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γ-Selective directed catalytic asymmetric hydroboration of 1,1-disubstituted alkenes.
Smith, Sean M; Hoang, Gia L; Pal, Rhitankar; Bani Khaled, Mohammad O; Pelter, Liberty S W; Zeng, Xiao Cheng; Takacs, James M.
Chem Commun (Camb) ; 48(100): 12180-2, 2012 Dec 28.
Article in English | MEDLINE | ID: mdl-23145431

ABSTRACT

Directed catalytic asymmetric hydroborations of 1,1-disubstituted alkenes afford γ-dioxaborato amides and esters in high enantiomeric purity (90-95% ee).


Subject(s)
Alkenes/chemistry , Boron/chemistry , Catalysis , Models, Molecular , Molecular Conformation , Stereoisomerism , Substrate Specificity
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