ABSTRACT
Visible-light-photoactive titania micro- or nanoparticles excel in a wide range of industrial areas, particularly in environmental remediation. The sol-gel methodology is one pivotal technique which has been successfully used to synthesize either crystalline and amorphous TiO2 micro- and nanoparticles due to its outstanding chemical simplicity and versatility, along with the green chemistry approach. This short review aims to collect and discuss the most recent developments in visible-light-photoactive titania-based nanoparticles in the environmental remediation area. Titania co-doping, titania composite design, and, recently, amorphous networks have been the most used strategies to address this goal. Finally, a prediction regarding the future of these fields is given.
ABSTRACT
Inorganic glass is a transparent functional material and one of the few materials that keeps leading innovation. In the last decades, inorganic glass was integrated into opto-electronic devices such as optical fibers, semiconductors, solar cells, transparent photovoltaic devices, or photonic crystals and in smart materials applications such as environmental, pharmaceutical, and medical sensors, reinforcing its influence as an essential material and providing potential growth opportunities for the market. Moreover, inorganic glass is the only material that is 100% recyclable and can incorporate other industrial offscourings and/or residues to be used as raw materials. Over time, inorganic glass experienced an extensive range of fabrication techniques, from traditional melting-quenching (with an immense diversity of protocols) to chemical vapor deposition (CVD), physical vapor deposition (PVD), and wet chemistry routes as sol-gel and solvothermal processes. Additive manufacturing (AM) was recently added to the list. Bulks (3D), thin/thick films (2D), flexible glass (2D), powders (2D), fibers (1D), and nanoparticles (NPs) (0D) are examples of possible inorganic glass architectures able to integrate smart materials and opto-electronic devices, leading to added-value products in a wide range of markets. In this review, selected examples of inorganic glasses in areas such as: (i) magnetic glass materials, (ii) solar cells and transparent photovoltaic devices, (iii) photonic crystal, and (iv) smart materials are presented and discussed.
ABSTRACT
Although fluorescent lamps (FL) are extensively used worldwide, recycling rates in some countries are still low. If disposed of inappropriately and broken, FL can cause soil contamination. Hg toxicity in FL is extensively discussed in the literature; however, few studies address the other toxic metals present in the phosphorous powder of FL (PPFL). This paper presents a characterization of the environmental mobility with sequential extraction scheme (SES) of Cd, Cu, Hg, Mn, Ni, Pb, and Zn in PPFL, and modeling the potential risks to human health, in case of direct disposal in soils. An after thermal treatment waste was used for safety reasons. The SES method included five fractions, and the quantification was performed by flame atomic absorption spectrometry (FAAS). Human health risk assessment (HHRA) was conducted using RISC4® software. The PPFL showed the following mobility sequence: Cu (85%) > Ni (81%) > Hg (80%) > Zn (77%) > Cd (75%) > Mn (6%) > Pb (2%), which suggests that Cu, Ni, Zn, and Cd, besides Hg, could be of environmental concern in terms of availability. HHRA showed the potential hazard of Cd, for both children and adults, in the hypothetical scenario of vegetable ingestion, considering vegetables grown in soils contaminated with FL waste. The thermal treatment does not completely remove Hg from the matrix, and the residual Hg still poses a risk to children. These results show that Hg and Cd can be hazardous to humans and reinforce the importance of the correct disposal and treatment of PPFL.
