On the change in bacterial size and magnetosome features for Magnetospirillum magnetotacticum (MS-1) under high concentrations of zinc and nickel.

The characteristic size, shape and specific alignment of magnetite crystals synthesized by magnetotactic bacteria is a highly coordinated process with precise control over magnetosome vesicle formation, uptake and transport of Fe, and magnetite biomineralization. Magnetosome membranes along with some specific membrane proteins regulate crystal nucleation and morphology of magnetite. Several previous works have indicated that the morphology of mature magnetite crystals is largely unaffected by environmental conditions, though some recent studies have shown the possibility of manipulation of the biomineralization process. In this study we have examined the effects of high concentrations of Zinc and Nickel on the growth of Magnetospirillum magnetotacticum (MS-1) and the corresponding magnetosome formation. Using various characterizations it is shown that the growth of the bacterial cells, as well as the size, shape and magnetosome chain alignment is significantly influenced in the presence of high concentrations of Zn or Ni.

Electrowetting of complex fluids: perspectives for rheometry on chip.

We explore the possibilities of electrowetting (EW) as a tool to assess the elastic properties of aqueous jellifying materials present in the form of a small droplet on a hydrophobic substrate. We monitored the EW response of aqueous solutions of gelatin (2-10 wt %) in ambient oil for various temperatures (8-40 degrees C) below and above the gel point. Whereas the drops remained approximately spherical cap-shaped under all conditions, the voltage-induced reduction of the contact angle became progressively less pronounced upon entering the gel state at lower temperatures. We modeled the decrease in contact angle by minimizing the total energy of the drops consisting of interfacial energies, electrostatic energy, and the elastic energy due to the deformation of the drop, which was taken into account in a modified Hertz model. This allowed fitting the data and extracting the elastic modulus G, which were found to agree well with macroscopic storage moduli G' obtained with oscillatory shear rheometry. These results show that EW can be used as a tool for characterizing soft materials with the elastic moduli ranging (at least) from 10 to 1000 Pa. Our observations also create interesting perspectives for performing in situ rheological measurement inside microfluidic chips.

Electrowetting --a versatile tool for controlling microdrop generation.

Integrating insulator-covered electrodes into a microfluidic flow focusing device (FFD) we demonstrate enhanced flexibility and control of the flow of two non-miscible liquids based on electrowetting (EW). In the parameters space, determined by liquid inlet pressures, we identify a specific region where drops can only be generated and addressed via EW. In this regime we show that the size distribution and the frequency of drop generation can be controlled by the applied voltage and the width of voltage pulses. Moreover it turns out that with EW the drop size and the frequency can be tuned independently. Finally we show that the same drop generation phenomena can also be observed in the presence of surfactants.

Segregation of fractal aggregates grown from two seeds.

We study the generalized diffusion-limited aggregates, grown from two proximal nucleation seeds placed at distance d lattice units and investigate the probability p(d) that these aggregates get connected. We vary the sticking probability to get a range of aggregate geometry from fractal to compact one. For fractal aggregates, p(d) decays rapidly with d , while for compact ones, the decay is so slow that p(d) approximately 1 for all practical distances. We experimentally demonstrate similar behavior for viscous fingering patterns with two injection points and electrochemical deposits grown on two cathodes. Our observations along with previous results on competitive growth suggest a common underlying principle.

Universality of the power-law approach to the jamming limit in random sequential adsorption dynamics.

Random sequential adsorption (RSA), on a two-dimensional continuum substrate, of different types of zero area objects that disallow domain formation and hence lead to jamming, is examined by simulation. In all the cases, in the asymptotic time regime, the approach of the number density rho(t) at instant t to jamming density rho(infinity) is found to exhibit power law rho(infinity)-rho(t) approximately t{-p} as that for RSA of finite area objects. These results suggest the possibility of the power law being universal for all jamming systems in RSA on a continuum substrate. A generalized analytical treatment is also proposed.