column system. Moreover, a simulation model developed to replicate column sorption could demonstrate the behaviour of the breakthrough curve, which is a key to the selection and assessment of the performance of a sorbent in an adsorbent column. The estimation errors in qe and k2 were found to influence the simulation outcomes. Hence, it is necessary to further investigate the other factors that can potentially influence sorption behaviour.

Migration of phthalates from PET water bottle in events of repeated uses and associated risk assessment.

Phthalates are widely used as a plasticizer in manufacturing polyethylene terephthalate (PET) bottles to improve softness, flexibility, durability, longevity, and workability. Phthalates are known in instigating profound human health hazards. In many developing countries, lack of proper disposal facilities established for empty PET bottles and the absence of legislation on reuse invariably persuade people to reuse them for storing potable water. An experiment was conducted with two commercial brands of PET bottles to explore the potential of phthalate migration when domestically refilled and reused in multiple times at two temperature conditions. Temperatures of ambient (27 ± 2 °C) and warm (60 ± 2 °C) were selected as the refilling temperatures because of the common practice by people. For both brands, only bis(2-ethylhexyl) phthalate (DEHP) levels were detected in refilled water in every event of reuse. For both brands, mean DEHP levels migrated to water at 60 ± 2 °C were significantly higher (p < 0.05) compared to those at 27 ± 2 °C. Risk analyses carried out on human health suggested that there exist no definite acute or chronic health risks when the refilled water is consumed continuously for 30 years for both temperatures. Still, such risks were higher for the consumption of refilled water of warm temperatures than those of ambient temperature. However, this study elucidates that DEHP migration would be at an alarming rate when the events of reuse of a single bottle increase so that regulations banning the reuse of empty PET bottles are paramount, especially for developing countries.

Relation of waste generation and composition to socio-economic factors: a case study.

To develop an effective waste management strategy for a given region, it is important to know the amount of waste generated and the composition of the waste stream. Past research has shown that the amount of waste generated is proportional to the population and the average mean living standards or the average income of the people. In addition, other factors may affect the amount and composition of waste. These are climate, living habits, level of education, religious and cultural beliefs, and social and public attitudes. This paper presents the findings of a study carried out in a suburban municipal area in Sri Lanka to determine the solid waste generation rate and waste composition based on field surveys and to determine the related socio-economic factors. A database was developed that included information on the quantity and composition of waste generated in a sample of households in the study area over a time period. The collected data was analysed to relate waste generation and composition data to various socio-economic factors. Over 400 sample households were selected for the study using a stratified random sampling methodology based on municipal wards and property values. A technique that considers both the number of households in a particular income group (property value range) and the standard deviation of property values within a given income group was used to determine the appropriate sample size for each municipal ward. Through category and regression analyses, the quantities of waste and waste composition were related to several socio-economic factors. The paper describes the basis for the sample selection, the methodology adopted for data collection, the socio-economic parameters used for the analysis, and the relationships developed from the analysis.