Trehalose-conjugated lentil-casein protein complexes prepared by structural interaction: Effects on water solubility and protein digestibility.

The two limiting factors for lentil protein utilization are water solubility and digestibility. In this study, we utilized two non-thermal techniques: (1) protein complexation of lentil and casein proteins using the pH-shifting method and (2) protein conjugation with trehalose to produce trehalose-conjugated lentil-casein protein complexes (T-CPs) with enhanced water solubility and digestibility. The protein structure of the T-CPs was analyzed for secondary protein structure, conformation protein, and tertiary protein structure using Fourier-transform infrared, UV, and fluorescence spectroscopies, respectively. The surface hydrophobicity and surface charge of T-CPs solution at pH 7.0 changed significantly (P < 0.05). Using these two non-thermal techniques, the water solubility and digestibility of T-CPs increased significantly (P < 0.05) by 85 to 89 % and 80 to 85 %, respectively. The results of this study suggested that these non-thermal techniques could enhance the surface and protein structure properties, improving water solubility and digestibility.

Integrating of electrocoagulation process with submerged membrane bioreactor for wastewater treatment under low voltage gradients.

Treating and reusing wastewater has become an essential aspect of water management worldwide. However, the increase in emerging pollutants such as polycyclic aromatic hydrocarbons (PAHs), which are presented in wastewater from various sources like industry, roads, and household waste, makes their removal difficult due to their low concentration, stability, and ability to combine with other organic substances. Therefore, treating a low load of wastewater is an attractive option. The study aimed to address membrane fouling in the submerged membrane bioreactor (SMBR) used for wastewater treatment. An aluminum electrocoagulation (EC) device was combined with SMBR as a pre-treatment to reduce fouling. The EC-SMBR process was compared with a conventional SMBR without EC, fed with real grey water. To prevent impeding biological growth, low voltage gradients were utilized in the EC deviceThe comparison was conducted over 60 days with constant transmembrane pressure and infinite solid retention time (SRT). In phase I, when the EC device was operated at a low voltage gradient (0.64 V/cm), no significant improvement in the pollutants removal was observed in terms of color, turbidity, and chemical oxygen demand (COD). Nevertheless, during phase II, a voltage gradient of 1.26 V/cm achieved up to 100%, 99.7%, 92%, 94.1%, and 96.5% removals in the EC-SMBR process in comparison with 95.1%, 95.4%, 85%, 91.7% and 74.2% removals in the SMBR process for turbidity, color, COD, ammonia nitrogen (NH3-N), total phosphorus (TP), respectively. SMBR showed better anionic surfactant (AS) removal than EC-SMBR. A voltage gradient of 0.64 V/cm in the EC unit significantly reduced fouling by 23.7%, while 1.26 V/cm showed inconsistent results. Accumulation of Al ions negatively affected membrane performance. Low voltage gradients in EC can control SMBR fouling if Al concentration is controlled. Future research should investigate EC-SMBR with constant membrane flux for large-scale applications, considering energy consumption and operating costs.

Evaluation of scrap metallic waste electrode materials for the application in electrocoagulation treatment of wastewater.

The constant need for sacrificial electrodes is one of the limitations of applying the EC in wastewater treatment. Accordingly, this study proposes a sustainable alternative in reusing scrap metallic wastes as electrode materials. Four different types of metallic wastes (beverage cans, used aluminum (Al) foil, scrap iron, and scrap mild steel) are proposed as sacrificial electrodes for grey water (GW) treatment using the EC technique. At electrical current densities (CD) ranging between 5 and 20 mA/cm2, the treatment performance was evaluated for a reaction time of 10 min in terms of the removal efficiency of some key parameters such as color, turbidity, chemical oxygen demand (COD), and electrical conductivity, energy and material consumption, and metal contamination of GW from electrodes. The results demonstrated that using metallic wastes as sacrificial electrodes can achieve a considerable reduction in color, turbidity, COD, and electric conductivity of about 97.2%, 99%, 88%, and 89%, respectively. However, their reuse as electrodes revealed some important concerns. Al foil undergoes quick and substantial perforation and loss of surface area during electrolysis. The scrap iron and scrap mild steel were found to cause metal contamination by increasing Fe ions in the treated GW. Generally, metal scrap wastes can serve effectively as alternative sustainable electrodes. However, further research is recommended regarding the operating costs, which are considered crucial aspects of the EC process in terms of energy consumption and the most efficient method of fabricating the metallic wastes into a form suitable for reuse in the EC technique.

