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J Environ Monit ; 7(3): 196-202, 2005 Mar.
Article in English | MEDLINE | ID: mdl-15735778

ABSTRACT

Pulsed column experiments using Co, fulvic acid and porous sediment packing, along with up/down-flooding experiments using Eu, humic acid and intact sandstone blocks have been performed. The elution of metal and humic and their distribution along the sandstone columns have been measured. A mixed equilibrium and kinetic coupled chemical transport model has been used to simulate the results. In both cases, one exchangeable and one non-exchangeable component have been used to simulate the interaction of metal and humic substance. For the pulsed experiments, a simple equilibrium approach was used to model humic sorption, while a two component, kinetic model was required for the sandstone columns.


Subject(s)
Benzopyrans/chemistry , Cobalt/chemistry , Europium/chemistry , Humic Substances , Models, Chemical , Adsorption , Geologic Sediments , Kinetics , Silicon Dioxide
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