Critical wetting transitions in two-dimensional systems subject to long-ranged boundary fields.

Using the quasiexact density-matrix renormalization-group method and ground-state analysis we study interface delocalization transitions in wide two-dimensional Ising strips subject to long-ranged boundary fields with opposite signs at the two surfaces. Based on this approach, our explicit calculations demonstrate that critical wetting transitions do exist for semi-infinite two-dimensional systems even if the corresponding effective interface potentials decay asymptotically for large l as slow as l(-delta) with delta<2, where l is the distance of the mean interface position from the one-dimensional surface. This supersedes opposite claims by Kroll and Lipowsky [Phys. Rev. B 28, 5273 (1983)] and by Privman and Svrakic [Phys. Rev. B 37, 5974 (1988)] obtained within effective interface models. The corresponding wetting phase diagram is determined, including the cases delta=2 and delta=49 with the latter mimicking short-ranged surface fields. Our analysis highlights the limits of reliability of effective interface models.

Interplay of complete wetting, critical adsorption, and capillary condensation.

The excess adsorption Gamma in two-dimensional Ising strips (infinityxL), subject to identical boundary fields at both one-dimensional surfaces decaying in the orthogonal direction j as -h1j(-p), is studied for various values of p and along various thermodynamic paths below the bulk critical point by means of the density-matrix renormalization-group method. The crossover behavior between the complete-wetting and critical-adsorption regimes, occurring in semi-infinite systems, is strongly influenced by confinement effects. Along isotherms T=const the asymptotic power-law dependences on the external bulk field, which characterize these two regimes, are pre-empted by capillary condensation. Along the pseudo-first-order phase-coexistence line of the strips, which varies with temperature, we find a broad crossover regime in which both the thickness of the wetting film and Gamma increase as functions of the reduced temperature tau but do not follow any power law. Above the wetting temperature the order-parameter profiles are not slablike but exhibit wide interfacial variations and pronounced tails.