ABSTRACT
Nanofluid preparation is a crucial step in view of their thermophysical properties as well as the intended application. This work investigates the influence of ultrasonication duration on the thermal conductivity of Fe3O4 nanofluid. In this work, water-based Fe3O4 nanofluids of various volume concentrations (0.01 and 0.025 vol.%) were prepared and the effect of ultrasonication time (10 to 55 min) on their thermal conductivity was investigated. Ultrasonication, up to a time duration of 40 min, was found to raise the thermal conductivity of Fe3O4 nanofluids, after which it starts to deteriorate. For a nanofluid with a concentration of 0.025 vol.%, the thermal conductivity increased to 0.782 W m-1K-1 from 0.717 W m-1K-1 as the ultrasonication time increased from 10 min to 40 min; however, it further deteriorated to 0.745 W m-1K-1 after a further 15 min increase (up to a total of 55 min) in ultrasonication duration. Thermal conductivity is a strong function of concentration of the nanofluid; however, the optimum ultrasonication time is the same for different nanofluid concentrations.
ABSTRACT
Technologies for wastewater remediation have been growing ever since the environmental and health concern is realized. Development of nanomaterials has enabled mankind to have different methods to treat the various kinds of inorganic and organic pollutants present in wastewater from many resources. Among the many materials, semiconductor materials have found many environmental applications due to their outstanding photocatalytic activities. TiO2 and ZnO are more effectively used as photocatalyst or adsorbents in the withdrawal of inorganic as well as organic wastes from the wastewater. On the other hand, graphene is tremendously being investigated for applications in environmental remediation in view of the superior physical, optical, thermal, and electronic properties of graphene nanocomposites. In this work, graphene-TiO2 and graphene-ZnO nanocomposites have been reviewed for photocatalytic wastewater treatment. The various preparation techniques of these nanocomposites have been discussed. Also, different design strategies for graphene-based photocatalyst have been revealed. These nanocomposites exhibit promising applications in most of the water purification processes which are reviewed in this work. Along with this, the development of these nanocomposites using biomass-derived graphene has also been introduced. PRACTITIONER POINTS: Graphene-TiO2 and graphene-ZnO nanocomposites are effective for wastewater treatment through photocatalysis. These nanocomposite photocatalysts have been used in the form of membrane as well as antibacterial agents. Synthetic strategies and design considerations of graphene-based photocatalyst play a major role. Biomass-derived graphene-TiO2 and graphene-ZnO nanocomposites have also found application in wastewater treatment.
Subject(s)
Graphite , Nanocomposites , Water Purification , Zinc Oxide , Catalysis , TitaniumABSTRACT
The present work pertains to synthesis of Sm-doped GO/KSrPO4 (GO/KSrPO4 :Sm) nanocomposite using ultrasound-assisted method. Successful decoration of graphene oxide sheets with the KSrPO4 :Sm3+ phosphor was confirmed using analysis techniques including SEM, EDS, UV/visible spectrometry, XRD, and FTIR of the prepared GO/KSrPO4 :Sm nanocomposite. Further, photocatalytic activity of this nanocomposite material was studied by examining degradation of methylene blue (MB) dye from water. The effects of several parameters like concentration of Sm3+ in KSrPO4 :Sm3+ phosphor within the GO/KSrPO4 :Sm nanocomposite photocatalyst, photocatalyst loading, initial dye concentration, pH, and preparation method were evaluated. At a higher concentration of Sm3+ in the photocatalyst (1 mol.%), higher photocatalyst loading (1.5 mg/ml), lesser dye concentration (20 mg/L), and higher pH (11.4), the GO/KSrPO4 :Sm nanocomposite photocatalyst prepared using ultrasound-assisted method showed higher dye removal compared to other conditions. A maximum of 83.35% removal of MB dye was achieved by the use of ultrasonically prepared GO/KSrPO4 :Sm nanocomposite photocatalyst having a concentration of 1 mol.% of Sm3+ in the KSrPO4 :Sm3+ phosphor at a loading of 1.5 mg/ml, initial dye concentration of 20 mg/L, and a pH of 11.4. Rate constant for MB dye degradation using the GO/KSrPO4:Sm nanocomposite photocatalyst synthesized by ultrasonic-assisted method was found to be 0.0053 min-1 . PRACTITIONER POINTS: GO/KSrPO4 :Sm nanocomposite photocatalyst prepared by ultrasonic-assisted method. Higher Sm3+ doping in nanocomposite with the use of ultrasound assisted method showed better performance of photocatalyst. A maximum removal of 83.35% of methylene blue dye was achieved.
