ABSTRACT
In this study, electrically-assisted micro-compression (EAMC) tests were conducted for cylindrical specimens of Ti-6Al-4V alloy with four geometric sizes and three initial microstructures. The result showed that the specimen temperature nonlinearly increased with the square of current density. The quasi-static heat equilibrium equation was established to quantify the effects of the scale factor on the Joule heat temperature. Moreover, it was demonstrated that the Joule temperature scale effect had a greater effect on the flow stress than the sample size effect for specimens of different dimensions. It was noted that the 0.5 mm diameter sample displayed abnormal deformation behavior, which was related to surface oxidation leading a brittle surface layer. By comparison of the microstructures, it was found that the αâß phase transformation occured below the ß transus temperature, which was attributed to the local Joule heat effect and the scattering of drift electrons during EAMC. Furthermore, the flow curves showed a strong dependence of the strength and ductility on the initial microstructure. The widmannstatten microstructure exhibited higher strength, smaller hardening rate and more easy flow localization compared with basket-weave microstructures, which was attributed to the low ß phase content and narrow interlamellar spacing of α lamellae grains in the widmannstatten microstructure.
ABSTRACT
With the rapid development of micro-electromechanical systems (MEMS), micro/nanoscale fabrication of 3D metallic structures with complex structures and multifunctions is becoming more and more important due to the recent trend of product miniaturization. As a promising micromanufacturing approach based on plastic deformation, micro/nanoforming shows the attractive advantages of high productivity, low cost, near-net-shape, and excellent mechanical properties, compared with other non-silicon-based micromanufacturing technologies. However, micro/nanoforming is far less established due to the so-called size effects in terms of materials models, process laws, tooling design, etc. The understanding of basic issues on micro/nanoforming is not yet mature, and it is currently a topic of rigorous investigation. Here, a systematic review on the micro/nanoforming processes of 3D structures with multifunctional properties is presented, wherein also a critical examination of the interplay between relevant length scales and size effects affecting the structural integrity of micro/mesoscale metallic systems is also provided. Finally, the challenges of micro/nanoscale fabrication are proposed, including the development trends of new micro/nanoforming processes, multiple field coupling effects, and theoretical modeling at the trans-scale.
ABSTRACT
The novel porous Ag2CO3 nanorods were facilely synthesized via a one-pot aqueous solution reaction at room temperature. The crystalline phase and size distribution of the nanorods were determined by X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. In addition, the porous feature of nanorods was confirmed by transmission electron microscopy (TEM) and nitrogen adsorption-desorption. The morphology and size of the Ag2CO3 crystal can be regulated via the choice of dispersing agents and adding approaches of reactants. Photocatalytic results show that the porous Ag2CO3 nanorods exhibit excellent photodegradation of rhodamine B (RhB) under visible-light irradiation, particularly the photoactivity performance and stability can be further improved in the presence of sodium bicarbonate (NaHCO3). It is indicated that NaHCO3 can prevent effectively the photocorrosion and promote the probability of electron-hole separation.
