Nanostructuring Biobased Epoxy Resin with PEO-PPO-PEO Block Copolymer.

A biobased diglycidyl ether of vanillin (DGEVA) epoxy resin was nanostructured by poly(ethylene oxide-b-propylene oxide-b-ethylene oxide) (PEO-PPO-PEO) triblock copolymer. Due to the miscibility/immiscibility properties of the triblock copolymer in DGEVA resin, different morphologies were obtained depending on the triblock copolymer amount. A hexagonally packed cylinder morphology was kept until reaching 30 wt% of PEO-PPO-PEO content, while a more complex three-phase morphology was obtained for 50 wt%, in which large worm-like PPO domains appear surrounded by two different phases, one of them rich in PEO and another phase rich in cured DGEVA. UV-vis measurements show that the transmittance is reduced with the increase in triblock copolymer content, especially at 50 wt%, probably due to the presence of PEO crystals detected by calorimetry.

Biocomposites with increased dielectric constant based on chitosan and nitrile-modified cellulose nanocrystals.

The motivation of the present work was the preparation of bio-based thin film nanocomposites with improved dielectric properties using modified nanocellulose and chitosan, both materials known to derive from industrial waste. Cyanoethylation of cellulose nanocrystals (CNC) was achieved through a "green" method for the first time. Then, modified CNCs were incorporated into a chitosan (Chi) matrix, obtaining a homogeneous and flexible material with higher dielectric constant due to the high dipole moment of the nitrile functional group. The value of dielectric constant rises with the content of modified CNCs, from a value of 5.5 for pure chitosan at 25 °C and 1 kHz up to a value of 8.5 for the nanocomposite with 50 wt% at the same conditions. These bio-based nanocomposites show an improvement in their dielectric properties compared to pure chitosan and chitosan/unmodified CNC nanocomposites (for which dielectric constant decreases up to 4.5 at 25 °C and 1 kHz) and can be considered for high-temperature applications. Characterization of cyanoethylated cellulose nanocrystals (CN-CNC) and nanocomposites was carried out by infrared spectroscopy (FT-IR), attenuated total reflectance spectroscopy (ATR), atomic force microscopy (AFM), thermogravimetric analysis (TGA), X-ray diffraction (XRD), and solid-state NMR and broad band dielectric spectroscopy (BDS). Tensile tests were developed for mechanical characterization.