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2.
Environ Sci Technol ; 51(23): 13779-13787, 2017 Dec 05.
Article in English | MEDLINE | ID: mdl-29086564

ABSTRACT

Hydraulic fracturing in shale gas formations involves the injection of large volumes of aqueous fluid deep underground. Only a small proportion of the injected water volume is typically recovered, raising concerns that the remaining water may migrate upward and potentially contaminate groundwater aquifers. We implement a numerical model of two-phase water and gas flow in a shale gas formation to test the hypothesis that the remaining water is imbibed into the shale rock by capillary forces and retained there indefinitely. The model includes the essential physics of the system and uses the simplest justifiable geometrical structure. We apply the model to simulate wells from a specific well pad in the Horn River Basin, British Columbia, where there is sufficient available data to build and test the model. Our simulations match the water and gas production data from the wells remarkably closely and show that all the injected water can be accounted for within the shale system, with most imbibed into the shale rock matrix and retained there for the long term.


Subject(s)
Groundwater , Hydraulic Fracking , Natural Gas , British Columbia , Oil and Gas Fields , Water Wells
3.
Environ Sci Technol ; 49(15): 9222-9, 2015 Aug 04.
Article in English | MEDLINE | ID: mdl-26186496

ABSTRACT

Recent studies suggest the possibility of CO2 sequestration in depleted shale gas formations, motivated by large storage capacity estimates in these formations. Questions remain regarding the dynamic response and practicality of injection of large amounts of CO2 into shale gas wells. A two-component (CO2 and CH4) model of gas flow in a shale gas formation including adsorption effects provides the basis to investigate the dynamics of CO2 injection. History-matching of gas production data allows for formation parameter estimation. Application to three shale gas-producing regions shows that CO2 can only be injected at low rates into individual wells and that individual well capacity is relatively small, despite significant capacity variation between shale plays. The estimated total capacity of an average Marcellus Shale well in Pennsylvania is 0.5 million metric tonnes (Mt) of CO2, compared with 0.15 Mt in an average Barnett Shale well. Applying the individual well estimates to the total number of existing and permitted planned wells (as of March, 2015) in each play yields a current estimated capacity of 7200-9600 Mt in the Marcellus Shale in Pennsylvania and 2100-3100 Mt in the Barnett Shale.


Subject(s)
Carbon Dioxide/analysis , Geologic Sediments/chemistry , Models, Theoretical , Oil and Gas Fields/chemistry , Computer Simulation , Methane/analysis , Natural Gas/analysis , Pennsylvania , Pressure , Time Factors
4.
Environ Sci Technol ; 49(7): 4757-64, 2015 Apr 07.
Article in English | MEDLINE | ID: mdl-25768798

ABSTRACT

Abandoned oil and gas (AOG) wells can provide pathways for subsurface fluid migration, which can lead to groundwater contamination and gas emissions to the atmosphere. Little is known about the millions of AOG wells in the U.S. and abroad. Recently, we acquired data on methane emissions from 42 plugged and unplugged AOG wells in five different counties across western Pennsylvania. We used historical documents to estimate well depths and used these depths with the emissions data to estimate the wells' effective permeabilities, which capture the combined effects of all leakage pathways within and around the wellbores. We find effective permeabilities to range from 10(-6) to 10(2) millidarcies, which are within the range of previous estimates. The effective permeability data presented here provide perspective on older AOG wells and are valuable when considering the leakage potential of AOG wells in a wide range of applications, including geologic storage of carbon dioxide, natural gas storage, and oil and gas development.


Subject(s)
Methane/analysis , Oil and Gas Fields , Carbon Dioxide/analysis , Groundwater , Pennsylvania , Permeability , Water Pollution
5.
Ground Water ; 53(3): 362-77, 2015.
Article in English | MEDLINE | ID: mdl-25662534

ABSTRACT

Geologic carbon sequestration (GCS) is being considered as a climate change mitigation option in many future energy scenarios. Mathematical modeling is routinely used to predict subsurface CO2 and resident brine migration for the design of injection operations, to demonstrate the permanence of CO2 storage, and to show that other subsurface resources will not be degraded. Many processes impact the migration of CO2 and brine, including multiphase flow dynamics, geochemistry, and geomechanics, along with the spatial distribution of parameters such as porosity and permeability. In this article, we review a set of multiphase modeling approaches with different levels of conceptual complexity that have been used to model GCS. Model complexity ranges from coupled multiprocess models to simplified vertical equilibrium (VE) models and macroscopic invasion percolation models. The goal of this article is to give a framework of conceptual model complexity, and to show the types of modeling approaches that have been used to address specific GCS questions. Application of the modeling approaches is shown using five ongoing or proposed CO2 injection sites. For the selected sites, the majority of GCS models follow a simplified multiphase approach, especially for questions related to injection and local-scale heterogeneity. Coupled multiprocess models are only applied in one case where geomechanics have a strong impact on the flow. Owing to their computational efficiency, VE models tend to be applied at large scales. A macroscopic invasion percolation approach was used to predict the CO2 migration at one site to examine details of CO2 migration under the caprock.


Subject(s)
Carbon Dioxide/chemistry , Carbon Sequestration , Geological Phenomena , Groundwater , Models, Theoretical , Porosity , Salts/chemistry
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