Combined electrocoagulation processes as a novel approach for enhanced pollutants removal: A state-of-the-art review.

A novel approach using the integration of electrocoagulation, with one or more treatment processes has been recently practiced to improve the removal of colloidal and non-biodegradable pollutants. Several treatment processes including adsorption, chemical coagulation, magnetic field, reverse osmosis, and membrane filtration have been combined with electrocoagulation treatment step to improve pollutants removal efficiency. These combined systems showed the potential to improve the performance of the treatment process. This paper presents a state-of-the-art review for the recent processes available in the literature that combine treatment electrocoagulation with one of the previously mentioned treatment processes. It is found that the removal efficiency of any combined processes is higher than that of any single treatment process and the combined process has up to 20% higher removal efficiency compared to electrocoagulation alone. However, most reported studies were conducted at bench-scale level with synthetic wastewater instead of real wastewater. The main aspects of these combined systems including process mechanism, kinetic models, cost and the scale up of combined processes were discussed and summarized. Finally, several concluding remarks were drawn in view of the literature investigations and the gaps that suggest more studies and insights for future development were addressed.

Treatment of olive mill effluent by adsorption on titanium oxide nanoparticles.

Olive mills wastewater (OMW) causes a serious environmental problem in the olive oil producing countries. This is due to its high organic matter content (COD), acidic pH values, suspended solids and high content of phytotoxic and antibacterial phenolic compounds. In this study, titanium dioxide (TiO2) as an adsorbent to reduce the COD value of the olive mill wastewater was investigated. Several variables were studied including the removal efficiency, effect of the initial COD value, amount of TiO2, temperature and pH value. The results revealed that the adsorption reached equilibrium within <120 min. Isotherm studies showed that the adsorption equilibrium data is in agreement with Freundlich isotherm. In addition, the results showed that the adsorption process was spontaneous and exothermic. The kinetic study indicated that adsorption did follow a pseudo-second order reaction. Variation of the amount of the TiO2 showed that using of 1.5 and 2 g/L of TiO2 caused the COD to drop from 1000 ppm to about 100 ppm (equilibrium concentration) in about 120 min. However, the use of 1 g/L of TiO2 exhibited almost the same effect on the COD-uptake, and the equilibrium concentration was about 400 ppm. The COD uptake was found to be inversely proportional with the temperature, pH value and the addition of salts such as sodium chloride (NaCl) and potassium chloride (KCl).

Development of a novel Submerged Membrane Electro-Bioreactor (SMEBR): performance for fouling reduction.

A novel Submerged Membrane Electro-Bioreactor (SMEBR) was developed to treat wastewater and control the problem of membrane fouling. To validate the new design, experimental work was achieved in a few phases. This paper describes the design constraints and criteria of the new developed SMEBR system, and shows the results of the performance of the SMEBR system to reduce membrane fouling when intermittent direct current (DC) (15 min ON/45 min OFF) was applied using cylindrical iron mesh for both electrodes. Application of the SMEBR system enhanced the membrane filterability by reducing the fouling rate up to 16.3% without any backwashing of the membrane module. The improvement in membrane filterability associated with a decrease in zeta potential of the mixed liquor flocs from -30.5 up to -15.3 mV and a decrease in specific resistance to filtration (SRF) up to 40% was observed.