Microstructure and Mechanical Properties of Hypereutectic Al-High Si Alloys up to 70 wt.% Si-Content Produced from Pre-Alloyed and Blended Powder via Laser Powder Bed Fusion.

Hypereutectic Al-high Si alloys are of immense interest for applications in the automotive, space or electronic industries, due their low weight, low thermal expansion, and excellent mechanical and tribological properties. Additionally, their production by laser powder bed fusion (LPBF) technology provides high flexibility in geometrical design and alloy composition. Since, most of the alloy properties could be improved by increasing the Si content, there is much interest in discovering the maximum that could be realized in LBPF Al-high Si alloys, without the appearance of any material failure. For this reason, in this work the production of Al-high Si alloys with extremely high silicon content of up to 70 wt.% was fundamentally investigated with respect to microstructure and mechanical properties. Highly dense (99.3%) and crack-free AlSi50 samples (5 × 5 × 5 mm3), with excellent hardness (225 HV5) and compressive strength (742 MPa), were successfully produced. Further, for the first time, AlSi70 LBPF samples of high density (98.8%) without cracks were demonstrated, using moderate scanning velocities. Simultaneously, the hardness and the compressive strength in the AlSi70 alloys were significantly improved to 350 HV5 and 935 MPa, as a result of the formation of a continuous Si network in the microstructure of the alloy. With respect to the powder source, it was found that the application of powder blends resulted in similar alloy properties as if pre-alloyed powders were used, enabling higher flexibility in prospective application-oriented alloy development.

PBF-LB/M of Low-Alloyed Steels: Bainite-like Microstructures despite High Cooling Rates.

Laser-based powder bed fusion of metals (PBF-LB/M) is an emerging technology with enormous potential for the fabrication of highly complex products due to the layer-wise fabrication process. Low-alloyed steels have recently gained interest due to their wide potential range of applications. However, the correlation between the processing strategy and the material properties remains mostly unclear. The process-inherent high cooling rates support the assumption that a very fine martensitic microstructure is formed. Therefore, the microstructure formation was studied by means of scanning electron microscopy, hardness measurements, and an analysis of the tempering stability. It could be shown that additively manufactured Bainidur AM samples possess a bainitic microstructure despite the high process-specific cooling rates in PBF-LB/M. This bainitic microstructure is characterized by an excellent tempering stability up to temperatures as high as 600 °C. In contrast to this, additively manufactured and martensitic-hardened specimens are characterized by a higher initial hardness but a significantly reduced tempering stability. This shows the potential of manufacturing products from Bainidur AM for high-temperature applications without the necessity of a post-process heat treatment for achieving the desired bainitic microstructure.

AlSi10Mg in Powder Bed Fusion with Laser Beam: An Old and Boring Material?

Powder bed fusion with laser beam of metals (PBF-LB/M) is a widely used technology to produce parts with a high freedom in design paired with excellent mechanical properties. The casting alloy AlSi10Mg features a wide process window and a microstructure with excellent mechanical properties which are not obtainable through conventional manufacturing. One possibility for achieving this is by influencing the solidification which then directly affects the local part properties. In this study, the effect of different laser beam profiles with gaussian and top-hat intensity distributions, as well as the influence of varying parameter sets on the microstructure and microhardness within the same specimen, was examined. A test specimen consisting of many small cubes was built with different parameters. It was found that the local properties can be varied in a wide range. Build-height-dependent in-situ aging effects can thereby be exploited for tailoring the local material properties. Thus, an extra degree of freedom is added to the design of additively manufactured parts.

In-Situ Alloy Formation of a WMoTaNbV Refractory Metal High Entropy Alloy by Laser Powder Bed Fusion (PBF-LB/M).

High entropy or multi principal element alloys are a promising and relatively young concept for designing alloys. The idea of creating alloys without a single main alloying element opens up a wide space for possible new alloy compositions. High entropy alloys based on refractory metals such as W, Mo, Ta or Nb are of interest for future high temperature applications e.g., in the aerospace or chemical industry. However, producing refractory metal high entropy alloys by conventional metallurgical methods remains challenging. For this reason, the feasibility of laser-based additive manufacturing of the refractory metal high entropy alloy W20Mo20Ta20Nb20V20 by laser powder bed fusion (PBF-LB/M) is investigated in the present work. In-situ alloy formation from mixtures of easily available elemental powders is employed to avoid an expensive atomization of pre-alloyed powder. It is shown that PBF-LB/M of W20Mo20Ta20Nb20V20 is in general possible and that a complete fusion of the powder mixture without a significant number of undissolved particles is achievable by in-situ alloy formation during PBF-LB/M when selecting favorable process parameter combinations. The relative density of the samples with a dimension of 6 × 6 × 6 mm3 reaches, in dependence of the PBF-LB/M parameter set, 99.8%. Electron backscatter diffraction (EBSD) and transmission electron microscopy (TEM) measurements confirm the presence of a single bcc-phase. Scanning electron microscopy (SEM) images show a dendritic and/or cellular microstructure that can, to some extent, be controlled by the PBF-LB/M parameters.

Grain Structure Evolution of Al-Cu Alloys in Powder Bed Fusion with Laser Beam for Excellent Mechanical Properties.

Powder Bed Fusion with Laser Beam of Metals (PBF-LB/M) is one of the fastest growing technology branches. More and more metallic alloys are being qualified, but processing of aluminum wrought alloys without cracks and defects is still challenging. It has already been shown that small parts with low residual porosity can be produced. However, suffering from microscopic hot cracks, the fracture behavior has been rather brittle. In this paper different combinations of temperature gradients and solidification rates are used to achieve specific solidification conditions in order to influence the resulting microstructure, as well as internal stresses. By this approach it could be shown that EN AW-2024, an aluminum-copper wrought alloy, is processable via PBF-LB/M fully dense and crack-free with outstanding material properties, exceeding those reported for commonly manufactured EN AW-2024 after T4 heat treatment.