ABSTRACT
A successful mechanochemical synthesis of a new nanoscale semi-conductive perovskite, La0.25Sr0.75Sn0.4In0.25Ru0.35O3 (LSSIRuO) was achieved through co-doping of SrSnO3. XRD and IR analyses confirmed that the sample crystallized in a pure perovskite GdFeO3 type structure (Pnma space group). Diffuse reflectance measurements revealed a direct band gap of 1.3 eV, which was significantly narrowed compared to that of SrSnO3 (4.1 eV). The investigation of DFT calculations into the sextenary systems La0.25Sr0.75[Sn0.4Ru0.35]In0.25O3 and La0.25Sr0.75[Sn0.5Ru0.25]In0.25O3 has revealed semiconductor behavior, very close to a semiconductor-semi metal transition. Importantly, Arrhenius-type charge transport was confirmed through a temperature-dependent conductivity study of the sample, showing good electrical conductivity of 3.6 S m-1 at 513 K with an activation energy of Ea = 0.19 eV. Furthermore, the compound exhibited ferromagnetic ordering at temperatures lower than 155 K, contrasting the diamagnetic behavior of SrSnO3. The narrower band gap value (1.3 eV) and improved electrical properties of LSSIRuO, in addition to its ferromagnetic characteristics, distinguish it as a promising candidate for applications in optoelectronics, as well as in memory and spintronic devices.